Method for generating hydrogen by water splitting, and photoelectrochemical cell and semiconductor electrode used therefor
US-2015322577-A1 · Nov 12, 2015 · US
US10411144B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10411144-B2 |
| Application number | US-201815979931-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 15, 2018 |
| Priority date | Jun 7, 2017 |
| Publication date | Sep 10, 2019 |
| Grant date | Sep 10, 2019 |
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A semiconductor electrode according to the present disclosure includes a conductive substrate; a semiconductor layer which is provided on the conductive substrate, and absorbs visible light; and a protection layer with which the semiconductor layer is coated, in which the protection layer is formed of an oxynitride, the visible light travels through the protection layer, and the protection layer has a thinner thickness than the semiconductor layer.
Opening claim text (preview).
The invention claimed is: 1. A semiconductor electrode, comprising: a conductive substrate; a semiconductor layer which is provided on the conductive substrate and is capable of absorbing visible light; and a protection layer with which the semiconductor layer is coated, wherein the protection layer is formed of an oxynitride; the visible light is capable of traveling through the protection layer; and the protection layer has a thinner thickness than the semiconductor layer. 2. The semiconductor electrode according to claim 1 , wherein the oxynitride forming the protection layer is an oxynitride of one selected from the group consisting of aluminum, silicon, and zirconium. 3. The semiconductor electrode according to claim 2 , wherein the oxynitride forming the protection layer is an aluminum oxynitride. 4. The semiconductor electrode according to claim 1 , wherein the semiconductor layer is formed of one selected from the group consisting of a nitride semiconductor and an oxynitride semiconductor. 5. The semiconductor electrode according to claim 4 , wherein the semiconductor layer is formed of a nitride semiconductor; and the nitride semiconductor is a nitride semiconductor of a transition metal selected from the group consisting of vanadium, niobium and tantalum. 6. The semiconductor electrode according to claim 5 , wherein the nitride semiconductor is a niobium nitride semiconductor. 7. The semiconductor electrode according to claim 4 , wherein the semiconductor layer is formed of an oxynitride semiconductor; and the oxynitride semiconductor is an oxynitride semiconductor of a transition metal selected from the group consisting of vanadium, niobium and tantalum. 8. The semiconductor electrode according to claim 7 , wherein the nitride semiconductor is a niobium oxynitride semiconductor. 9. A gas generation device, comprising: a semiconductor electrode comprising: a conductive substrate; a semiconductor layer which is provided on the conductive substrate and is capable of absorbing visible light; and a protection layer with which the semiconductor layer is coated, wherein the protection layer is formed of an oxynitride; the visible light is capable of traveling through the protection layer; and the protection layer has a thinner thickness than the semiconductor layer; a counter electrode connected electrically with the conductive substrate; an electrolyte aqueous solution in contact with the semiconductor electrode and the counter electrode; and a container in which the semiconductor electrode, the counter electrode, and the electrolyte aqueous solution are contained.
Decomposition of water (by electrolysis of water C25B1/04) · CPC title
by electrolysis of water · CPC title
characterised by shape or form · CPC title
Production of hydrogen; Production of gaseous mixtures containing hydrogen · CPC title
Electricity · mapped topic
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