Light-emitting device
US-12155019-B2 · Nov 26, 2024 · US
US10411174B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10411174-B2 |
| Application number | US-201515129848-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 27, 2015 |
| Priority date | Mar 31, 2014 |
| Publication date | Sep 10, 2019 |
| Grant date | Sep 10, 2019 |
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A semiconductor light-emitting device including at least a substrate, a reflector having a concave cavity, and an optical semiconductor element, wherein the reflector is formed of a resin composition containing an inorganic substance; in a spectrum obtained when the reflector is measured by an X-ray diffraction method using CuKα radiation (wavelength=1.5418 A), an intensity ratio (P1/P2) of a peak intensity P1 of the highest intensity diffraction peak in a range of diffraction angle 2θ of 0° to 24° to the peak intensity P2 of the highest intensity diffraction peak in a range of diffraction angle 2θ of more than 24° to 70° is 0.01 or more and 1.0 or less; and an ash content of the reflector is 60% by mass or more. A semiconductor light-emitting device and an optical-semiconductor-mounting substrate, including a reflector having an extremely high light reflection property and excellent dimensional stability.
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The invention claimed is: 1. A semiconductor light-emitting device comprising: a substrate; a reflector having a concave cavity; and an optical semiconductor element, wherein: the reflector is formed of a resin composition containing an inorganic substance and at least one of polymethylpentene, polyethylene, or polypropylene; the reflector has a reflectance of 90% or more; in a spectrum obtained when the reflector is measured by an X-ray diffraction method using CuKα radiation (wavelength=1.5418 A), an intensity ratio (P1/P2) of a peak intensity P1 of a highest intensity diffraction peak in a range of a first diffraction angle 2θ of 0° to 24° to the peak intensity P2 of the highest intensity diffraction peak in a range of a second diffraction angle 2θ of more than 24° to 70° is 0.01 or more and 1.0 or less; and an ash content of the reflector is 60% by mass or more, which reflects a weight ratio of the inorganic substance in the resin composition that forms the reflector. 2. The semiconductor light-emitting device according to claim 1 , wherein, among the diffraction peaks in a range of the first diffraction angle 2θ of 0° to 24°, the highest intensity diffraction peak is any one of peaks at 2θ=9.3±1°, 13.4±1°, 16.7±1°, and 18.3±1°. 3. The semiconductor light-emitting device according to claim 1 , wherein, in a range of the second diffraction angle 2θ of more than 24° to 70°, the highest intensity diffraction peak is any one of peaks at 2θ=27.4±1°, 36.1±1°, 41.2±1°, 54.3±1°, 56.6±1°, 69.0±1°, 25.3±1°, 37.9±1°, 48.1±1°, 54.0±1°, 55.1±1°, 62.7±1°, 25.7±1°, 30.8±1°, 36.3±1°, 48.0±1°, 54.2±1°, and 55.2±1°. 4. The semiconductor light-emitting device according to claim 1 , wherein the diffraction peaks in a range of the first diffraction angle 2θ of 0° to 24° include a combination of diffraction peaks at least at 2θ=9.3±1°, 13.4±1°, 16.7±1°, and 18.3±1°. 5. The semiconductor light-emitting device according to claim 1 , wherein the diffraction peaks in a range of the second diffraction angle 2θ of more than 24° to 70° include any one of the following combinations (1) to (3): (1) a combination of diffraction peaks at least at 2θ=27.4±1°, 36.1±1°, 41.2±1°, 54.3±1°, 56.6±1°, and 69.0±1°; (2) a combination of diffraction peaks at least at 2θ=25.3±1°, 37.9±1°, 48.1±1°, 54.0±1°, 55.1±1°, and 62.7±1°; and (3) a combination of diffraction peaks at least at 2θ=25.3±1°, 25.7±1°, 30.8±1°, 36.3±1°, 48.0±1°, 54.2±1°, and 55.2±1°. 6. The semiconductor light-emitting device according to claim 1 , wherein, in a range of the first diffraction angle 2θ of 0° to 24°, the highest intensity diffraction peak is a peak at 2θ=9.3±1°. 7. The semiconductor light-emitting device according to claim 1 , wherein, in a range of the second diffraction angle 2θ of more than 24° to 70°, the highest intensity diffraction peak is a peak at 2θ=27.4±1°. 8. The semiconductor light-emitting device according to claim 1 , wherein the optical semiconductor element is an LED element. 9. The semiconductor light-emitting device according to claim 1 , wherein the cavity of the reflector is filled with a sealing resin. 10. The semiconductor light-emitting device according to claim 1 , wherein the resin composition further contains a cross-linking agent. 11. An optical-semiconductor-mounting substrate comprising: a substrate; and a reflector having a concave cavity, wherein: the reflector is formed of a resin composition containing an inorganic substance and at least one of polymethylpentene, polyethylene, or polypropylene; the reflector has a reflectance of 90% or more; in a spectrum obtained when the reflector is measured by an X-ray diffraction method using CuKα radiation (wavelength=1.5418 A), an intensity ratio (P1/P2) of a peak intensity P1 of the highest intensity diffraction peak in a range of a first diffraction angle 2θ of 0° to 24° to the peak intensity P2 of the highest intensity diffraction peak in a range of a second diffraction angle 2θ of more than 24° to 70° is 0.01 or more and 1.0 or less; and an ash content of the reflector is 60% by mass or more, which reflects a weight ratio of the inorganic substance in the resin composition that forms the reflector. 12. The optical-semiconductor-mounting substrate according to claim 11 , wherein, among the diffraction peaks in a range of the first diffraction angle 2θ of 0° to 24°, the highest intensity diffraction peak is any one of peaks at 2θ=9.3±1°, 13.4±1°, 16.7±1°, and 18.3±1°. 13. The optical-semiconductor-mounting substrate according to claim 11 , wherein, in a range of the second diffraction angle 2θ of more than 24° to 70°, the highest intensity diffraction peak is any one of peaks at 2θ=27.4±1°, 36.1±1°, 41.2±1°, 54.3±1°, 56.6±1°, 69.0±1°, 25.3±1°, 37.9±1°, 48.1±1°, 54.0±1°, 55.1±1°, 62.7±1°, 25.7±1°, 30.8±1°, 36.3±1°, 48.0±1°, 54.2±1°, and 55.2±1°. 14. The optical-semiconductor-mounting substrate according to claim 11 , wherein the diffraction peaks in a range of the first diffraction angle 2θ of 0° to 24° include a combination of diffraction peaks at least at 2θ=9.3±1°, 13.4±1°, 16.7±1°, and 18.3±1°. 15. The optical-semiconductor-mounting substrate according to claim 11 , wherein the diffraction peaks in a range of the second diffraction angle 2θ of more than 24° to 70° include any one of the following combinations (1) to (3): (1) a combination of diffraction peaks at least at 2θ=27.4±1°, 36.1±1°, 41.2±1°, 54.3±1°, 56.6±1°, and 69.0±1°; (2) a combination of diffraction peaks at least at 2θ=25.3±1°, 37.9±1°, 48.1±1°, 54.0±1°, 55.1±1°, and 62.7±1°; and (3) a combination of diffraction peaks at least at 2θ=25.3±1°, 25.7±1°, 30.8±1°, 36.3±1°, 48.0±1°, 54.2±1°, and 55.2±1°. 16. The optical-semiconductor-mounting substrate according to claim 11 , wherein, in a range of the first diffraction angle 2θ of 0° to 24°, the highest intensity diffraction peak is a peak at 2θ=9.3±1°. 17. The optical-semiconductor-mounting substrate according to claim 11 , wherein, in a range of the second diffraction angle 2θ of more than 24° to 70°, the highest intensity diffraction peak is a peak at 2θ=27.4±1°. 18. The optical-semiconductor-mounting substrate according to claim 11 , wherein the cavity of the reflector is filled with a sealing resin. 19. The optical-semiconductor-mounting substrate according to claim 11 , wherein the resin composition further contains a cross-linking agent. 20. The semiconductor light-emitting device according to claim 1 , wherein the inorganic substance includes titanium oxide and glass fiber. 21. The semiconductor light-emitting device according to claim 1 , wherein the resin composition further contains a cross-linking agent having a saturated or unsaturated cyclic structure wherein at least one atom among atoms forming at least one ring is bonded to any of an allyl group, a methacryl group, an allyl group via a linking group, or a methacryl group via a linking group. 22. The semiconductor light-emitting device according to claim 1 , wherein the resin composition further contains a cross-linking agent comprising triallyl isocyanurate, methyldiallyl isocyanurate, diallylmonoglycidyl isocyanurate, monoallyldiglycidyl isocyanurate, trimethallyl isocyanurate, a diallyl ester of orthophthalic acid, or a diallyl ester of isophthalic acid. 23. A semiconductor light-emitting device comprising: a substrate; a reflector having a concave cavity; and an optical semiconductor element, wherein: the reflector is formed of a resin
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