Exfoliating layered transition metal dichalcogenides

Patent metadata

Field	Value
Publication number	US-10414668-B1
Application number	US-201815953637-A
Country	US
Kind code	B1
Filing date	Apr 16, 2018
Priority date	Nov 27, 2017
Publication date	Sep 17, 2019
Grant date	Sep 17, 2019

Abstract

A technique for exfoliating a transition metal dichalcogenide material to produce separated nano-scale platelets includes combining the transition metal dichalcogenide material with a liquid to form a slurry, wherein the transition metal dichalcogenide material includes layers of nano-scale platelets and has a general chemical formula MX2, and wherein M is a transition metal and X is sulfur, selenium, or tellurium. The slurry of the transition metal dichalcogenide material is treated with an oxidant to form peroxo-metalate intermediates on an edge region of the layers of nano-scale platelets of the transition metal dichalcogenide material. The peroxo-metalate intermediates is treated with a reducing agent to form negatively charged poly-oxo-metalates to induce separation of the transition metal dichalcogenide material into the separated nano-scale platelets of the transition metal dichalcogenide material.

First claim

What is claimed is:

1. A method of exfoliating a transition metal dichalcogenide material to produce separated nano-scale platelets, the method comprising:
combining the transition metal dichalcogenide material with a liquid to form a slurry, wherein the transition metal dichalcogenide material comprises layers of nano-scale platelets and has a general chemical formula MX 2 , and wherein M is a transition metal and X is sulfur, selenium, or tellurium;
treating the slurry of the transition metal dichalcogenide material with an oxidant to form peroxo-metalate intermediates on an edge region of the layers of nano-scale platelets of the transition metal dichalcogenide material; and
treating the peroxo-metalate intermediates with a reducing agent to form negatively charged poly-oxo-metalates to induce separation of the transition metal dichalcogenide material into the separated nano-scale platelets of the transition metal dichalcogenide material.

2. The method of claim 1 , wherein the transition metal comprises any of titanium, zirconium, hafnium, vanadium, niobium, tantalum, molybdenum, tungsten, rhenium, nickel, palladium, platinum, copper, silver, and gold, and wherein the chalcogenide comprises any of sulfur, selenium, and tellurium.

3. The method of claim 1 , further comprising agitating the slurry by any of stirring and ultrasonicating.

4. The method of claim 1 , wherein the liquid comprises an organic solvent selected from the group consisting of a polar protic solvent, a polar aprotic solvent, and combinations thereof.

5. The method of claim 4 , wherein the organic solvent is selected from the group consisting of acetonitrile, methanol, ethanol, acetone, methyl ethyl ketone, N,Ndimethylformamide, N-methylpyrrolidone, and combinations thereof.

6. The method of claim 1 , wherein the reducing agent comprises any of a hydride donor and an electron transfer species.

7. The method of claim 6 , wherein the hydride donor comprises any of sodium borohydride and lithium borohyride, and wherein the electron transfer species comprises any of ascorbic acid and hydroquinone.

8. The method of claim 1 , wherein the oxidant comprises any of peroxide and peroxo-acid.

9. The method of claim 8 , wherein the peroxide comprises any of cumene hydroperoxide, hydrogen peroxide, and 3-chloroperbenzoic acid.

10. The method of claim 1 , further comprising isolating the separated nano-scale platelets of the transition metal dichalcogenide material by any of decantation, centrifugation, and filtration.

Assignees

• Us Gov Air Force
• Us Air Force

Inventors

• Vaia Richard A
• Jawaid Ali M

Classifications

• C01P2006/22

  Rheological behaviour as dispersion, e.g. viscosity, sedimentation stability · CPC title

• C01P2004/24

  Nanoplates, i.e. plate-like particles with a thickness from 1-100 nanometer · CPC title

• C01P2002/89

  by mass-spectroscopy · CPC title

• C01P2002/85

  by XPS, EDX or EDAX data · CPC title

• C01P2002/84

  by UV- or VIS- data · CPC title