In situ, real-time in-line detection of filling errors in pharmaceutical product manufacturing using water proton NMR
US-11971374-B2 · Apr 30, 2024 · US
US10401313B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10401313-B2 |
| Application number | US-201715604029-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 24, 2017 |
| Priority date | May 24, 2016 |
| Publication date | Sep 3, 2019 |
| Grant date | Sep 3, 2019 |
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Downhole fluid volumes of a geological formation may be estimated using nuclear magnetic resonance (NMR) measurements, even in organic shale reservoirs. Multi-dimensional NMR measurements, such as two-dimensional NMR measurements and/or, in some cases, one or more well-logging measurements relating to total organic carbon may be used to estimate downhole fluid volumes of hydrocarbons such as bitumen, light hydrocarbon, kerogen, and/or water. Having identified the fluid volumes in this manner or any other suitable manner from the NMR measurements, a reservoir producibility index (RPI) may be generated. The downhole fluid volumes and/or the RPI may be output on a well log to enable an operator to make operational and strategic decisions for well production.
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The invention claimed is: 1. A method comprising: obtaining, using one or more downhole well-logging tools, nuclear magnetic resonance measurements and one or more additional log measurements that are at least collectively sensitive to total organic carbon in a wellbore through a geological formation, wherein the nuclear magnetic resonance measurements comprise at least T1 and T2 measurements; and using one or more processors to estimate a fluid volume of a hydrocarbon or a fluid volume of water, or both, in the geological formation at a depth of the wellbore, including by: (a) comparing expected T1-T2 responses for water and hydrocarbon to the nuclear magnetic resonance measurements to obtain the estimate of the fluid volume of the hydrocarbon or the estimate of the fluid volume of the water, or both; (b) computing an uncertainty of the estimate of the fluid volume of the hydrocarbon based at least in part on the one or more additional log measurements that are at least collectively sensitive to total organic carbon; (c) computing an uncertainty of the estimate of the fluid volume of the water based at least in part on the one or more additional log measurements that are at least collectively sensitive to total volume of water; and iteratively performing (a) and (b) or (a) and (c) using one or more variations of the expected T1-T2 response for hydrocarbon such that the uncertainty of the estimate is reduced or optimized; and using the estimate of the fluid volume of the hydrocarbon, the estimate of the fluid volume of the water, the uncertainty of the estimate of the fluid volume of the hydrocarbon, or the uncertainty of the estimate of the fluid volume of the water, or any combination thereof, to generate one or more tracks of a well log. 2. The method of claim 1 , wherein the geological formation comprises an organic shale formation. 3. The method of claim 1 , wherein the one or more tracks of the well log that are generated comprise using the estimate of the fluid volume of the hydrocarbon, the estimate of the fluid volume of the water, the uncertainty of the estimate of the fluid volume of the hydrocarbon, or the uncertainty of the estimate of the fluid volume of the water, or any combination thereof. 4. The method of claim 1 , wherein the one or more tracks of the well log that are generated comprise a reservoir producibility index computed using the estimate of the fluid volume of the hydrocarbon, the estimate of the fluid volume of the water, or both. 5. The method of claim 1 , wherein comparing the expected T1-T2 responses for water and hydrocarbon to the nuclear magnetic resonance measurements to obtain the estimate of the fluid volume of the hydrocarbon or the estimate of the fluid volume of the water, or both comprises: calculating a function of T1 distribution in relation to T2; and calculating volume fractions of one or more types of hydrocarbons and water according to a departure of each from the calculated function to estimate the fluid volume of the hydrocarbon or the estimate of the fluid volume of the water, or both. 6. The method of claim 5 , wherein the function of T1 distribution in relation to T2 comprises a logarithmic mean. 7. The method of claim 5 , wherein the one or more types of hydrocarbon fluids comprise at least bitumen and light hydrocarbon. 8. The method of claim 1 , wherein computing the uncertainty of the estimate of the fluid volume of the hydrocarbon based at least in part on the one or more additional log measurements that are at least collectively sensitive to total organic carbon comprises: calculating a volume of kerogen based at least in part on NMR porosity; calculating a total organic carbon due to bitumen and light hydrocarbon based at least in part on the one or more additional log measurements that are at least collectively sensitive to total organic carbon and the volume of kerogen calculated based at least in part on the NMR porosity; calculating an apparent total organic carbon from NMR; and calculating an absolute difference between the apparent total organic carbon from NMR the total organic carbon from the one or more additional log measurements that are at least collectively sensitive to total organic carbon to obtain the uncertainty of the estimate of the fluid volume of the hydrocarbon. 9. The method of claim 1 , wherein computing the uncertainty of the estimate of the fluid volume of the water based at least in part on the one or more additional log measurements that are at least collectively sensitive to total volume of water comprises: calculating a total volume of water based at least in part on the one or more additional log measurements that are at least collectively sensitive to total volume of water; calculating an apparent total volume of water from NMR; and calculating an absolute difference between the apparent total volume of water from NMR and the total volume of water from the one or more additional log measurements that are at least collectively sensitive to total volume of water to obtain the uncertainty of the estimate of the fluid volume of the water.
Relaxometry, i.e. quantification of relaxation times or spin density (G01R33/50 takes precedence) · CPC title
Measurement of solid, liquid or gas content · CPC title
operating with electron or nuclear magnetic resonance · CPC title
Making measurements of geologic samples, e.g. measurements of moisture, pH, porosity, permeability, tortuosity or viscosity · CPC title
Cross-Sectional Technologies · mapped topic
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