Photochemical reaction device, photochemical reaction method using same, and lactam production method using said method

Patent metadata

Field	Value
Publication number	US-10414724-B2
Application number	US-201515517424-A
Country	US
Kind code	B2
Filing date	Sep 17, 2015
Priority date	Oct 9, 2014
Publication date	Sep 17, 2019
Grant date	Sep 17, 2019

Abstract

Provided is a photochemical reaction device wherein two partitions formed from an optically transparent material are arranged apart from each other between a light source and a reaction liquid, and an optically transparent fluid introduction/discharge means for introducing an optically transparent fluid between the partitions and discharging the fluid and a state change detection means for detecting a change in the state of the optically transparent fluid at the discharge side of the optically transparent fluid introduction/discharge means are provided. Also provided are a photochemical reaction method that uses the photochemical reaction device and a lactam production method that uses the photochemical reaction method. The present invention prevents decreases in the performance of the light source even when the optically transparent material in the photochemical reaction device is damaged, and makes it possible to reliably prevent ignition even if the reaction liquid is a flammable liquid.

First claim

The invention claimed is:

1. A photochemical reaction method characterized by using a photochemical reaction device, wherein the photochemical reaction device comprises:
a light source comprising a light source module having a substrate mounted with a plurality of light emitting diodes inserted into a photochemical reactor in which a reaction liquid is contained or flown and served to a photochemical reaction by irradiating the light from said light source to said reaction liquid,
two partitions formed from an optically transparent material arranged apart from each other between said light source and said reaction liquid which is a flammable liquid,
an optically transparent fluid introduction/discharge means for introducing an optically transparent fluid between said partitions and discharging said fluid and a state change detection,
means for detecting a change in the state of said optically transparent fluid at the discharge side of said optically transparent fluid introduction/discharge means, and
said state change detection means comprises means for detecting a change in pressure or flow rate of said optically transparent fluid, and

wherein the photochemical reaction method comprises the steps of:
sealing an inert gas inside an inner partition of said two partitions at a condition of positive pressure; and
irradiating the light from said light source to said reaction liquid to perform the photochemical reaction.

2. The photochemical reaction method according to claim 1 , wherein at least the light emission of said light source is stopped when a value detected by said state change detection means deviates from a preset range.

3. The photochemical reaction method according to claim 2 , wherein a coolant introduction/discharge means for introducing and discharging a light source coolant into and from said light source module is provided, and when the light emission of said light source module is stopped, the introduction/discharge of the coolant controlled by said coolant introduction/discharge means is stopped and the introduction of said optically transparent fluid controlled by said optically transparent fluid introduction/discharge means is stopped.

4. The photochemical reaction method according to claim 1 , wherein said flammable liquid is a cycloalkane.

5. The photochemical reaction method according to claim 4 , wherein a cycloalkanone oxime is produced by performing photoirradiation to said cycloalkane and a photo nitrosating agent.

6. The photochemical reaction method according to claim 5 , wherein said cycloalkanone oxime is cyclohexanone oxime or cyclododecanone oxime.

7. The photochemical reaction method according to claim 5 , wherein said photo nitrosating agent is nitrosyl chloride or trichloronitrosomethane.

8. The photochemical reaction method according to claim 1 , wherein said inert gas is nitrogen.

9. A photochemical reaction method comprising using a photochemical reaction device having a light source, including a light source module having a substrate mounted with a plurality of light emitting diodes, inserted into the photochemical reaction device in which a reaction liquid is contained or flown,
introducing an optically transparent fluid between partitions of the photochemical reaction device and discharging said optically transparent fluid from between said partitions of the photochemical reaction device;
detecting a change in discharge pressure or discharge flow rate of said optically transparent fluid;
sealing an inert gas at a condition of positive pressure inside an inner partition of two of the partitions of the photochemical reaction device arranged apart from each other between the light source and a flammable reaction liquid; and
irradiating light from said light source to perform a photochemical reaction.

Assignees

• Toray Industries

Inventors

• Sugimoto Takenori
• Takahashi Toru
• Sugawara Kazuki

Classifications

• C07C249/04

  of oximes · CPC title

• C07B61/00

  Other general methods · CPC title

• B01J19/12

  employing electromagnetic waves · CPC title

• C07D201/04 Primary

  from or via oximes by Beckmann rearrangement · CPC title

• B01J2219/1203

  Incoherent waves · CPC title