Apparatus and process for preparing acetylene and synthesis gas

Patent metadata

Field	Value
Publication number	US-10407305-B2
Application number	US-201414912809-A
Country	US
Kind code	B2
Filing date	Aug 28, 2014
Priority date	Aug 29, 2013
Publication date	Sep 10, 2019
Grant date	Sep 10, 2019

Abstract

An apparatus ( 10 ) for preparing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen is proposed, comprising a mixing unit ( 12 ), a mixing section and a mixing diffuser ( 16 ). The mixing unit ( 12 ) has a feed orifice ( 18 ) for supply of a hydrocarbonaceous stream, a feed orifice ( 20 ) for supply of an oxygenous stream, a swirl register and a distributor plate ( 24 ). The distributor plate ( 24 ) is disposed between the mixing section ( 14 ) and the feed orifice ( 18 ) for supply of a hydrocarbonaceous stream. The distributor plate ( 24 ) has orifices ( 28 ). The swirl register ( 22 ) is disposed between the feed orifice ( 20 ) for supply of an oxygenous stream and the mixing section ( 14 ). The mixing diffuser ( 16 ) is connected to the mixing section ( 14 ).
There is a further proposal of a process for preparing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen.

First claim

The invention claimed is:

1. An apparatus, comprising a mixing unit, a mixing section and a mixing diffuser,
wherein the mixing unit has a feed orifice for supply of a hydrocarbonaceous stream, a feed orifice for supply of an oxygenous stream, a swirl register and a distributor plate,
wherein the distributor plate is disposed between the mixing section and the feed orifice for supply of a hydrocarbonaceous stream,
wherein the swirl register is disposed between the feed orifice for supply of an oxygenous stream and the mixing section and the swirl register imparts a swirl flow to the oxygenous stream in the mixing section,
wherein the distributor plate has orifices such that the hydrocarbonaceous stream passes through the orifices and directly enters the the oxygenous stream in the mixing section, and
wherein the mixing diffuser is connected to the mixing section.

2. The apparatus according to claim 1 , wherein the mixing section is essentially cylindrical, and wherein the distributor plate is configured such that the distributor plate completely surrounds the mixing section, viewed in a circumferential direction.

3. The apparatus according to claim 1 , wherein the swirl register is disposed at least partly within the distributor plate.

4. The apparatus according to claim 1 , wherein the orifices are arranged in homogeneous or inhomogeneous distribution in the distributor plate.

5. The apparatus according to claim 4 , wherein the distributor plate is configured such that the ratio of the sum total of the cross-sectional areas of the orifices to a surface area of the distributor plate is from 0.1 to 0.4.

6. The apparatus according to claim 1 , wherein the feed orifice for supply of the hydrocarbonaceous stream is arranged essentially radially with respect to a center axis of the mixing section.

7. The apparatus according to claim 1 , wherein the feed orifice for supply of an oxygenous stream is arranged essentially parallel to a center axis of the mixing section.

8. The apparatus according to claim 1 , wherein the mixing section is connected to a mixing tube having a length and a diameter, wherein the length and diameter are configured such that a mixture of the oxygenous stream and the hydrocarbonaceous stream in operation of the apparatus in the mixing tube has a flow velocity of 0.2 mach to 1 mach.

9. The apparatus according to claim 1 , wherein the swirl register has a swirl number of 0.3 to 1.

10. A process for preparing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen in the apparatus of claim 1 ,
the method comprising:
feeding a hydrocarbonaceous stream is to a mixing section through a first feed orifice; and
feeding an oxygenous stream to the mixing section through a second feed orifice,
wherein a distributor plate is arranged between the mixing section ( 14 ) and the first feed orifice for supply of a hydrocarbonaceous stream,
wherein the distributor plate has orifices,
wherein a swirl register is disposed between the second feed orifice for supply of an oxygenous stream and the mixing section, wherein a mixing diffuser is connected to the mixing section.

11. The process according to claim 10 , wherein the distributor plate is configured such that the ratio of the sum total of the cross-sectional areas of the orifices to a surface area of the distributor plate is from 0.1 to 0.4.

12. The process according to claim 10 , wherein the hydrocarbonaceous stream is fed in essentially radially with respect to a center axis of the mixing section, wherein the oxygenous stream is fed in essentially parallel to a center axis of the mixing section.

13. The process according to claim 10 , wherein the mixing tube has a length and a diameter, the length and diameter being configured such that the process for preparing acetylene and synthesis gas by partial oxidation of hydrocarbons with oxygen is conducted such that a mixture of the oxygenous stream and the hydrocarbonaceous stream in the mixing tube has a flow velocity of 0.2 mach to 1 mach.

14. The process according to claim 10 , wherein the swirl register has a swirl number of 0.3 to 1.

Assignees

• Basf Se

Inventors

• Kern Matthias
• Russ Michael
• Renze Peter
• Vicari Maximilian

Classifications

• B01J4/002 Primary

  Nozzle-type elements (nozzle-type reactors B01J19/26) · CPC title

• C07C2/78 Primary

  Processes with partial combustion · CPC title

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• C01B3/36 Primary

  using oxygen; using mixtures containing oxygen as gasifying agents · CPC title

• C01B2203/0255

  containing a non-catalytic partial oxidation step · CPC title