Method and reactor for cracking hydrocarbon and method for coating the reactor

Patent metadata

Field	Value
Publication number	US-10407620-B2
Application number	US-201715805805-A
Country	US
Kind code	B2
Filing date	Nov 7, 2017
Priority date	Dec 22, 2010
Publication date	Sep 10, 2019
Grant date	Sep 10, 2019

Abstract

A reactor having an inner surface accessible to the hydrocarbon and providing a sintered product of at least one of cerium oxide, zinc oxide, tin oxide, zirconium oxide, boehmite and silicon dioxide, and a perovskite material of formula A a B b C c D d O 3−δ . 0<a<1.2, 0≤b≤1.2, 0.9<a+b≤1.2, 0<c<1.2, 0≤d≤1.2, 0.9<c+d≤1.2, −0.5<δ<0.5, wherein A is selected from calcium, strontium, barium, and any combination thereof; B is selected from lithium, sodium, potassium, rubidium, and any combination thereof; C is selected from cerium, zirconium, antimony, praseodymium, titanium, chromium, manganese, ferrum, cobalt, nickel, gallium, tin, terbium and any combination thereof; and D is selected from lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, scandium, titanium, vanadium, chromium, manganese, ferrum, cobalt, nickel, copper, zinc, yttrium, zirconium, niobium, molybdenum, technetium, ruthenium, rhodium, palladium, silver, cadmium, hafnium, tantalum, tungsten, rhenium, osmium, iridium, platinum, gold, gallium, indium, tin, antimony and any combination thereof.

First claim

The invention claimed is:

1. A method for cracking hydrocarbon, comprising:
providing steam and hydrocarbon, wherein said hydrocarbon is an ethane containing feedstock; and
feeding steam and hydrocarbon into a reactor having an inner surface accessible to hydrocarbon, the inner surface comprising a sintered product of a perovskite material of formula AaBbCcDdO3−δ and an inorganic material, wherein
the inorganic material comprises at least one of cerium oxide, zinc oxide, tin oxide, zirconium oxide, boehmite and silicon dioxide;
0<a<1.2, 0≤b≤1.2, 0.9<a+b≤1.2, 0<c<1.2, 0≤d≤1.2, 0.9<c+d≤1.2, −0.5<δ<0.5;
A is selected from calcium (Ca), strontium (Sr), barium (Ba), and any combination thereof;
B is selected from lithium (Li), sodium (Na), potassium (K), rubidium (Rb) and any combination thereof;
C is selected from cerium (Ce), zirconium (Zr), antimony (Sb), praseodymium (Pr), titanium (Ti), chromium (Cr), manganese (Mn), ferrum (Fe), cobalt (Co), nickel (Ni), gallium (Ga), tin (Sn), terbium (Tb) and any combination thereof; and
D is selected from lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu), scandium (Sc), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), ferrum (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), technetium (Tc), ruthenium (Ru), rhodium (Rh), palladium (Pd), silver (Ag), cadmium (Cd), hafnium (Hf), tantalum (Ta), tungsten (W), rhenium (Re), osmium (Os), iridium (Ir), platinum (Pt), gold (Au), gallium (Ga), indium (In), tin (Sn), antimony (Sb) and any combination thereof,
said method further comprising heating said steam and said hydrocarbon at a temperature of from about 480° C. to about 1,000° C. in order to form ethylene,
wherein the perovskite material is selected from SrCeO 3 , SrZr 0.3 Ce 0.7 O 3 , BaMnO 3 , BaCeO 3 , and BaZr 0.3 Ce 0.7 O 3 , BaZr 0.3 Ce 0.5 Y 0.2 O 3 , BaZr 0.1 Ce 0.7 Y 0.2 O 3 , BaZrO 3 , BaZr 0.7 Ce 0.3 O 3 , BaCe 0.5 Zr 0.5 O 3 , BaCe 0.9 Y 0.1 O 3 , BaCe 0.85 Y 0.15 O 3 , and BaCe 0.5 Y 0.2 O 3 .

2. The method of claim 1 , wherein the sintered product comprises BaZr 0.3 Ce 0.7 O 3 .

3. The method of claim 2 , wherein the inorganic material comprises a combination of zirconium oxide and cerium oxide.

4. The method of claim 2 , wherein the inorganic material comprises a combination of boehmite and cerium oxide.

5. A method for cracking hydrocarbon, comprising:
providing steam and hydrocarbon; and
feeding steam and hydrocarbon into a reactor having an inner surface accessible to hydrocarbon, the inner surface comprising a sintered product of a perovskite material of formula AaBbCcDdO3−δ and an inorganic material, wherein
the inorganic material comprises at least one of cerium oxide, zinc oxide, tin oxide, zirconium oxide, boehmite and silicon dioxide;
0<a<1.2, 0≤b≤1.2, 0.9<a+b≤1.2, 0<c<1.2, 0≤d≤1.2, 0.9<c+d≤1.2, −0.5<δ<0.5;
A is selected from calcium (Ca), strontium (Sr), barium (Ba), and any combination thereof;
B is selected from lithium (Li), sodium (Na), potassium (K), rubidium (Rb) and any combination thereof;
C is selected from cerium (Ce), zirconium (Zr), antimony (Sb), praseodymium (Pr), titanium (Ti), chromium (Cr), manganese (Mn), ferrum (Fe), cobalt (Co), nickel (Ni), gallium (Ga), tin (Sn), terbium (Tb) and any combination thereof; and
D is selected from lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), lutetium (Lu), scandium (Sc), titanium (Ti), vanadium (V), chromium (Cr), manganese (Mn), ferrum (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), technetium (Tc), ruthenium (Ru), rhodium (Rh), palladium (Pd), silver (Ag), cadmium (Cd), hafnium (Hf), tantalum (Ta), tungsten (W), rhenium (Re), osmium (Os), iridium (Ir), platinum (Pt), gold (Au), gallium (Ga), indium (In), tin (Sn), antimony (Sb) and any combination thereof,
wherein the perovskite material is selected from SrCeO 3 , SrZr 0.3 Ce 0.7 O 3 , BaMnO 3 , BaCeO 3 , and BaZr 0.3 Ce 0.7 O 3 , BaZr 0.3 Ce 0.5 Y 0.2 O 3 , BaZr 0.1 Ce 0.7 Y 0.2 O 3 , BaZrO 3 , BaZr 0.7 Ce 0.3 O 3 , BaCe 0.5 Zr 0.5 O 3 , BaCe 0.9 Y 0.1 O 3 , BaCe 0.85 Y 0.15 O 3 , and BaCe 0.5 Y 0.2 O 3 .

6. The method of claim 5 , wherein the hydrocarbon comprises at least one of ethane, heptane, liquid petroleum gas, naphtha, and gas oil.

7. The method of claim 5 , wherein the sintered product comprises BaZr 0.3 Ce 0.7 O 3 .

8. The method of claim 5 , wherein the inorganic material comprises a combination of zirconium oxide and cerium oxide.

9. The method of claim 5 , wherein the inorganic material comprises a combination of boehmite and cerium oxide.

Assignees

• Gen Electric

Inventors

• Gu Yanfei
• Peng Wenqing
• Wang Shizong
• Lin Chuan
• Kool Lawrence Bernard
• Wu Zhaoping
• Fu Qijia
• Deng Zhigang

Classifications

• C10B43/14 Primary

  Preventing incrustations · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title

• C10G2300/807

  Steam · CPC title

• C10G2300/1059

  Gasoil having a boiling range of about 330 - 427 °C · CPC title

• C04B35/50

  based on rare-earth compounds {(non-oxide rare earth compounds C04B35/5156)} · CPC title