Thermal treatment process of a steel sheet and device for its implementation

Patent metadata

Field	Value
Publication number	US-10428401-B2
Application number	US-201314766332-A
Country	US
Kind code	B2
Filing date	Feb 6, 2013
Priority date	Feb 6, 2013
Publication date	Oct 1, 2019
Grant date	Oct 1, 2019

Abstract

A thermal treatment process of a ferrous alloy sheet is provided. The process includes the step of performing a thermal treatment on said sheet when running, by immersing it into at least one molten oxides bath. The molten oxides bath has a viscosity lower than 3·10 −1 Pa·s, the surface of the bath is in contact with a non-oxidizing atmosphere and the molten oxides are inert towards iron. The difference between the temperature of the ferrous alloy sheet at the entry of the bath and the temperature of the bath is between 25° C. and 900° C. The residues of oxides remaining on the surfaces of the ferrous alloy sheet at the exit of the bath are eliminated. A device for implementing this process is also provided.

First claim

What is claimed is:

1. A thermal treatment process for a ferrous alloy sheet comprising the steps of:
performing a thermal treatment on a running ferrous alloy sheet by immersing the ferrous alloy sheet into at least one molten oxides bath, the molten oxides bath having a viscosity lower than 3·10 −1 Pa·s, a surface of the bath being in contact with a non-oxidizing atmosphere, the molten oxides being inert towards iron and a difference (ΔT) between a temperature of the ferrous alloy sheet at an entry of the bath and a temperature of the bath being between 25° C. and 900° C.; and
eliminating residues of molten oxides remaining on surfaces of the ferrous alloy sheet at an exit of the bath.

2. The thermal treatment process according to claim 1 , wherein the temperature of the ferrous alloy sheet when the sheet enters the bath is lower than the temperature of the bath, resulting in a heating the ferrous alloy sheet.

3. The thermal treatment process according to claim 2 , wherein the ferrous alloy sheet is pre-heated prior to immersion into the molten oxides bath.

4. The thermal treatment process according to claim 2 , wherein the temperature of the molten oxides bath is within a range of 600° C. to 900° C.

5. The thermal treatment process according to claim 4 , wherein the temperature of the molten oxides bath is from 700 to 850° C.

6. The thermal treatment process according to claim 1 , wherein the ferrous alloy sheet is cooled after having been heated in the molten oxides bath.

7. The thermal treatment process according to claim 2 , wherein the molten oxides bath initially comprises:
45% w≤B 2 O 3 ≤90% w;
10% w≤Li 2 O≤55% w; and
0% w≤Na 2 O≤10% w.

8. The thermal treatment process according to claim 7 , wherein the Na 2 O is at least partially replaced by at least one of: CaO, K 2 O, SiO 2 , P 2 O 5 or MnO 2 .

9. The thermal treatment process according to claim 7 , wherein the molten oxides bath initially comprises 45% w≤B 2 O 3 ≤55% w and 40% w≤LiO 2 ≤50% w.

10. The thermal treatment process according to claim 1 , wherein the temperature of the ferrous alloy sheet when the sheet enters the bath is higher than the temperature of the bath, resulting in a cooling of the ferrous alloy sheet.

11. The thermal treatment process according to claim 10 , wherein the temperature of the molten oxides bath is from 600° C. to 700° C.

12. A thermal treatment process according to claim 10 , wherein the molten oxides bath initially comprises:
45% w≤B 2 O 3 ≤70% w;
30% w≤Li 2 O≤55% w; and
10% w≤Na 2 O≤20% w.

13. The thermal treatment process according to claim 12 , wherein Na 2 O is at least partially replaced by at least one of: CaO, K 2 O, SiO 2 , P 2 O 5 or MnO 2 .

14. The thermal treatment process according to claim 6 , wherein the cooling step is performed using a process where the temperature of the ferrous alloy sheet when the sheet enters the bath is higher than the temperature of the bath, resulting in a cooling of the ferrous alloy sheet.

15. The thermal treatment process according to claim 1 , wherein the ferrous alloy sheet is subjected to a coating step.

16. The thermal treatment process according to claim 1 , wherein the ferrous alloy sheet is a steel sheet.

17. The thermal treatment process according to claim 1 , wherein the molten oxides bath has a viscosity lower than 2·10 −1 Pa·s.

18. A device for implementing the thermal treatment process according to claim 1 , comprising:
a molten oxides bath having a viscosity lower than 3·10 −1 Pa·s, a surface of the bath being in contact with a non-oxidizing atmosphere and the molten oxides being inert towards iron; and
an elimination device for eliminating residues of molten oxides remaining on surfaces of the ferrous alloy sheet at an exit of the bath.

19. The device according to claim 18 , comprising a heating module for preheating the ferrous alloy sheet located upstream the molten oxides bath.

20. The device according to claim 18 , comprising a coating module for coating the ferrous alloy sheet located downstream the molten oxides bath.

21. The device according to claim 20 , comprising a cooling module for cooling the ferrous alloy sheet located between the molten oxides bath and the coater.

22. The device according to claim 18 , wherein said molten oxides bath has a viscosity lower than 2·10 −2 Pa·s.

23. The device according to claim 19 , wherein the heating module is an induction furnace.

24. The device according to claim 20 , wherein the coating module is a bath.

Assignees

• Arcelormittal

Inventors

• Larnicol Maiwenn Tifenn Soazig
• Bordignon Michel Roger Louis
• Vanden Eynde Xavier Marc Jacques Edmond Robert
• Farinha Ana Isabel
• Gerkens Pascal
• Noville Jean-Francois
• Smal Julien Christopher Michel

Classifications

• C21D9/46 Primary

  for sheet metals · CPC title

• C23C22/00

  Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals · CPC title

• C21D1/70

  while heating or quenching · CPC title

• C21D1/63

  for bath quenching · CPC title

• C21D1/607

  Molten salts · CPC title