Method for producing acetic acid

Patent metadata

Field	Value
Publication number	US-10428004-B2
Application number	US-201715540195-A
Country	US
Kind code	B2
Filing date	May 25, 2017
Priority date	Jan 18, 2017
Publication date	Oct 1, 2019
Grant date	Oct 1, 2019

Abstract

It is intended to provide a method capable of suppressing distillation apparatus corrosion as a method for producing acetic acid, comprising the step of distilling a crude acetic acid solution containing acetic acid and an impurity having a higher boiling point than that of acetic acid to purify the acetic acid. The method for producing acetic acid of the present invention comprises the step described above, wherein the distillation of the crude acetic acid solution is performed under a condition involving a distillation column bottom temperature of not more than 165° C. An acetic acid concentration in the crude acetic acid solution to be subjected to the distillation is preferably not less than 90 mass %. Examples of the impurity having a higher boiling point than that of acetic acid include acetate salts, acetic anhydride, and propionic acid. A column bottom pressure of the distillation column is preferably less than 0.255 MPaG.

First claim

The invention claimed is:

1. A method for producing acetic acid, comprising distilling a crude acetic acid solution containing acetic acid and an impurity having a higher boiling point than that of acetic acid to purify the acetic acid, wherein the method comprises
carbonylating methanol with carbon monoxide to produce acetic acid,
evaporating a reaction mixture obtained by the carbonylation to separate into a vapor stream and a residual liquid stream,
removing a lower boiling point component by distillation to separate the vapor stream into an overhead stream rich in lower boiling point component and a first acetic acid stream rich in acetic acid,
dehydrating the first acetic acid stream by distillation to separate into a second acetic acid stream more enriched with acetic acid than the first acetic acid stream, and a vapor of an overhead stream containing a larger amount of a component having a lower boiling point than that of acetic acid as compared with the second acetic acid stream, and
removing a higher boiling point component by distillation to separate the second acetic acid stream into a vapor as an overhead stream containing a larger amount of a component having a lower boiling point than that of acetic acid as compared with a bottom fraction, the bottom fraction containing a larger amount of a component having a higher boiling point than that of acetic acid as compared with the overhead stream, and a third acetic acid stream more enriched with acetic acid than the second acetic acid stream; and
wherein the distillation of the second acetic acid stream is performed under a condition involving a column bottom temperature of a distillation column of 70 to 165° C. and a column bottom pressure of the distillation column of not less than 0.01 MPaG and less than 0.255 MPaG, and
the bottom fraction of the distillation column has an acetate salt concentration of not more than 34% by mass, an acetic anhydride concentration of not more than 90% by mass, and a propionic acid concentration of not more than 90% by mass.

2. The method for producing acetic acid according to claim 1 , wherein an acetic acid concentration in the second acetic acid stream is not less than 90% by mass.

3. The method for producing acetic acid according to claim 1 , wherein the impurity having a higher boiling point than that of acetic acid comprises at least one compound selected from the group consisting of an acetate salt, acetic anhydride, and propionic acid.

4. The method for producing acetic acid according to claim 1 , further comprising distilling the acetic acid stream to purify the acetic acid, comprising at least one distillation in which an acetic acid concentration in the crude acetic acid solution to be subjected to the distillation is not less than 97% by mass, and in all distillations, the distillation of the crude acetic acid solution is performed under a condition involving a column bottom temperature of the distillation column of not more than 165° C.

5. The method for producing acetic acid according to claim 1 , wherein a material for the distillation column is at least one material selected from the group consisting of a nickel-based alloy, stainless steel, aluminum, and titanium.

6. The method for producing acetic acid according to claim 1 , wherein potassium hydroxide is fed or added to the first acetic acid stream via a potassium hydroxide introduction line.

7. The method for producing acetic acid according to claim 1 , wherein the distillation of the first acetic acid stream is performed under a condition involving a column bottom temperature of a distillation column of not more than 165° C.

8. The method for producing acetic acid according to claim 1 , wherein potassium hydroxide is fed or added to the second acetic acid stream via a potassium hydroxide introduction line.

9. The method for producing acetic acid according to claim 1 , wherein the distillation of the second acetic acid stream is performed under a condition involving a column bottom temperature of a distillation column of not more than 155° C.

10. The method for producing acetic acid according to claim 1 , wherein the acetate salt concentration in the bottom fraction is 1 ppm by mass to 34% by mass.

11. The method for producing acetic acid according to claim 1 , wherein the acetate salt concentration in the bottom fraction is 100 ppm by mass to 25% by mass.

12. The method for producing acetic acid according to claim 1 , wherein the acetate salt concentration in the bottom fraction is lowered by decreasing the amount of an alkali added for use in the neutralization of hydrogen iodide.

13. The method for producing acetic acid according to claim 1 , wherein the acetic anhydride concentration in the bottom fraction is 10 ppm by mass to 74% by mass.

14. The method for producing acetic acid according to claim 1 , wherein the acetic anhydride concentration in the bottom fraction is lowered by hydrolyzing the acetic anhydride by the addition of water into piping or an apparatus positioned upstream of the distillation column, or into the distillation column.

15. The method for producing acetic acid according to claim 1 , wherein the propionic acid concentration in the bottom fraction is 100 ppm by mass to 91% by mass.

16. The method for producing acetic acid according to claim 1 , further comprising introducing the third acetic acid stream to an ion exchange resin column so that an alkyl iodide in the third acetic acid stream is removed to obtain a fourth acetic acid stream.

17. The method for producing acetic acid according to claim 16 , further comprising distilling the fourth acetic acid stream under a condition involving a column bottom temperature of a product column of not more than 165° C. to obtain purified acetic acid.

18. The method for producing acetic acid according to claim 17 , wherein an acetate salt concentration in a column bottom fraction of the product column is 0.1 ppb by mass to 1% by mass.

19. The method for producing acetic acid according to claim 17 , wherein an acetic anhydride concentration in the column bottom fraction of the product column is 0.1 ppm by mass to 60% by mass.

20. The method for producing acetic acid according to claim 17 , wherein a propionic acid concentration in the column bottom fraction of the product column is 1 ppm by mass to 10% by mass.

Assignees

• Daicel Corp

Inventors

• Shimizu Masahiko
• Mizutani Yoshihisa

Classifications

• B01D15/361

  Ion-exchange · CPC title

• C07C51/12 Primary

  on an oxygen-containing group in organic compounds, e.g. alcohols · CPC title

• C07C51/44

  by distillation · CPC title

• B01D3/009 Primary

  in combination with chemical reactions · CPC title

• B01D3/143

  by two or more of a fractionation, separation or rectification step · CPC title