Forming a surface layer of a ceramic matrix composite article

Patent metadata

Field	Value
Publication number	US-10399911-B2
Application number	US-201615005790-A
Country	US
Kind code	B2
Filing date	Jan 25, 2016
Priority date	Jan 27, 2015
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

The disclosure describes techniques for forming a surface layer of an article including a CMC using a cast. In some examples, the surface layer includes three-dimensional surface features, which may increase adhesion between the CMC and a coating on the CMC. In some examples, the surface layer may include excess material, with or without three-dimensional surface features, which is on the CMC. The excess material may be machined to remove some of the excess material and facilitate conforming the article to dimensional tolerances, e.g., for fitting the article to another component. The excess material may reduce a likelihood that the CMC (e.g., reinforcement material in the CMC) is damaged by the machining.

First claim

What is claimed is:

1. A method comprising:
filling a cast with a slurry;
depositing the slurry on a surface of an impregnated porous preform using the cast to form a surface layer including a plurality of three-dimensional surface features, wherein the cast defines the negative of the three-dimensional surface features, and wherein the impregnated porous preform comprises a reinforcement material and at least one matrix precursor;
drying the slurry to form a greenbody preform; and
infiltrating the greenbody preform with a molten infiltrant to form a composite article including the three-dimensional surface features.

2. The method of claim 1 , wherein:
the slurry comprises a first slurry; and
the method further comprises, prior to depositing the first slurry on the surface of the impregnated porous preform:
impregnating a porous preform with a second slurry; and
drying the second slurry to form the impregnated porous preform.

3. The method of claim 2 , wherein a composition of the first slurry is different than a composition of the second slurry.

4. The method of any claim 1 , wherein depositing the slurry on the surface of the impregnated porous preform using the cast to form the surface layer including the plurality of three dimensional features comprises stamping the slurry on the surface of the impregnated porous preform using the cast to form the surface layer including the plurality of three dimensional features.

5. The method of claim 1 , wherein the three-dimensional surface features comprise at least one of depressions, grooves, ridges, or protrusions.

6. The method of claim 1 , wherein the plurality of three-dimensional surface features extend over only part of the surface.

7. The method of claim 1 , further comprising forming a bond coating on the surface layer including the plurality of three-dimensional surface features, wherein the bonding coat comprises silicon.

8. The method of claim 1 , further comprising forming an environmental barrier coating on the surface layer including the plurality of three-dimensional surface features, wherein the environmental barrier coating comprises at least one of barium strontium aluminosilicate, strontium aluminosilicate, barium aluminosilicate, a rare earth disilicate, or a rare earth monosilicate.

9. The method of claim 8 , further comprising forming a CMAS-resistant coating on the environmental barrier coating, wherein the CMAS-resistant coating comprises a rare earth oxide, silica, and an alkali oxide and is essentially free of zirconia and hafnia.

10. The method of claim 1 , further comprising forming an abradable coating on the surface layer including the plurality of three-dimensional surface features, wherein the abradable coating comprises at least one of barium strontium aluminosilicate, strontium aluminosilicate, barium aluminosilicate, a rare earth disilicate, or a rare earth monosilicate, and wherein the abradable coating comprises porosity between about 10 vol. % and about 50 vol. %.

11. The method of claim 1 , further comprising:
3D printing a master mold defining the geometry of the three-dimensional surface features; and
forming the cast as the negative of the master mold.

12. A method comprising:
placing a porous preform in a mold adjacent a cast, wherein the cast defines a negative of a plurality of three-dimensional surface features and a space between a surface of the porous preform and the cast;
impregnating the porous preform and the space between the surface of the porous preform and the cast with a slurry to form an impregnated porous preform including a surface layer including the plurality of three-dimensional surface features, wherein shapes of respective three-dimensional surface features of the plurality of three-dimensional surface features are defined by the negative of the plurality of three-dimensional surface features defined by the cast;
drying the slurry to form a greenbody preform; and
infiltrating the greenbody preform with a molten infiltrant to form a composite article including the three-dimensional surface features.

13. The method of claim 12 , wherein the three-dimensional surface features comprise at least one of depressions, grooves, ridges, or protrusions.

14. The method of claim 12 , wherein the plurality of three-dimensional surface features extend over only part of the surface.

15. The method of claim 12 , further comprising forming a bond coating on the surface layer including the plurality of three-dimensional surface features, wherein the bonding coat comprises silicon.

16. The method of claim 12 , further comprising forming an environmental barrier coating on the surface layer including the plurality of three-dimensional surface features, wherein the environmental barrier coating comprises at least one of barium strontium aluminosilicate, strontium aluminosilicate, barium aluminosilicate, a rare earth disilicate, or a rare earth monosilicate.

17. The method of claim 12 , further comprising forming an abradable coating on the surface layer including the plurality of three-dimensional surface features, wherein the abradable coating comprises at least one of barium strontium aluminosilicate, strontium aluminosilicate, barium aluminosilicate, a rare earth disilicate, or a rare earth monosilicate, and wherein the abradable coating comprises porosity between about 10 vol. % and about 50 vol. %.

18. The method of claim 16 , further comprising forming a CMAS-resistant coating on the environmental barrier coating, wherein the CMAS-resistant coating comprises a rare earth oxide, silica, and an alkali oxide and is essentially free of zirconia and hafnia.

19. The method of claim 12 , further comprising:
3D printing a master mold defining the geometry of the three-dimensional surface features; and
forming the cast as the negative of the master mold.

Assignees

• Rolls Royce Corp
• Rolls Royce High Temperature Composites Inc

Inventors

• Shim Sungbo
• Thibault Robert Wesley
• Shinavski Robert
• Lee Kang N

Classifications

• C04B2237/61

  Joining two substrates of which at least one is porous by infiltrating the porous substrate with a liquid, such as a molten metal, causing bonding of the two substrates, e.g. joining two porous carbon substrates by infiltrating with molten silicon · CPC title

• C04B2237/38

  Fiber or whisker reinforced · CPC title

• C04B2237/348

  Zirconia, hafnia, zirconates or hafnates · CPC title

• C04B2237/346

  Titania or titanates · CPC title

• C04B2237/343

  Alumina or aluminates · CPC title