Apparatus and system for swing adsorption processes

Patent metadata

Field	Value
Publication number	US-10427089-B2
Application number	US-201715496510-A
Country	US
Kind code	B2
Filing date	Apr 25, 2017
Priority date	May 31, 2016
Publication date	Oct 1, 2019
Grant date	Oct 1, 2019

Abstract

Provided are apparatus and systems for performing a swing adsorption process. This swing adsorption process may involve performing a startup mode process prior to beginning a normal operation mode process to remove contaminants from a gaseous feed stream. The startup mode process may be utilized for swing adsorption processes, such as TSA and/or PSA, which are utilized to remove one or more contaminants from a gaseous feed stream.

First claim

What is claimed is:

1. A process for removing contaminants from a gaseous feed stream with a swing adsorption process, the process comprising:
passing a gaseous feed stream to a swing adsorption process that comprises a plurality of adsorbent bed units, each of the adsorbent bed units performs a swing adsorption cycle that includes an adsorption step and a regeneration step; wherein the swing adsorption cycle comprises:
performing a first bed adsorption step for a first adsorbent bed unit of the plurality of adsorbent bed units that comprises passing a gaseous feed stream through the first adsorbent bed unit having a first adsorbent bed to separate one or more contaminants from the gaseous feed stream to form a first product stream; and
performing a second bed regeneration step for a second adsorbent bed unit of the plurality of adsorbent bed units that comprises passing at least a portion of the first product stream through the second adsorbent bed unit having a second adsorbent bed to separate one or more contaminants from the second adsorbent bed to form a first purge product stream;

wherein the process further comprises mixing a slip stream from a downstream process with the at least a portion of the first product stream prior to performing the second bed regeneration step and adjusting the amount of the at least a portion of the first product stream utilized in the second bed regeneration step based on the amount of the slip stream from the downstream process.

2. The process of claim 1 , further comprising:
determining whether the first product stream is within a specification for a contaminant;
if the first product stream is within the specification, passing at least a portion of the first product stream to the downstream process;
if the first product stream is not within the specification, performing a regeneration step for the first adsorbent bed unit that comprises passing a portion of a second product stream through the first adsorbent bed unit to separate one or more contaminants from the first adsorbent bed to form a second purge product stream, wherein the second product stream is provided from another of the plurality of adsorbent bed units; and
repeating the adsorbent step for the first adsorbent bed unit.

3. The process of claim 1 , further comprising heating the at least a portion of the first product stream prior to passing the at least the portion of the first product stream through the second adsorbent bed unit, wherein the at least a portion of the first product stream is heated to a temperature in the range between a temperature in the range between 450° F. and the gaseous feed stream temperature.

4. The process of claim 1 , further comprising separating one or more contaminants from the at least the portion of the first product stream prior to passing the at least the portion of the first product stream through the second adsorbent bed unit.

5. The process of claim 4 , wherein the separating further comprises reducing the pressure of the at least the portion of the first product stream by at least 10% relative to the pressure of the stream prior to the separating the one or more contaminants.

6. The process of claim 1 , further comprising heating the purge product stream, wherein the purge product stream is heated to a temperature 10° F. greater than the dew point of the purge product stream.

7. The process of claim 6 , further comprising:
separating one or more contaminants from the purge product stream to form conditioned purge product stream; and
mixing the conditioned purge product stream with the gaseous feed stream upstream of the swing adsorption process.

8. The process of claim 1 , wherein the cycle duration is for a period greater than 1 second and less than 2400 seconds.

9. The process of claim 1 , wherein the gaseous feed stream is a hydrocarbon containing stream having greater than one volume percent hydrocarbons based on the total volume of the feed stream.

10. The process of claim 1 , wherein the gaseous feed stream comprises hydrocarbons and CO 2 , wherein the CO 2 content is in the range of two hundred parts per million volume to less than or equal to about 2% volume of the gaseous feed stream.

11. The process of claim 1 , wherein the swing adsorption process is configured to lower the carbon dioxide (CO 2 ) level to less than 50 parts per million.

12. The process of claim 1 , wherein the gaseous feed stream comprises hydrocarbons and H 2 O, wherein the H 2 O is in the range of 0.2 parts per million volume to saturation levels in the gaseous feed stream.

13. The process of claim 1 , wherein the gaseous feed stream comprises hydrocarbons and H 2 O, wherein the H 2 O is in the range of 100 parts per million volume to 1500 parts per million volume.

14. The process of claim 1 , wherein the downstream process is a liquefied natural gas (LNG) process that comprises an LNG process unit; and
separating a flash fuel stream from the LNG process unit and utilizing the flash fuel stream from the LNG process unit as at least a portion of the slip stream.

15. The process of claim 1 , wherein the downstream process is a cryogenic natural gas liquid recovery (NGL) process having a NGL process unit; and further comprising separating an overhead stream from the NGL process unit and utilizing the overhead stream from the NGL process unit as at least a portion of the purge slip stream.

16. The process of claim 1 , wherein the cycle duration is greater than 2 seconds and less than 800 seconds.

17. The process of claim 1 , further comprising providing an external gas stream and mixing the external gas stream with the portion of the first product stream, wherein the external gas stream is a nitrogen containing stream having greater than one volume percent nitrogen based on the total volume of the external stream.

18. The process of claim 1 wherein the at least a portion of the first product stream is greater than 50% of the product stream.

19. The process of of claim 1 wherein the at least a portion of the first product stream is greater than 75% of the product stream.

Assignees

• Nagavarapu Ananda Krishna
• Barnes William
• Marshall Bennett D
• Kelley Bruce T
• Johnson Robert A
• Exxonmobil Upstream Res Co

Inventors

• Nagavarapu Ananda Krishna
• Barnes William
• Marshall Bennett D
• Kelley Bruce T
• Johnson Robert A

Classifications

• B01D53/0462 Primary

  Temperature swing adsorption · CPC title

• B01D2257/504

  Carbon dioxide · CPC title

• B01D2256/245

  Methane · CPC title

• B01D2259/4068

  using more than ten beds · CPC title

• B01D2257/80

  Water · CPC title