Printable film

Patent metadata

Field	Value
Publication number	US-10406850-B2
Application number	US-201214342441-A
Country	US
Kind code	B2
Filing date	Oct 4, 2012
Priority date	Oct 7, 2011
Publication date	Sep 10, 2019
Grant date	Sep 10, 2019

Abstract

The present application relates to a film having a polyester layer comprising a blend of amorphous polyester and a copolymer of an olefin and a hydrocarbon ester of an acrylic acid, wherein the amount of copolymer is at least 30 parts per 100 parts by weight of amorphous polyester and wherein the polyester layer exhibits an E-modulus at 23 C of at least 200 N/mm2?. The application further discloses a method of making graphic with the film, in particular by ink jet printing and further discloses a method of applying the graphic to a substrate such as a building or a vehicle.

First claim

The invention claimed is:

1. Film having a polyester layer comprising
a blend of amorphous polyester and a copolymer of an olefin and a hydrocarbon ester of an acrylic acid,
wherein the amount of copolymer is at least 30 parts per 100 parts by weight of amorphous polyester and
wherein the polyester layer exhibits an E-modulus at 23° C. of at least 200 N/mm 2 .

2. Film according to claim 1 wherein said film has opposite first and second major sides and wherein said polyester layer defines the surface at the first major side.

3. Film according to claim 2 wherein said second major side comprises an adhesive layer.

4. Film according to claim 1 wherein said film is a single layer film consisting of said polyester layer.

5. Film according to claim 1 wherein said amorphous polyester has a glass transition temperature of at least 0° C.

6. Film according claim 1 wherein the amorphous polyester has an E-modulus of at least 200 N/mm 2 .

7. Film according to claim 1 wherein the amount of the copolymer is between 50 and 110 parts by weight per 100 parts of amorphous polyester.

8. Film according to claim 1 wherein the copolymer is a copolymer consisting of repeating units of an alpha olefin and one or more alkyl acrylates or methacrylates.

9. Film according to claim 1 wherein the E-modulus at 23° C. of the polyester layer is between 200 N/mm 2 and 1000 N/mm 2 .

10. A method of making a graphic suitable for application on vehicles or buildings, the method comprising printing of an ink composition on a film as defined in claim 1 and wherein said ink composition is printed on said polyester layer.

11. A method according to claim 10 wherein said ink composition comprises organic solvent.

12. A method according to claim 10 wherein an image is printed.

13. A graphic comprising the film of claim 1 having an ink composition printed on the polyester layer of a film.

14. A method of applying a graphic comprising adhering a graphic as defined in claim 13 to a vehicle or a building.

15. A film according to claim 1 wherein the polyester layer exhibits an E-modulus at 23° C. of at least 300 N/mm 2 .

Assignees

• 3M Innovative Properties Co

Inventors

• Schappert Klaus D

Classifications

• B41M5/0047 Primary

  by ink-jet printing · CPC title

• Y10T428/24802

  Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] · CPC title

• B44C1/16

  for applying transfer pictures or the like · CPC title

• B41M5/508

  Supports · CPC title

• C08L23/04

  Homopolymers or copolymers of ethene · CPC title