Olefin oxidation process, reaction apparatus and system

Patent metadata

Field	Value
Publication number	US-10400179-B2
Application number	US-201515515187-A
Country	US
Kind code	B2
Filing date	Sep 29, 2015
Priority date	Sep 29, 2014
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

This invention discloses an olefin oxidation process, including a step of under olefin oxidation conditions, successively passing a reaction feed from the No.1 catalyst bed through the No.n catalyst bed, wherein if the apparent velocity of each of the reaction materials passing from the No.1 catalyst bed through the No.n catalyst bed is respectively named as v1 to vn, and if m represents any integer in the region [2, n], the relationship vm-1<vm holds. The process according to this invention is capable of extending the service life of the catalyst, especially the single-pass service life thereof, and at the same time, suppressing any side-reaction over a prolonged period of time. This invention further discloses a fixed-bed reaction apparatus and a system for olefin oxidation.

First claim

We claim:

1. An olefin oxidation process, comprising a step of successively passing a reaction mixture comprising an olefin and at least one oxidant through n catalyst beds respectively designated as No.1 catalyst bed through No. n catalyst bed, wherein an apparent velocity of the reaction mixture at the No.1 catalyst bed through the No. n catalyst bed are respectively designated as v 1 to v n , and
v m-1 <v m ,
wherein n represents an integer in the range of from 2 to 50, and m represents an integer from 2 to n.

2. The process according to claim 1 , wherein
A m-1 /A m >1,
wherein A m-1 represents an averaged cross-sectional area of the No. m−1 catalyst bed, A m represents an averaged cross-sectional area of the No. m catalyst bed.

3. The process according to claim 1 , further comprising the step of obtaining a reaction discharge comprising an olefin oxide; and isolating the olefin oxide from the reaction discharge, wherein the reaction discharge depleted of the olefin oxide forms an exhaust stream.

4. The process according to claim 3 , wherein a compartment is disposed between two adjacent catalyst beds among the n catalyst beds, further comprising introducing a carrier fluid into the compartment, wherein the carrier fluid is at least one selected from the group consisting of the reaction discharge, a solvent, an inert gas, and the exhaust stream.

5. The process according to claim 1 , wherein each of the n catalyst beds are independently loaded with at least one titanium silicalite.

6. The process according to claim 1 , wherein in the reaction feed, a molar ratio of the olefin to the at least one oxidant is 0.1-10:1, and a weight hourly space velocity of the olefin is 0.1-20 h −1 , based on a total amount of catalyst loaded in the n catalyst beds, wherein a reaction pressure (gauge) is 0-5 MPa, and a reaction temperature is 0-120 degrees Celsius.

7. The process according to claim 1 , wherein
T m-1 −T m =5 to 30,
wherein T m-1 represents reaction temperature (in degree Celsius) across the No. m−1 catalyst bed, and T m represents reaction temperature (in degree Celsius) across the No. m catalyst bed.

8. A fixed-bed reaction apparatus, comprising an entrance, a reaction zone, n catalyst beds designated as No. 1 catalyst bed through No. n catalyst bed arranged within the reaction zone, and an exit, wherein a reaction mixture enters the reaction zone via the entrance and successively passes through the n catalyst beds, and then discharges from the exit as a reaction discharge, wherein the fixed-bed reaction apparatus further comprises a speed-increasing means arranged in such a manner that, when the apparent velocity of the reaction mixture passing through each of the No. 1 catalyst bed through the No. n catalyst bed are respectively designated as v 1 to v n , the following relationship holds,
v m-1 <v m ,
wherein n represents an integer in the range of from 2 to 50, and m represents any integer from 2 to n.

9. The fixed-bed reaction apparatus according to claim 8 , wherein the speed-increasing means is a diameter-changing section of the reaction zone and/or an internal arranged within the reaction zone, and the diameter-changing section or the internal is arranged in such a manner that the following relationship holds,
A m-1 /A m >1,
wherein A m-1 represents an averaged cross-sectional area of the No. m−1 catalyst bed, A m represents an averaged cross-sectional area of the No. m catalyst bed.

10. The fixed-bed reaction apparatus according to claim 8 , wherein the speed-increasing means is a reaction discharge introduction conduit, a solvent introduction conduit, an inert gas introduction conduit or any combination thereof, wherein the reaction discharge introduction conduit is arranged to introduce a part of the reaction discharge into one or more compartments, the solvent introduction conduit is arranged to introduce a solvent into one or more compartments, and the inert gas introduction conduit is arranged to introduce an inert gas into one or more compartments, wherein each of the one or more compartments is located between two adjacent catalyst beds among the n catalyst beds.

11. A system for olefin oxidation, comprising at least a reaction feed unit, an olefin oxidation reaction unit, and a reaction discharge separation unit, wherein the olefin oxidation reaction unit comprises one or more fixed-bed reaction apparatuses according to claim 8 .

12. The system according to claim 11 , wherein the reaction discharge separation unit isolates an olefin oxide from the reaction discharge of the fixed-bed reaction apparatus to form an exhaust stream that is depleted of olefin oxide, and wherein the speed-increasing means is an exhaust stream introduction conduit arranged to introduce the exhaust stream or a part thereof into one or more compartments in the fixed-bed apparatus, wherein each of the one or more compartments is disposed between two adjacent catalyst beds among the n catalyst beds.

13. The fixed-bed reaction apparatus according to claim 8 , wherein n represents 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19 or 20.

14. The fixed-bed reaction apparatus according to claim 8 , wherein n represents 2, 3, 4, 5, 6, 7, 8, 9 or 10.

15. The fixed-bed reaction apparatus according to claim 8 , wherein the speed-increasing means is arranged in such a manner that the following relationship holds:
v m /v m-1 =1.5 to 15.

16. The fixed-bed reaction apparatus according to claim 8 , wherein the speed-increasing means is arranged in such a manner that the following relationship holds:
v m /v m-1 =2 to 10.

17. The fixed-bed reaction apparatus according to claim 9 , wherein the diameter-changing section or the internal is arranged in such a manner that the following relationship holds:
1< A m-1 /A m ≤15.

18. The fixed-bed reaction apparatus according to claim 9 , wherein the diameter-changing section or the internal is arranged in such a manner that the following relationship holds:
1.5≤ A m-1 /A m ≤10.

19. The process according to claim 1 , wherein the olefin is at least one selected from C 3-6 α-olefins, and the at least one oxidant is at least one selected from the group consisting of hydrogen peroxide, organic peroxides, and peracids.

20. The process according to claim 1 , wherein v m /v m-1 =1.5 to 15, wherein m represents an integer from 2 to n.

Assignees

• China Petroleum & Chem Corp
• Sinopec Res Inst Petroleum

Inventors

• Shi Chunfeng
• Long Jun
• Zhu Bin
• Lin Min

Classifications

• C07D301/12 Primary

  with hydrogen peroxide or inorganic peroxides or peracids · CPC title

• C07D301/19

  with organic hydroperoxides · CPC title

• C07D303/04

  containing only hydrogen and carbon atoms in addition to the ring oxygen atoms · CPC title

• B01J20/04

  comprising compounds of alkali metals, alkaline earth metals or magnesium · CPC title

• B01J21/04

  Alumina · CPC title