Lithium silicate glass ceramic

Patent metadata

Field	Value
Publication number	US-10407341-B2
Application number	US-201715717565-A
Country	US
Kind code	B2
Filing date	Sep 27, 2017
Priority date	Oct 7, 2016
Publication date	Sep 10, 2019
Grant date	Sep 10, 2019

Abstract

The invention relates to a lithium silicate glass ceramic, which contains at least lithium disilicate as a crystal phase, and lithium aluminum silicate as further crystal phase. The lithium silicate glass ceramic in its initial composition contains Al2O3 at 1.5 to 3.5 percent by weight, and K2O at 0.6 to 1.8 percent by weight.

First claim

The invention claimed is:

1. A method for the production of a lithium silicate glass ceramic intended for a dental molded body, comprising the following steps:
a) melting of the starting components containing at least SiO 2 , P 2 O 5 , Al 2 O 3 , Li 2 O, K 2 O, ZrO 2 ,
b) filling of the melt into containers,
c) cooling of the melt to room temperature,
d) performance of a crystallization in the melt that has solidified to molded parts by means of a first heat treatment,
e) cooling to room temperature,
f) performance of a second heat treatment, wherein the molded parts are heated to a temperature TW2 between 720° C. and 780° C. and are held at this temperature for a time period tW2,
g) cooling of the molded parts to room temperature;
wherein the first heat treatment is carried out in three steps, wherein in a first step the molded part is maintained for a time t1 where 1 minute≤t1≤60 minutes at a temperature T1 where 250° C.≤T1≤600° C.,
wherein in the second step, the molded part is maintained for a time t2 where 1 minute≤t2≤150 minutes at a temperature T2 where 600° C.≤T2≤700° C., and
wherein in the third step the molded part is held for a time t3 where 10 minutes≤t3≤60 minutes at a temperature T3 where 700° C.≤T3≤850° C.

2. The method according to claim 1 , wherein in method step d) lithium disilicate and lithium phosphate are exclusively formed.

3. The method according to claim 1 , wherein crystallization of lithium aluminum silicate crystals occurs during the second heat treatment, which is carried out for the time tW2 with 1 minute≤tW2≤60 minutes.

4. The method according to claim 1 , wherein following method step e) and before method step f) the molded part for production of a molded body is pressed or the molded part for production of a molded body is worked in a material-removing manner.

5. The method according to claim 1 , wherein the second heat treatment for crystallization of lithium aluminum silicate crystals is carried out at the temperature TW2 where 750° C.≤tW2≤780° C. for the time tW2 where 1 minute≤tW2≤4 minutes.

6. A method for the production of a lithium silicate glass ceramic intended for a dental molded body, comprising the following steps:
a) melting of the starting components containing at least SiO 2 , P 2 O 5 , Al 2 O 3 , Li 2 O, K 2 O, ZrO 2 ,
b) filling of the melt into containers,
c) cooling of the melt to room temperature,
d) performance of a crystallization in the melt that has solidified to molded parts by means of a first heat treatment,
e) cooling to room temperature,
f) performance of a second heat treatment, wherein the molded parts are heated to a temperature TW2 between 720° C. and 780° C. and are held at this temperature for a time period tW2,

cooling of the molded parts to room temperature;
wherein for pressing the molded part it is held at a temperature TP where 730° C.≤TP≤900° C. for a time tP where tP 10 minutes≤tP≤50 minutes, and then pressed.

7. The method according to claim 6 , wherein in method step d) lithium disilicate and lithium phosphate are exclusively formed.

8. The method according to claim 6 , wherein crystallization of lithium aluminum silicate crystals occurs during the second heat treatment, which is carried out for the time tW2 with 1 minute≤tW2≤60 minutes.

9. The method according to claim 6 , wherein following method step e) and before method step f) the molded part for production of a molded body is pressed or the molded part for production of a molded body is worked in a material-removing manner.

10. The method according to claim 6 , wherein the second heat treatment for crystallization of lithium aluminum silicate crystals is carried out at the temperature TW2 where 750° C.≤tW2≤780° C. for the time tW2 where 1 minute≤tW2≤4 minutes.

11. A use of a lithium silicate glass ceramic, which comprises as the crystal phase lithium aluminum silicate, at least in form of spodumene, with a percentage by volume of more than 0 vol % to 10 vol % of lithium silicate glass ceramic, for the production of a dental molded body; wherein the lithium silicate glass ceramic includes sogdianite.

12. The use according to claim 11 , wherein the lithium silicate glass ceramic includes virgilite.

Assignees

• Dentsply Sirona Inc

Inventors

• Vollmann Markus
• Wissel Irmgard
• Meegdes Marcel
• Wiesner Carsten

Classifications

• C03C10/0009

  containing silica as main constituent · CPC title

• C03C4/0028

  for crystal glass, e.g. lead-free crystal glass · CPC title

• C03C4/0021

  for dental use · CPC title

• C03C3/17

  containing aluminium or beryllium · CPC title

• C03C3/093

  containing zinc or zirconium · CPC title