Macronutrient compositions with supramolecular structures for agricultural use
US-2024124370-A1 · Apr 18, 2024 · US
US10407353B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10407353-B2 |
| Application number | US-201515509672-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 10, 2015 |
| Priority date | Sep 12, 2014 |
| Publication date | Sep 10, 2019 |
| Grant date | Sep 10, 2019 |
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The present technology relates to a micronutrient fertilizer comprising immediate release and sustained release components contained within a hydrated polyelectrolyte solution. The fertilizer is readily dispersed and stable over long periods of time.
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What is claimed is: 1. A liquid micronutrient fertilizer composition comprising an aqueous dispersion of soluble and insoluble micronutrients, a polyelectrolyte, and a metal complexing agent; wherein the total combined weight of both the insoluble micronutrient and the soluble micronutrient about 25%-85% by weight, wherein the polyelectrolyte is added to the aqueous micronutrient fertilizer dispersion at a concentration of about 0.1% - 10%, by weight, with respect to the total weight of the micronutrient fertilizer composition; and wherein the metal complexing agent is present in a concentration of about 1%-20% by weight, with respect to total weight of the micronutrient fertilizer composition; and wherein the polyelectrolyte comprises at least one polymer selected from the group consisting of alginic acid, sodium alginate, humic acid, chitosan, polylignosulfonate, polyacrylic acid, and polystyrene sulfonate; and wherein the metal complexing agent comprises at least one metal complexing agent selected from the group consisting of citric acid, ethylenediaminetetracetic acid, tartaric acid, and mixtures thereof; and wherein the soluble micronutrient comprises at least one micronutrient selected from the group consisting of magnesium chloride, magnesium citrate, iron (II) sulphate, iron (II) citrate, zinc sulfate, boron trichloride magnesium sulfate, aluminum chloride, aluminum sulfate, potassium aluminum sulfate, calcium chloride, calcium sulfate, calcium ammonium citrate, calcium citrate, hydrated chromium (III) sulfate, manganese chloride, manganese sulfate, manganese oxysulfate, manganese citrate, iron (II) chloride, iron (III) chloride, iron (III) oxychloride, potassium chloride, potassium sulfate, and mixtures thereof; and wherein the insoluble micronutrient comprises at least one micronutrient selected from the group consisting of magnesium oxide, iron (II) oxide, iron (III) oxide, zinc oxide, iron hydroxide, elemental boron, elemental magnesium, magnesium carbonate, dolomite, hydrated dolomite, magnesium hydroxide, magnesium oxalate, struvite, calcium sulfate, gypsum, calcium carbonate, calcium phosphate, calcitic limestone, eggshells, bonemeal, calcium apatite, copper (I) oxide, copper (II) oxide, copper carbonate, copper (II) phosphate, elemental zinc, zinc chromate, zinc molybdate, zinc hydroxide, zinc nitride, zinc blende, wurtzite, zinc pyrophosphate, zinc phosphide, zinc phosphate, elemental manganese, manganese (II) oxide, and mixtures thereof. 2. The composition of claim 1 , wherein the polyelectrolyte comprises at least one polymer selected from the group consisting of alginic acid, and sodium alginate. 3. The composition of claim 1 , wherein the soluble micronutrient comprises at least one micronutrient selected from the group consisting of zinc nitrate, zinc sulfate, magnesium chloride, iron (II) sulfate, and combinations thereof. 4. The composition of claim 1 , wherein the insoluble micronutrient comprises at least one micronutrient selected from the group consisting of zinc oxide, magnesium oxide, iron (II) oxide, iron (III) oxide, iron hydroxide, and combinations thereof. 5. The composition of claim 1 , wherein pH of the micronutrient fertilizer composition is from about 6.0 to about 10.0. 6. The composition of claim 2 , wherein the soluble micronutrient comprises at least one micronutrient selected from the group consisting of zinc nitrate, zinc sulfate, magnesium chloride, iron (II) sulfate, and combinations thereof. 7. The composition of claim 6 , wherein the insoluble micronutrient comprises at least one micronutrient selected from the group consisting of zinc oxide, magnesium oxide, iron (II) oxide, iron (III) oxide, iron hydroxide, and combinations thereof. 8. The composition of claim 7 , wherein pH of the micronutrient fertilizer composition is from about 6.0 to about 10.0.
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