Two stage upgrading of light olefins

Patent metadata

Field	Value
Publication number	US-10400182-B2
Application number	US-201815871614-A
Country	US
Kind code	B2
Filing date	Jan 15, 2018
Priority date	Jan 20, 2017
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

The present disclosure relates generally processes and systems for converting a mixture of light hydrocarbons to liquid transportation fuels by first cracking the light hydrocarbons to an intermediate comprising olefins, which is converted by contacting with a catalyst comprising at least one zeolite in two separate conversion stages with an intervening recovery of liquid product. The first stage conversion favors oligomerization of larger olefins to form diesel range products that are collected prior to directing unconverted smaller olefins to be oligomerized in a second stage conversion conducted at a higher temperature and lower pressure.

First claim

We claim:

1. A method for converting a light hydrocarbon feedstock to produce liquid transportation fuels, the method comprising:
a) providing a light hydrocarbon feedstock comprising at least 80 wt % of hydrocarbon molecules that contain five or less carbon atoms;
b) thermally cracking the light hydrocarbon feedstock in a cracking unit to produce a raw cracked gas stream comprising ethylene, propylene, butenes, acetylene and dienes, hydrogen, methane and unconverted feedstock;
c) quenching and partially condensing the raw cracked gas stream to produce pyrolysis gasoline comprising molecules containing five or more carbon atoms and a raw cracked olefins stream comprising predominantly C2-C4 hydrocarbons selected from ethene, propene, acetylene, butenes and dienes and also hydrogen, methane, carbon monoxide, carbon dioxide and unconverted hydrocarbon feedstock;
d) contacting the raw cracked olefins stream with a first catalyst comprising a zeolite in a first stage conversion reactor at a first temperature that is between 180° C. to 300° C. and a first pressure that is between 300 psig and 500 psig, wherein the first catalyst, the first temperature and the first pressure in the first stage conversion reactor are configured to produce a first stage effluent comprising at least 10 wt % of hydrocarbons that are characterized by a boiling point ranging from 193° C. to 360° C. at 1 atm;
e) separating the first stage effluent in a first separator to produce a first condensed liquid hydrocarbons comprising at least five carbon atoms, and an unconverted light olefin stream comprising four or less carbon atoms;
f) converting the unconverted light olefin stream by contacting with a second catalyst in a second stage conversion reactor maintained at a second pressure that is in a range between about 14 psig and 300 psig and at least 100 psig less than the first pressure and a second temperature that is in a range between 300° C. and 450° C. and at least 20° C. higher than the first temperature, to produce a second stage effluent;
g) separating the second stage effluent in a second separator to produce an unconverted light gas stream comprising four or less carbon atoms, and a second condensed liquid hydrocarbons comprising at least five carbon atoms.

2. The method of claim 1 , wherein the light hydrocarbon feedstock comprises at least 90 wt % of hydrocarbon molecules that contain five or less carbon atoms.

3. The method of claim 1 , wherein the light hydrocarbon feedstock comprises at least 90 wt % of hydrocarbon molecules that contain four or less carbon atoms.

4. The method of claim 1 , wherein the light hydrocarbon feedstock comprises at least 97 wt % of hydrocarbon molecules that contain six or less carbon atoms.

5. The method of claim 1 , wherein the first catalyst, the first temperature and the first pressure in the first stage conversion reactor are configured to produce a first stage effluent comprising at least 15 wt % of hydrocarbons that are characterized by a boiling point ranging from 193° C. to 360° C. at 1 atm.

6. The method of claim 1 , wherein the first catalyst, the first temperature and the first pressure in the first stage conversion reactor are configured to produce a first stage effluent comprising at least 60 wt. % of hydrocarbon molecules that are characterized by a boiling point that ranges from 40° C. to 360° C.

7. The method of claim 1 , wherein the first temperature is in a range between 200° C. and 260° C.

8. The method of claim 1 , wherein the second temperature is in a range between 320° C. and 365° C. and the second pressure is in a range from 40 psig to 200 psig.

9. The method of claim 1 , wherein the second temperature is at least 25° C. higher than the first temperature.

10. The method of claim 1 , wherein the second catalyst in the second stage conversion reactor comprises at least one zeolite.

11. The method of claim 1 , wherein the first catalyst in the first stage conversion reactor and the second catalyst in the second stage conversion reactor each comprise ZSM-5 zeolite.

12. The method of claim 1 , wherein the first temperature is in a range between 200° C. and 260° C. and the first pressure is in a range between 300 psig and 500 psig, while the second temperature is in a range between 320° C. and 365° C. and the second pressure is in a range from 40 psig to 200 psig.

13. The method of claim 1 , wherein the first stage effluent comprises more hydrocarbons, based on weight, that are characterized by a boiling point in a range from 193° C. to 360° C. at 1 atm than the second stage effluent.

14. The method of claim 1 , wherein the light hydrocarbon feedstock is a Y-grade fraction of natural gas liquids.

15. The method of claim 1 , further comprising mixing the first condensed liquid hydrocarbons and the second condensed liquid hydrocarbons to produce final liquid product hydrocarbons comprising hydrocarbon molecules that are characterized by a boiling point in a range of gasoline or diesel.

16. The method of claim 1 , wherein the unconverted light gas stream in the step g) is separated into (i) a light hydrocarbons recycle stream that is fed upstream of the cracking unit and (ii) a hydrogen stream.

Assignees

• Phillips 66 Co

Inventors

• Yao Jianhua
• Xie Hong
• Randolph Bruce B
• Lusk Steven E
• Ghonasgi Dhananjay B
• Marda Jonathan R

Classifications

• C10G2300/1088

  Olefins · CPC title

• C10G2400/02

  Gasoline · CPC title

• B01D3/143

  by two or more of a fractionation, separation or rectification step · CPC title

• B01J29/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively · CPC title

• C10G50/00 Primary

  Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation · CPC title