Use of a polymer mixture as a sensor mixture

Patent metadata

Field	Value
Publication number	US-10408778-B2
Application number	US-201314138496-A
Country	US
Kind code	B2
Filing date	Dec 23, 2013
Priority date	Jan 17, 2013
Publication date	Sep 10, 2019
Grant date	Sep 10, 2019

Abstract

A polymer mixture is provided suitable for use in a cable as a sensor polymer mixture for determining the mechanical and/or electrical stability or aging of a cable. The method may use the determination of changes in the polymer mixture, especially for determination of the aging and/or stability, for example as a measure for estimation of the wear or the remaining service life of a cable having the polymer mixture.

First claim

The invention claimed is:

1. Sensor device for a cable, the cable having at least one conductor inside of a sheath and/or an inner sheath, said sensor device being designed for determining the ageing of said cable, said sensor device comprising:
a polymer sensor mixture being a separate structure from both said sheath and/or said inner sheath of said cable and said at least one conductor, said polymer sensor mixture being arranged along said cable sheath or inner sheath, said separate structure of said polymer sensor mixture including, entirely within it, at least two additional spaced-apart conductors, said at least two additional spaced-apart conductors being arranged at a distance apart from one another within the separate structure of said polymer sensor mixture and having contact with said polymer sensor mixture, wherein said polymer sensor mixture, with said two additional spaced apart conductors therein, takes the form of a filament,
said at least two additional spaced-apart conductors within said polymer sensor mixture are parallel to one another and to the longitudinal axis of the filament;
said separate structure of polymer sensor mixture, with said at least two additional conductors, forming a sensor element disposed on an outside or an inside of said sheath or inner sheath, and
a measurement unit, wherein each of said two additional conductors of said sensor element arranged within the sensor mixture are connected to said measurement unit,
wherein said polymer sensor mixture is a polymer mixture having:
at least one polymer;
inorganic fillers;
processing aids;
0.2 to 6% by weight of carbon nanotubes;
optionally plasticizers;
optionally a crosslinking system; and
optionally dye.

2. Sensor device according to claim 1 , wherein the carbon nanotubes have an average diameter of 8-10 nm, an average length of 1 to 5 μm, a carbon content of at least 90%, the remainder being metal oxides, and a BET surface area of 200 to 400 m 2 /g.

3. Sensor device according to claim 1 , wherein the polymer mixture contains up to 60% by weight of flame retardant.

4. Sensor device according to claim 1 , wherein at least one optical fiber, arranged along the cable, is connected to an optical detector from which the measurements are sent to an evaluation unit connected to said measurement unit, said evaluation unit being set up to correlate measurements from the measurement unit with the measurements from the optical detector, at least one optical fiber having a glass composition whose optical properties are temperature-dependent and/or at least one optical fiber having a glass composition whose optical properties can be varied by radioactive irradiation.

5. Method for determining the aging of a cable constructed with a sensor device according to claim 1 , wherein measurements of the conductivity, the resistance, the capacity and/or the dissipation factor of the sensor mixture are determined.

6. Method according to claim 5 , wherein an optical fiber arranged along the cable has temperature-dependent optical properties, and measurements of the temperature-dependent optical properties are taken, and/or in that the cable contains an optical fiber which is arranged along the cable and has optical properties dependent on radioactive irradiation, and measurements of the optical properties thereof dependent on radioactive irradiation are taken.

7. Method according to claim 5 , wherein the measurements of the conductivity, the resistance, the capacity and/or the dissipation factor of the sensor mixture, measurements of temperature-dependent optical properties and/or measurements of optical properties dependent on radioactive irradiation are compared in an evaluation unit with data which contain a predetermined correlation of the aging of at least one polymer mixture in the cable with this measurement.

8. Sensor device according to claim 1 , wherein the polymer mixture has 0.2 to 4% by weight of carbon nanotubes.

9. Sensor device according to claim 1 , wherein the sensor element is arranged on the outer surface of said cable sheath and/or within said cable sheath.

10. Sensor device according to claim 1 , wherein said at least two spaced-apart conductors are embedded in said polymer sensor mixture.

11. Sensor device according to claim 1 , further comprising said cable.

12. Sensor device for a cable, the cable having at least one conductor and a sheath or an inner sheath, said sensor device being designed for determining the ageing of said cable, said sensor device comprising:
a polymer sensor mixture arranged as separate polymer structure within the cross section of said sheath or inner sheath and running along the length of said cable, said polymer sensor mixture being in the form of at least two or more separate polymer filaments, each of which extend separately from, but within said sheath or inner sheath, substantially along the entire length of the cable, the filaments making up a component of the cross section of said sheath or of said inner sheath along the entire length of the cable, and
a measurement unit, wherein said component is connected to said measurement unit at ends of said filaments,
wherein said polymer sensor mixture is a polymer mixture having:
at least one polymer;
inorganic fillers;
processing aids;
0.2 to 6% by weight of carbon nanotubes;
optionally plasticizers;
optionally a crosslinking system; and
optionally dye.

13. Sensor device according to claim 12 , wherein one end of each filament is electrically connected to said measurement unit in a first longitudinal section of said cable, and the ends thereof arranged in a second longitudinal section of said cable, spaced apart from the first longitudinal section, are electrically connected to one another.

14. Sensor device according to claim 12 , wherein said at least two filaments are spaced-apart within said sheath or said inner sheath.

15. Sensor device according to claim 12 , wherein the carbon nanotubes have an average diameter of 8-10 nm, an average length of 1 to 5 μm, a carbon content of at least 90%, the remainder being metal oxides, and a BET surface area of 200 to 400 m 2 /g.

16. Sensor device according to claim 12 , wherein the polymer mixture contains up to 60% by weight of flame retardant.

17. Sensor device according to claim 12 , wherein at least one optical fiber, arranged along the cable, is connected to an optical detector from which the measurements are sent to an evaluation unit connected to said measurement unit, said evaluation unit being set up to correlate measurements from the measurement unit with the measurements from the optical detector, at least one optical fiber having a glass composition whose optical properties are temperature-dependent and/or at least one optical fiber having a glass composition whose optical properties can be varied by radioactive irradiation.

18. Method for determining the aging of a cable constructed with a sensor device according to claim 1 , wherein measurements of the conductivity, the resistance, the capacity and/or the dissipation factor of the sensor mixture are determined.

19. Method according to claim 18 , wherein an optical fiber arranged along the cable has temperature-dependent optical properties, and measurements of the temperature-dependent optical properties are taken, and/or in that the cable contains an optical fiber which is arranged along the cable and has optical properties dependent on radioactive irradiation, and measurements of the optical properties thereof dependent on radioactive irradiation are

Assignees

• Nexans

Inventors

• Meyer Matthias
• Gonnet Jean Marc
• Combessis Anthony

Classifications

• G01N33/442

  Resins; Plastics · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• G01N27/041 Primary

  of a solid body · CPC title

• C08L23/02

  not modified by chemical after-treatment · CPC title

• G01N27/22

  by investigating capacitance · CPC title