Amphiphilic magnetic nanoparticles and aggregates to remove hydrocarbons and metal ions and synthesis thereof

Patent metadata

Field	Value
Publication number	US-10418159-B2
Application number	US-201515312194-A
Country	US
Kind code	B2
Filing date	May 18, 2015
Priority date	May 20, 2014
Publication date	Sep 17, 2019
Grant date	Sep 17, 2019

Abstract

The present invention relates to a magnetic nanoparticle comprising: a) a core containing a ferromagnetic material; b) an outer coating containing a mixture of a lipophilic compound and a hydrophilic compound. The outer coating of the above particle makes the nanoparticle stable in water and, simultaneously, capable of adsorbing/emulsifying large amounts of hydrophobic/lipophilic compounds. The present invention further relates to a process for the preparation of the above-mentioned particles as well as their use in the removal of hydrocarbons from solid or liquid environments and metal ions from contaminated water (wastewater).

First claim

The invention claimed is:

1. Magnetic nanoparticle comprising:
a core containing a ferromagnetic material, wherein the core has a surface that is functionalized with an outer coating comprising
at least one lipophilic compound and at least one hydrophilic compound, each of which is covalently bonded to the surface and randomly distributed on it to form, respectively, lipophilic and hydrophilic islands wherein said at least one lipophilic compound and said at least one hydrophilic compound are present in the outer coating in a molar ratio comprised between 1:0.1 and 1:10.

2. Nanoparticle according to claim 1 , wherein said ferromagnetic material is selected from magnetite, maghemite, barium ferrite, cobalt ferrite, nickel ferrite, manganese ferrite, strontium ferrite, or zinc ferrite.

3. Nanoparticle according to claim 1 , wherein said at least one lipophilic compound is selected from palmitoleic acid, oleic acid, erucic acid, linoleic acid, linolenic acid, arachidonic acid, and ricinoleic acid.

4. Nanoparticle according to claim 1 , wherein said at least one lipophilic compound and said at least one hydrophilic compound are present in the outer coating in a molar ratio comprised between 1:0.8 and 1:1.5.

5. Nanoparticle according to claim 4 , wherein said at least one lipophilic compound and said at least one hydrophilic compound are present in the outer coating in a molar ratio of about 1:1.

6. Nanoparticle according to claim 1 , wherein said at least one hydrophilic compound is selected from a hydrophilic carboxylic acid or an alkaline or alkaline earth salt of a fatty acid containing a sulfonate group.

7. Nanoparticle according to claim 6 , wherein said hydrophilic carboxylic acid is selected from methacrylic acid or a polymer thereof, acrylic acid or a polymer thereof, citric acid, adipic acid, malic acid, ascorbic acid, oxalic acid, malonic acid, succinic acid and fumaric acid.

8. Nanoparticle according to claim 6 , wherein said alkaline salt of a fatty acid containing a sulfonate group is selected from a sodium or potassium salt of sulfonated palmitoleic acid, sulfonated oleic acid, sulfonated erucic acid, sulfonated linoleic acid, sulfonated linolenic acid, sulfonated arachidonic acid, and sulfonated ricinoleic acid.

9. Nanoparticle according to claim 6 , wherein said alkaline earth salt of a fatty acid containing a sulfonate group is selected from a calcium or magnesium salt of sulfonated palmitoleic acid, sulfonated oleic acid, sulfonated erucic acid, sulfonated linoleic acid, sulfonated linolenic acid, sulfonated arachidonic acid, and sulfonated ricinoleic acid.

10. Aggregate containing nanoparticles according to claim 1 , having a particle size of less than 25 micron.

11. Process for preparing a magnetic nanoparticle, comprising the co-precipitation of an aqueous solution of Iron(II) and Iron (III) salts and a solution containing a lipophilic and a hydrophilic compound, wherein said lipophilic compound and said hydrophilic compound are present in said solution in a molar ratio comprised between 1:0.1 and 1:10, wherein said magnetic nanoparticle comprises: a core containing a ferromagnetic material, wherein the core has a surface that is functionalized with an outer coating comprising at least one lipophilic compound and at least one hydrophilic compound, each of which is covalently bonded to the surface and randomly distributed on it to form, respectively, lipophilic and hydrophilic islands.

12. Process according to claim 11 , wherein said lipophilic compound is selected from palmitoleic acid, oleic acid, erucic acid, linoleic acid, linolenic acid, arachidonic acid, and ricinoleic acid.

13. Process according to claim 11 , wherein said hydrophilic compound is selected from a hydrophilic carboxylic acid or an alkaline or alkaline earth salt of a fatty acid containing a sulfonate group.

14. Process according to claim 13 , wherein said hydrophilic carboxylic acid is selected from methacrylic acid or a polymer thereof, acrylic acid or a polymer thereof, citric acid, adipic acid, malic acid, ascorbic acid, oxalic acid, malonic acid, succinic acid, and fumaric acid.

15. Process according to claim 13 , wherein said alkaline salt of a fatty acid containing a sulfonate group is selected from a sodium or potassium salt of sulfonated palmitoleic acid, sulfonated oleic acid, sulfonated erucic acid, sulfonated linoleic acid, sulfonated linolenic acid, sulfonated arachidonic acid, and sulfonated ricinoleic acid.

16. Process according to claim 13 , wherein said alkaline earth salt of a fatty acid containing a sulfonate group is selected from a calcium or magnesium salt of sulfonated palmitoleic acid, sulfonated oleic acid, sulfonated erucic acid, sulfonated linoleic acid, sulfonated linolenic acid, sulfonated arachidonic acid, and sulfonated ricinoleic acid.

17. Process according to claim 11 , wherein said lipophilic compound and said hydrophilic compound are preset in said solution in a molar ratio comprised between 1:0.8 and 1:1.5.

18. Process according to claim 11 , wherein said co-precipitation takes place in a basic environment.

19. Method of removing hydrophobic or lipophilic compounds from solid or liquid environment with a nanoparticle according to claim 1 , said method comprising
dispersing said nanoparticle in said solid or liquid environment, said nanoparticle being capable of adsorbing hydrophobic or lipophilic compounds;
thereby removing said hydrophobic or lipophilic compounds from said solid or liquid environment.

20. Method according to claim 19 , wherein said hydrophobic or lipophilic compounds are selected from silicone oils, fluorinated compounds, and hydrocarbons.

21. Method of removing metals dissolved in contaminated water with a nanoparticle according to claim 1 , said method comprising:
dispersing said nanoparticle in said contaminated water, said nanoparticle being capable of adsorbing metals;
thereby removing said metals from said contaminated water.

22. Method according to claim 21 , wherein said metals are selected from chromium, iron, zinc, copper, arsenic and manganese.

23. Method according to claim 21 wherein said particles with respect to the contaminated water to be purified are present in a 1/10 ratio by weight.

Assignees

• Milano Politecnico

Inventors

• Moscatelli Davide
• Masi Maurizio
• Pesce Ruggiero Maria

Classifications

• B03C1/288

  disposed at the outer circumference of a recipient · CPC title

• B03C1/015

  by chemical treatment imparting magnetic properties to the material to be separated, e.g. roasting, reduction, oxidation · CPC title

• C02F2101/203

  Iron or iron compound · CPC title

• H01F1/0054 Primary

  Coated nanoparticles, e.g. nanoparticles coated with organic surfactant · CPC title

• C02F1/288

  using composite sorbents, e.g. coated, impregnated, multi-layered · CPC title