Organic electrochemical transistors with tunable threshold voltage

Patent metadata

Field	Value
Publication number	US-10424751-B2
Application number	US-201715801125-A
Country	US
Kind code	B2
Filing date	Nov 1, 2017
Priority date	Nov 1, 2017
Publication date	Sep 24, 2019
Grant date	Sep 24, 2019

Abstract

One embodiment provides electronic device, which can include at least two organic electrochemical transistors (OECTs). A respective OECT includes a conductive channel, a gate electrically coupled to the conductive channel via a first electrolyte, and source and drain electrodes separated from each other by the conductive channel. The electrochemical potentials of redox-couples of the at least two organic electrochemical transistors are different, thereby resulting in the at least two organic electrochemical transistors having different threshold voltages. An alternative embodiment can provide an organic electrochemical transistor (OECT). The OECT can include a conductive channel, a gate electrically coupled to the conductive channel via a first electrolyte, and source and drain electrodes separated from each other by the conductive channel. The gate can include a conductive current collector and at least one redox-couple. An electrochemical potential associated with the redox-couple varies in response to a stimulus.

First claim

What is claimed is:

1. An electronic device, comprising:
at least two organic electrochemical transistors, wherein a respective organic electrochemical transistor comprises:
a conductive channel;
a gate electrically coupled to the conductive channel via a first electrolyte, wherein the gate comprises a conductive current collector and at least one redox-couple having a predetermined electrochemical potential; and
source and drain electrodes separated from each other by the conductive channel;

wherein electrochemical potentials of redox-couples of the at least two organic electrochemical transistors are different, thereby resulting in the at least two organic electrochemical transistors having different threshold voltages.

2. The electronic device of claim 1 , wherein the channel comprises one of: a conductive polymer, a conductive inorganic material, and a small-molecule material, and wherein the conductive polymer comprises poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS).

3. The electronic device of claim 1 , wherein the at least one redox-couple is selected from a group consisting of:
Fe(CN) 6 3−/4− ,
I − /I 3 − ,
viologen and its derivatives,
indigo and its derivatives,
Ag/AgCl,
Prussian blue,
polyaniline,
PEDOT,
Cu/Cu 2+ , and
ferrocene and its derivatives.

4. The electronic device of claim 1 , wherein the at least one redox-couple is dissolved in a second electrolyte.

5. The electronic device of claim 4 , further comprising a membrane configured to separate the second electrolyte from the first electrolyte, thereby preventing the at least one redox-couple from reacting with the conductive channel.

6. The electronic device of claim 5 , wherein the membrane comprises one or more of:
a porous glass frit,
an ion-selective membrane,
an ion-conductive glass,
a polymer membrane, and
an ionically conductive membrane.

7. The electronic device of claim 1 , wherein the first electrolyte comprises one or more of:
water and a salt dissolved in the water,
an organic solvent and a salt dissolved in the organic solvent, and
an ionic liquid.

8. The electronic device of claim 1 , wherein at least one member of the at least one redox-couple is in solid form.

9. The electronic device of claim 8 , wherein the solid redox-couple comprises:
an electrochemically active polymer,
an insoluble organic redox-couple,
an insoluble inorganic redox couple, or
an intercalation material.

10. The electronic device of claim 1 , wherein the gate comprises at least two redox-couples having different electrochemical potentials.

11. An organic electrochemical transistor, comprising:
a conductive channel;
a gate electrically coupled to the conductive channel via a first electrolyte, wherein the gate comprises a conductive current collector and at least one redox-couple, wherein an electrochemical potential associated with the at least one redox-couple varies in response to a stimulus, and wherein the at least one redox-couple is dissolved in a second electrolyte; and
source and drain electrodes separated from each other by the conductive channel.

12. The organic electrochemical transistor of claim 11 , wherein the stimulus comprises one of:
a temperature change,
a change in concentration of a chemical substance,
a change in concentration of a biological substance,
a change in pH level,
a change in humidity,
a change in pressure, and
a change in heat flow.

13. The organic electrochemical transistor of claim 11 , wherein the channel comprises one of: a conductive polymer, a conductive inorganic material, and a small-molecule material, and wherein the conductive polymer comprises poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS).

14. The organic electrochemical transistor of claim 11 , wherein the at least one redox-couple is selected from a group consisting of:
Fe(CN) 6 3−/4− ,
I − /I 3 − ,
viologen and its derivatives,
indigo and its derivatives,
Ag/AgCl,
Prussian blue,
polyaniline,
PEDOT,
Cu/Cu 2+ , and
ferrocene and its derivatives.

15. The organic electrochemical transistor of claim 11 , further comprising a membrane configured to separate the second electrolyte from the first electrolyte, thereby preventing the at least one redox-couple from reacting with the conductive channel.

16. The organic electrochemical transistor of claim 15 , wherein the membrane comprises one or more of:
a porous glass frit,
an ion-selective membrane,
an ion-conductive glass,
a polymer membrane, and
an ionically conductive membrane.

17. The organic electrochemical transistor of claim 11 , wherein the first electrolyte comprises one or more of:
water and a salt dissolved in the water,
an organic solvent and a salt dissolved in the organic solvent, and
an ionic liquid.

18. The organic electrochemical transistor of claim 11 , wherein at least one member of the redox-couple is in solid form, and wherein the at least one solid redox-couple comprises:
an electrochemically active polymer,
an insoluble organic redox-couple,
an insoluble inorganic redox couple, or
an intercalation material.

19. The organic electrochemical transistor of claim 11 , wherein the gate comprises at least two redox-couples having different electrochemical potentials.

Assignees

• Palo Alto Res Ct Inc

Inventors

• Doris Sean E
• Pierre Adrien

Classifications

• H01L51/0035

  Electricity · mapped topic

• H01L51/0508 Primary

  Electricity · mapped topic

• H01L51/0037

  Electricity · mapped topic

• H10K85/1135

  Polyethylene dioxythiophene [PEDOT]; Derivatives thereof · CPC title

• H10K10/46 Primary

  Field-effect transistors, e.g. organic thin-film transistors [OTFT] (H10K10/43 takes precedence) · CPC title