Process for the preparation of carbon fiber-carbon nanotubes reinforced hybrid polymer composites for high strength structural applications

Patent metadata

Field	Value
Publication number	US-10400074-B2
Application number	US-201715792831-A
Country	US
Kind code	B2
Filing date	Oct 25, 2017
Priority date	Oct 25, 2016
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

The present invention relates to the development of carbon fiber carbon nanotubes reinforced polymer composites for high strength structural applications. It is very difficult to incorporate higher amount of carbon fiber >60 vol % in any of the polymer matrix. Beyond this loading the mechanical properties of these composite starts deteriorate. Therefore, further improvement in the mechanical properties is not possible. Herein, a novel method is developed to fabricate the hybrid carbon fiber epoxy composites reinforced with multiwalled carbon nanotubes. The flexural strength of the hybrid composites (˜45 vol % CF+CNT) was achieved more than 600 MPa which is more than 35% over pure carbon fiber/epoxy composites (˜50 vol % CF). These high strength hybrid composites can be used in wind mill blades, turbine blades, sport industries, automobile and airframe.

First claim

The invention claimed is:

1. A process for the preparation of carbon fiber carbon nanotubes (CNTs) reinforced polymer composites wherein the steps comprising:
a) mixing 0.1 to 0.5% (w/w) of multi walled carbon nanotubes (MWCNTs) having a diameter in the range of 20 to 100 nm and a length in the range of 20 to 200 microns with 45 to 55 g of epoxy polymer pre heated at a temperature ranging from 40 to 60 degree C. and homogenizing for 5 to 30 min to obtain a mixture;
b) adding a hardener at 23% by weight of epoxy to the mixture obtained in step [a] followed by stirring for 2 to 10 min using a magnetic stirrer;
c) cutting six layers of Carbon fiber cloth (CF) of dimension 14 cm×17 cm each from a carbon fiber cloth sheet;
d) dispersing the MWCNTs having the diameter in the range of 20 to 100 nm and the length in the range of 20 to 200 microns in a solvent with a high energy homogenizer for 10 to 15 min;
e) sonicating the MWCNTs obtained in step [d] for a period of 20 to 40 min and again homogenizing for 5 to 10 min to obtain homogenized MWCNTs;
f) fabricating five MWCNT papers having a dimension of 20 cm×20 cm using the homogenized MWCNTs obtained in step [e] by vacuum filtration;
g) cutting the MWCNT papers obtained in step [f] to a dimension of 14 cm×17 cm length; and
h) applying the mixture obtained in step [b] on both sides of the six layers of the CF as obtained in step [c] and the MWCNT papers as obtained in step [g] and stacking them alternately and sandwiched between die steel plates, followed by pressing at 100 to 150 kg/cm 2 first at a temperature ranging from 70 to 90 degree C. for a period of 1.5 to 2.5 h and then at a temperature ranging from 140 to 160 degree C. for a period of 3.5 to 4.5 h, followed by cooling at room temperature to obtain the desired CNTs reinforced polymer composites.

2. The process as claimed in claim 1 , wherein the epoxy polymer is selected from a thermosetting resin.

3. The process as claimed in claim 2 , wherein the thermosetting resin is epoxy resins or polyesters.

4. The process as claimed in claim 1 , wherein the CNTs are MWCNTs.

5. The process as claimed in claim 1 , wherein the CNTs are selected from the group consisting of arc discharged based and chemical vapor deposition (CVD) based CNTs.

6. The process as claimed in claim 1 , wherein the vacuum filtration is carried out using a vacuum filtration unit comprising a top, filter paper/nylon cloth, metallic sieve, bottom tank, silicon sheet, nut and bolt, silicon O-ring, vacuum port and rotary pump.

7. The process as claimed in claim 1 , wherein the pressing is done using a hydraulic press with heater.

8. The process as claimed in claim 1 , wherein the solvent is selected from the group consisting of water, chloroform, toluene, N-methyl pyrolidone, ethanol, acetone and combinations thereof.

Assignees

• Council Scient Ind Res

Inventors

• Singh Bhanu Pratap
• Teotia Satish
• Dhakate Sanjay Rangnath

Classifications

• C08J5/042

  with carbon fibres · CPC title

• B29C70/081

  Combinations of fibres of continuous or substantial length and short fibres · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• D06M15/55

  Epoxy resins · CPC title

• C08J5/06

  using pretreated fibrous materials · CPC title