Lithium ionic conductor, fabrication method therefor and all-solid lithium secondary battery
US-2015340734-A1 · Nov 26, 2015 · US
US10411295B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10411295-B2 |
| Application number | US-201515531565-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 26, 2015 |
| Priority date | Dec 22, 2014 |
| Publication date | Sep 10, 2019 |
| Grant date | Sep 10, 2019 |
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According to one embodiment of the present invention, provided is an ionic conductor comprising lithium (Li), borohydride (BH 4 − ), phosphorus (P), and sulfur (S), wherein, in X-ray diffraction (CuKα: λ=1.5405 Å), the ionic conductor has diffraction peaks, at least, at 2θ=14.4±1.0 deg, 15.0±1.0 deg, 24.9±1.0 deg, 29.2±1.5 deg, 30.3±1.5 deg, 51.1±2.5 deg and 53.5±2.5 deg.
Opening claim text (preview).
The invention claimed is: 1. An ionic conductor comprising lithium (Li), borohydride (BH 4 − ), phosphorus (P), and sulfur (S), wherein, in X-ray diffraction (CuKα: λ=1.5405 Å), the ionic conductor has diffraction peaks, at least, at 2θ=14.4±1.0 deg, 15.0±1.0 deg, 24.9±1.0 deg, 29.2±1.5 deg, 30.3±1.5 deg, 51.1±2.5 deg and 53.5±2.5 deg. 2. A method for producing an ionic conductor, which comprises mixing LiBH 4 and P 2 S 5 at a molar ratio of LiBH 4 : P 2 S 5 =x: (1−x) [wherein x is greater than 0.85 and 0.98 or less] to obtain a mixture, and subjecting the mixture to a heat treatment, wherein the ionic conductor comprises lithium (Li), borohydride (BH 4 − ), phosphorus (P), and sulfur (S), and has diffraction peaks, at least, at 2θ=14.4±1.0 deg, 15.0±1.0 deg, 24.9±1.0 deg, 29.2±1.5 deg, 30.3±1.5 deg, 51.1±2.5 deg and 53.5±2.5 deg in X-ray diffraction (CuKα: λ=1.5405 Å). 3. The method for producing an ionic conductor according to claim 2 , wherein the temperature applied in the heat treatment is 50° C. to 300° C. 4. The method for producing an ionic conductor according to claim 3 , wherein the temperature applied in the heat treatment is 60° C. to 200° C. 5. The method for producing an ionic conductor according to claim 2 , wherein the mixing is carried out in an inert gas atmosphere. 6. A solid electrolyte for all-solid-state batteries, comprising the ionic conductor according to claim 1 . 7. An all-solid-state battery comprising the solid electrolyte for all-solid-state batteries according to claim 6 . 8. The method for producing an ionic conductor according to claim 3 , wherein the mixing is carried out in an inert gas atmosphere. 9. The method for producing an ionic conductor according to claim 4 , wherein the mixing is carried out in an inert gas atmosphere.
Apparatus or processes specially adapted for manufacturing conductors or cables · CPC title
Ionic conductors · CPC title
sulfides · CPC title
Solid materials · CPC title
Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title
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