Production of products with favourable GHG emission reductions from cellulosic feedstocks

Patent metadata

Field	Value
Publication number	US-10428353-B2
Application number	US-201916284379-A
Country	US
Kind code	B2
Filing date	Feb 25, 2019
Priority date	Mar 6, 2014
Publication date	Oct 1, 2019
Grant date	Oct 1, 2019

Abstract

The present invention provides a process for producing one or more products for use as a transportation or heating fuel. In various embodiments the process comprises treating a cellulosic feedstock in one or more processing steps that release extractives from the feedstock. A solids-liquid separation is subsequently conducted on the process stream comprising the extractives and solids. An aqueous stream comprising one or more of the extractives may be fed to an anaerobic digester to produce crude biogas from which one or more impurities may optionally be removed. In various embodiments the process further comprises providing a solids stream to a thermal process. A product produced or derived from the thermal process may displace a product made from fossil fuel. One or more products obtained or derived from at least one of the foregoing process steps are provided for use as a transportation or heating fuel. In various embodiments the process enables advantaged fuel credit generation.

First claim

The invention claimed is:

1. A process for producing a transportation or heating fuel comprising the steps of:
(i) treating a cellulosic feedstock in one or more processing steps that release extractives comprising acetic acid, acetate or a combination thereof from the feedstock;
(ii) conducting a solids-liquid separation on a process stream comprising the extractives and solids, thereby producing an aqueous stream comprising the extractives and a solids stream comprising insoluble components;
(iii) feeding at least a portion of the aqueous stream comprising one or more of the extractives to an anaerobic digester to produce a crude biogas that comprises carbon dioxide;
(iv) removing at least 80 wt % of the carbon dioxide present in the crude biogas to produce a purified biogas;
(v) carrying out or causing one or more parties to carry out a process comprising subjecting solids from at least one stream selected from the solids stream comprising the insoluble components and a stream derived therefrom to a thermal process to produce a fuel or fuel intermediate;
(vi) introducing the purified biogas produced in step (iv) to a pipeline and causing withdrawal of an amount of methane from said pipeline corresponding to an amount of the purified biogas introduced to the pipeline;
(vii) providing one or more products obtained or derived from step (v), step (vi) or a combination thereof for use as a transportation or heating fuel; and
(viii) generating or causing generation of a renewable fuel credit with respect to said one or more products.

2. The process of claim 1 , wherein the one or more products are produced or derived from the methane withdrawn from the pipeline.

3. The process of claim 1 , wherein the cellulosic feedstock is straw, stover or an energy crop.

4. The process of claim 1 , comprising obtaining a liquid stream from the anaerobic digester and recirculating the liquid stream or a portion thereof to the anaerobic digester or to a stage upstream of the anaerobic digester.

5. The process of claim 1 , comprising:
(a) obtaining a liquid stream from the anaerobic digester and introducing the liquid stream or a portion thereof to the anaerobic digester or to a stage upstream of the anaerobic digester; and
(b) conducting a second solids-liquid separation on the solids stream comprising the insoluble components or a stream derived therefrom to produce a second aqueous stream and introducing the second aqueous stream or a portion thereof to the digester or to a stage upstream of the digester.

6. The process of claim 1 , comprising obtaining a slurry comprising microorganisms from the anaerobic digester, conducting a solids-liquid separation on said slurry to obtain a concentrated slurry of microorganisms and introducing the concentrated slurry of microorganisms to the anaerobic digester or to a stage upstream of the anaerobic digester.

7. The process of claim 1 , wherein the aqueous stream comprising one or more of the extractives or the portion of said aqueous stream further comprises sulfur and wherein said process further comprises:
(a) converting the sulfur or a portion thereof to gaseous hydrogen sulfide in said digester;
(b) treating the gaseous hydrogen sulfide to produce elemental sulfur or an oxide of sulfur;
(c) recovering an acid comprising sulfuric acid, sulfurous acid, sulfur dioxide or a combination thereof from the elemental sulfur or oxide of sulfur; and
(d) using the recovered acid in the process as a catalyst or for neutralizing alkali.

8. The process of claim 1 , wherein the solids stream comprising the insoluble components comprises densified solids.

9. The process of claim 1 , wherein the solids stream comprises lignin.

10. The process of claim 9 , wherein the thermal process comprises gasification.

11. The process of claim 9 , wherein the thermal process comprises pyrolysis.

12. The process of claim 11 , wherein the fuel or fuel intermediate produced in step (v) comprises pyrolysis oil.

13. The process of claim 9 , wherein the fuel or fuel intermediate produced in step (v) comprises syngas, hydrogen, methane, or pyrolysis oil.

14. The process of claim 9 , wherein the fuel or fuel intermediate produced in step (v) comprises dimethyl ether, methanol, ethanol, or liquid hydrocarbons.

15. The process of claim 9 , wherein the fuel or fuel intermediate produced in step (v) comprises gasoline.

16. The process of claim 9 , wherein the fuel or fuel intermediate comprises pyrolysis oil.

17. The process of claim 9 , wherein the fuel or fuel intermediate comprises diesel.

18. A process for producing a transportation or heating fuel comprising the steps of:
(i) treating a cellulosic feedstock in one or more processing steps that release extractives comprising acetic acid, acetate or a combination thereof from the feedstock;
(ii) conducting a solids-liquid separation on a process stream comprising the extractives and solids, thereby producing an aqueous stream comprising the extractives and a solids stream comprising lignin;
(iii) feeding at least a portion of the aqueous stream comprising one or more of the extractives to an anaerobic digester to produce a crude biogas that comprises carbon dioxide;
(iv) removing at least a portion of the carbon dioxide present in the crude biogas to produce a purified biogas;
(v) carrying out or causing one or more parties to carry out a process comprising subjecting solids from at least one stream selected from the solids stream comprising the lignin and a stream derived therefrom to a thermal process to produce a fuel or fuel intermediate;
(vi) introducing the purified biogas produced in step (iv) to a pipeline and causing withdrawal of an amount of methane from said pipeline corresponding to an amount of the purified biogas introduced to the pipeline;
(vii) providing one or more products obtained or derived from step (v), step (vi) or a combination thereof for use as a transportation or heating fuel; and
(viii) generating or causing generation of a renewable fuel credit with respect to said one or more products.

Assignees

• Iogen Corp

Inventors

• Foody Patrick J

Classifications

• C01B3/34

  by reaction of hydrocarbons with gasifying agents · CPC title

• C10J3/82

  Gas withdrawal means · CPC title

• C01B2203/0283

  containing a CO-shift step, i.e. a water gas shift step · CPC title

• C10J2300/1659

  to liquid hydrocarbons · CPC title

• C10J2300/0916

  Biomass · CPC title