Method of preparing irradiation targets for radioisotope production and irradiation target

Patent metadata

Field	Value
Publication number	US-10424417-B2
Application number	US-201515545906-A
Country	US
Kind code	B2
Filing date	Jan 29, 2015
Priority date	Jan 29, 2015
Publication date	Sep 24, 2019
Grant date	Sep 24, 2019

Abstract

Irradiation targets, useful in preparing radioisotopes by exposure of the target to a neutron flux in instrumentation tubes of a nuclear power reactor, are prepared by a method comprising the steps of:
providing a powder of an oxide of a rare earth metal having a purity of greater than 99%; consolidating the powder in a mold to form a round green body having a green density of at least 50 percent of the theoretical density; and sintering the spherical green body in solid phase at a temperature of at least 70 percent of a solidus temperature of the rare earth metal oxide powder to form a round sintered rare earth metal oxide target having a sintered density of at least 80 percent of the theoretical density.

First claim

The invention claimed is:

1. A method for preparing irradiation targets for radioisotope production in instrumentation tubes of a nuclear power reactor, the method comprising the steps of:
providing a powder of an oxide of a rare earth metal having a purity of greater than 99%;
consolidating the powder in a mold to form a substantially spherical green body having a green density of at least 50 percent of the theoretical density; and
sintering the green body in an oxidizing atmosphere in solid phase at a temperature of at least 70 percent of a solidus temperature of the rare earth metal oxide powder to form a substantially spherical sintered rare earth metal oxide target having a sintered density of at least 80 percent of the theoretical density.

2. The method of claim 1 wherein the rare earth metal is selected from the group consisting of Nd, Sm, Y, Dy, Ho, Er, Tm, Yb and Lu.

3. The method of claim 2 wherein the rare earth metal is Sm, Y, Ho or Yb.

4. The method of claim 1 wherein the powder of the rare earth metal oxide has a purity of greater than 99.9 percent.

5. The method of claim 1 wherein the rare earth metal is monoisotopic.

6. The method of claim 1 wherein the powder is consolidated at a pressure in a range of between 1 and 600 MPa.

7. The method of claim 1 wherein the green density is in a range between 55 and 65 percent of the theoretical density.

8. The method of claim 1 wherein the sintering temperature is between 70 and 80 percent of the solidus temperature of the rare earth metal oxide.

9. The method of claim 1 wherein the sintering temperature is in a range of from 1650 to 1800° C.

10. The method of claim 1 wherein the green body is sintered for a time period of from 4 to 24 hours.

11. The method of claim 1 wherein the green body is sintered under atmospheric pressure.

12. The method of claim 1 wherein the green body is sintered in an atmosphere consisting of nitrogen and oxygen.

13. The method of claim 1 wherein the sintered target has a porosity of less than 10%.

14. The method of claim 1 wherein the sintered target has a diameter in a range of from 1 to 5 mm.

15. A sintered rare earth metal oxide target obtained by the method according to claim 1 , wherein the sintered target is substantially spherical and has a density of at least 80 percent of the theoretical density, and wherein the rare earth metal oxide has a purity of greater than 99% wherein the sintered rare oxide target is resistant to a pneumatic transport pressure of 10 bar and an impact velocity of 10 m/s.

16. A method for producing radioisotopes wherein the sintered rare earth metal oxide target of claim 15 is inserted in an instrumentation tube of a nuclear power reactor and exposed to neutron flux when in energy producing operation.

17. The method of claim 16 wherein the rare earth metal oxide is ytterbium ytterbia and the radioisotope is Lu-177.

Assignees

• Framatome Gmbh

Inventors

• Schuster Beatrice
• Bathelt Robert
• Goesswein Karl

Classifications

• H05H6/00 Primary

  Targets for producing nuclear reactions (supports for targets or objects to be irradiated G21K5/08 {; preparation of tritium C01B4/00; targets, e.g. pellets for fusion reactions by laser or charged particles beam injection H05H1/22}) · CPC title

• G21G1/02 Primary

  in nuclear reactors (by thermonuclear reactions G21B; conversion of nuclear fuel G21C) · CPC title