Electrode for an electrochemical gas sensor, manufacturing method for an electrode, and use of an electrode

Patent metadata

Field	Value
Publication number	US-10416108-B2
Application number	US-201515311340-A
Country	US
Kind code	B2
Filing date	May 13, 2015
Priority date	May 16, 2014
Publication date	Sep 17, 2019
Grant date	Sep 17, 2019

Abstract

An electrode ( 100 ) for an electrochemical gas sensor ( 1 ), wherein the electrode has a gas-permeable membrane ( 4 ). A graphene layer ( 3 ) is applied as an electrode material to the gas-permeable membrane ( 4 ). Such an electrode ( 1 ) is prepared, for example, by applying a dispersion of graphene or graphene oxide in a volatile liquid to the gas-permeable membrane and evaporating the volatile liquid.

First claim

The invention claimed is:

1. An electrochemical gas sensor comprising:
a sensor housing;
an auxiliary electrode disposed in the housing; and
electrochemical gas sensor electrode disposed in the housing, the electrochemical gas sensor electrode comprising:
a gas-permeable membrane forming a gas-permeable membrane layer of the electrochemical gas sensor electrode; and
a graphene layer applied on the gas-permeable membrane layer as an electrode material having a resistance lower than 10 kΩ and which is gas-permeable, wherein the graphene layer is applied to the gas-permeable membrane by a process comprising the steps of:
dispersing graphene powder in a volatile liquid to provide a graphene dispersion; and
applying the graphene dispersion to the gas-permeable membrane.

2. An electrochemical gas sensor in accordance with claim 1 , wherein the graphene layer is in the form of a multi-layer graphene.

3. An electrochemical gas sensor in accordance with claim 1 , wherein the process of applying the graphene to the gas-permeable membrane further comprises the step of evaporating the volatile liquid from the graphene dispersion applied to the gas-permeable membrane.

4. An electrochemical gas sensor in accordance with claim 1 , wherein the graphene layer applied to the gas-permeable membrane consists of reduced graphene oxide.

5. An electrochemical gas sensor in accordance with claim 1 , wherein the process of applying the graphene to the gas-permeable membrane further comprises the following steps:
preparing the gas-permeable membrane;
dispersing graphene oxide, as the graphene, in the volatile liquid to provide a graphene oxide dispersion as the graphene dispersion;
applying the graphene oxide dispersion to the gas-permeable membrane as a part of the step of applying the graphene dispersion to the gas-permeable membrane; and
treating the graphene oxide deposited on the gas-permeable membrane with a reducing agent such that the graphene layer consists of reduced graphene oxide.

6. An electrochemical gas sensor in accordance with claim 5 , wherein the reducing agent is selected from the group consisting of hydrazine, hydrogen iodide and mixtures containing hydrazine and hydrogen iodide.

7. An electrochemical gas sensor in accordance with claim 1 , wherein the process of applying the graphene to the gas-permeable membrane further comprises the following steps:
dispersing graphene oxide, as the graphene, in the volatile liquid to provide a graphene oxide dispersion as the graphene dispersion;
treating the graphene oxide dispersion with a reducing agent, so that the graphene oxide dispersion is at least partly converted into a reduced graphene oxide dispersion;
applying the reduced graphene oxide dispersion treated with the reducing agent to the gas-permeable membrane as a part of the step of applying the graphene dispersion to the gas-permeable membrane; and
evaporating the volatile liquid.

8. An electrochemical gas sensor in accordance with claim 7 , wherein the reducing agent is selected from the group consisting of hydrazine, hydrogen iodide and mixtures containing hydrazine and hydrogen iodide.

9. A method for preparing an electrode for an electrochemical sensor comprising a sensor housing, an auxiliary electrode and an electrochemical gas sensor electrode, the electrochemical gas sensor electrode comprising a gas-permeable membrane and a graphene layer applied as an electrode material to the gas-permeable membrane wherein the method comprises the following steps:
preparing a graphene dispersion or a graphene oxide-containing dispersion or both a graphene dispersion and a graphene oxide-containing dispersion with a volatile liquid as a dispersing agent;
applying the dispersion to a gas-permeable membrane; and,
evaporating the volatile liquid such that the graphene or the graphene oxide or both the graphene and the graphene oxide is deposited as a graphene or graphene oxide or both a graphene and graphene oxide layer on the gas-permeable membrane to provide the electrode material, applied to the gas-permeable membrane, with a resistance lower than 10 kΩ and which is gas-permeable.

10. A method in accordance with claim 9 , further comprising the step of treating the graphene oxide with a reducing agent wherein the reducing agent is used in the gaseous state or as a solution.

11. A method in accordance with claim 10 , wherein the reducing agent is selected from the group comprising hydrazine, hydrogen iodide and mixtures containing hydrazine and hydrogen iodide.

12. A method in accordance with claim 10 , wherein the step of treating the graphene oxide with a reducing agent occurs after the step of evaporating the volatile liquid.

13. A method in accordance with claim 10 , wherein the step of treating the graphene oxide with a reducing agent occurs prior to applying the dispersion to the gas-permeable membrane.

14. A method in accordance with claim 9 , further comprising measuring a gas with the electrochemical gas sensor.

15. A method in accordance with claim 14 , wherein the electrochemical gas sensor is a gas sensor determining Propofol.

16. A method in accordance with claim 14 , wherein the electrochemical gas sensor is a gas sensor determining chlorine dioxide.

17. An electrochemical gas sensor comprising at least one electrode comprising:
a gas-permeable membrane forming a gas-permeable membrane layer of the electrochemical gas sensor electrode; and
a graphene layer applied on the gas-permeable membrane layer as an electrode material having a resistance lower than 10 kΩ and which is gas-permeable, wherein the graphene layer is applied to the gas-permeable membrane by a process comprising the steps of:
dispersing graphene powder in a volatile liquid to provide a graphene dispersion; and
applying the graphene dispersion to the gas-permeable membrane.

18. An electrochemical gas sensor in accordance with claim 17 , wherein the process of applying the graphene to the gas-permeable membrane further comprises the steps of:
preparing the gas-permeable membrane;
dispersing graphene oxide, as the graphene, in the volatile liquid to provide a graphene oxide dispersion as the graphene dispersion;
applying the graphene oxide dispersion to the gas-permeable membrane as a part of the step of applying the graphene dispersion to the gas-permeable membrane; and
treating the graphene oxide deposited on the gas-permeable membrane with a reducing agent such that the graphene layer consists of reduced graphene oxide.

19. An electrochemical gas sensor in accordance with claim 18 , wherein the reducing agent is selected from the group consisting of hydrazine, hydrogen iodide and mixtures containing hydrazine and hydrogen iodide.

20. An electrochemical gas sensor in accordance with claim 17 , wherein the process of applying the graphene to the gas-permeable membrane further comprises the following steps:
dispersing graphene oxide, as the graphene, in the volatile liquid to provide a graphene oxide dispersion as the graphene dispersion;
treating the graphene oxide dispersion with a reducing agent, so that the graphene oxide dispersion is at least partly converted into a reduced graphene oxide dispersion;
applying the reduced graphene oxide dispersion treated with the reducing agent to the gas-permeable membrane as a part of the step of applying the graphene dispersion to the gas-permeable membrane; and
evaporating the volatile liquid.

Assignees

• Draeger Safety Ag & Co Kgaa

Inventors

• Sommer Sabrina
• Mett Frank

Classifications

• G01N27/308 Primary

  at least partially made of carbon · CPC title

• G01N27/4045

  for gases other than oxygen · CPC title

• C01B32/194 Primary

  After-treatment · CPC title

• G01N27/304 Primary

  Gas permeable electrodes · CPC title

• H01M4/0404

  by coating on electrode collectors · CPC title