NMR in kinetics of hydrocarbon generation

Patent metadata

Field	Value
Publication number	US-10408962-B2
Application number	US-201615215403-A
Country	US
Kind code	B2
Filing date	Jul 20, 2016
Priority date	Jul 28, 2015
Publication date	Sep 10, 2019
Grant date	Sep 10, 2019

Abstract

Disclosed are methods of characterizing kerogen and its hydrocarbon generation potential using NMR as the primary analytical tool, and using such data to derive the kinetics of hydrocarbon generation and alteration, thus predicting the hydrocarbon potential of source rock in geological setting, which can then be used in petroleum exploration and production.

First claim

The invention claimed is:

1. A method of determining and using hydrocarbon generation potential from kerogen, said method comprising:
a) obtaining a sample of kerogen;
b) performing elemental analysis on a portion of said kerogen to determine its C, H, N, S and O content;
c) performing nuclear magnetic resonance (NMR) analysis on a portion of said kerogen to determine its initial relative abundances of different H and C species;
d) pyrolyzing a portion of said kerogen to determine a pyrolysis temperature profile and to produce petroleum fluid and a kerogen residue;
e) analyzing the composition of said petroleum fluid;
f) performing NMR analysis on said kerogen residue; and
g) predicting hydrocarbon generation from said kerogen using the data obtained in steps b-f to determine the hydrocarbon generating potential of said kerogen; and,
h) using said hydrocarbon generating potential in formulating and executing exploration and production plans.

2. The method of claim 1 , wherein said NMR analysis is solid state NMR.

3. The method of claim 1 , wherein said NMR analysis uses 13C NMR.

4. The method of claim 1 , wherein said NMR analysis uses 1H NMR.

5. The method of claim 1 , wherein said NMR analysis uses 15N NMR.

6. The method of claim 1 , wherein said NMR analysis uses both 13C and 1H NMR.

7. The method of claim 1 , wherein said NMR analysis is solid-state magic angle spinning (MAS) NMR.

8. The method of claim 1 , wherein said NMR analysis is solid state NMR using cross polarization (CP).

9. The method of claim 1 , wherein said NMR analysis is solid state NMR using direct polarization (DP).

10. The method of claim 1 , wherein said NMR analysis is solid state NMR using both CP and DP.

11. The method of claim 1 , wherein said method uses spin counting to calibrate NMR data.

12. The method of claim 1 , wherein predicting step uses a network of first order parallel reactions.

13. The method of claim 1 , wherein predicting step uses higher order parallel reactions plus sequential reactions.

14. The method of claim 1 , wherein predicting step uses the Arrhenius equation.

15. The method of claim 1 , wherein said pyrolyzing step produced a pyrogram that can be read to determine S1, S2, S3, and Tmax.

16. The method of claim 1 , wherein said identifying step uses gas chromatography or mass spectrometry or NMR or a combination thereof.

17. The method claim 1 , wherein NMR provides relative abundances of rigid H, mobile H and C species.

18. The method of claim 1 , wherein gold vessel thermolysis of a portion of said isolated kerogen is performed as a double check of the data.

19. A method of determining and using hydrocarbon generation potential from kerogen, said method comprising:
a) obtaining a sample of source rock containing kerogen;
b) grinding said source rock to produce a powder;
c) extracting said powder to produce isolated kerogen;
d) performing elemental analysis on a portion of said isolated kerogen to determine its C, H, N, S and O content;
e) performing NMR analysis on a portion of said isolated kerogen to determine its initial relative abundances of different H and C species;
f) pyrolyzing a portion of said isolated kerogen to determine a pyrolysis temperature profile and to produce petroleum fluid and a kerogen residue;
g) analyzing the composition of said petroleum fluid;
h) performing NMR analysis on said kerogen residue; and
i) predicting hydrocarbon generation potential from said kerogen using the data obtained in steps d-h and using first order parallel reactions or higher order parallel reactions plus sequential reactions; and,
j) using said hydrocarbon generating potential in formulating exploration and production plans and using said exploration and production plans in exploring and producing hydrocarbons.

Assignees

• Conocophillips Co

Inventors

• Song Yishu

Classifications

• G01R33/5605

  by transferring coherence or polarization from a spin species to another, e.g. creating magnetization transfer contrast [MTC], polarization transfer using nuclear Overhauser enhancement [NOE] · CPC title

• G01R33/4641

  Sequences for NMR spectroscopy of samples with ultrashort relaxation times such as solid samples · CPC title

• G01R33/4608

  RF excitation sequences for enhanced detection, e.g. NOE, polarisation transfer, selection of a coherence transfer pathway · CPC title

• G01R33/46

  NMR spectroscopy · CPC title

• G01N33/241

  for hydrocarbon content · CPC title