Glass sheet and method for producing glass sheet

Patent metadata

Field	Value
Publication number	US-10399894-B2
Application number	US-201414777280-A
Country	US
Kind code	B2
Filing date	Mar 18, 2014
Priority date	Mar 19, 2013
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

The glass sheet of the present invention is a glass sheet with a thickness of 1.6 mm or less produced by a float process in which a molten glass material is formed into a sheet on a molten metal. When one surface of the glass sheet kept in contact with the molten metal during the formation of the molten glass material into the glass sheet is defined as a first surface and the other surface of the glass sheet opposite to the first surface is defined as a second surface, at least the first surface has been subjected to a treatment for forming a densified dealkalized layer therein. An etching rate ER 1 (nm/min) of the first surface and an etching rate ER 2 (nm/min) of the second surface satisfy a relation of ER 2 /ER 1 ≤0.8 when the first surface and the second surface are etched using 0.1 mass % hydrofluoric acid at 50° C. as an etching liquid.

First claim

The invention claimed is:

1. A glass sheet with a thickness of 1.6 mm or less produced by a float process in which a molten glass material is formed into a sheet on a molten metal, wherein
when one surface of the glass sheet kept in contact with the molten metal during the formation of the molten glass material into the glass sheet is defined as a first surface and the other surface of the glass sheet opposite to the first surface is defined as a second surface, at least the first surface has been subjected to a single treatment for forming a densified dealkalized layer therein at a treatment temperature at or within a range of 410° C. to 580° C., and
an etching rate ER 1 (nm/min) of the first surface and an etching rate ER 2 (nm/min) of the second surface satisfy a relation of ER 2 /ER 1 ≤0.8 when the first surface and the second surface are etched using 0.1 mass % hydrofluoric acid at 50° C. as an etching liquid, and
the etching rate ER 1 is 10 nm/min or more.

2. The glass sheet according to claim 1 , wherein ER 1 and ER 2 satisfy a relation of ER 2 /ER 1 ≤0.7.

3. The glass sheet according to claim 2 , wherein the second surface has been subjected to a treatment for forming a densified dealkalized layer therein.

4. The glass sheet according to claim 1 , wherein the second surface has been subjected to a treatment for forming a densified dealkalized layer therein.

5. A method for producing a glass sheet with a thickness of 1.6 mm or less, comprising the steps of:
(I) forming a molten glass material into a glass ribbon on a molten metal; and
(II) subjecting at least one surface of the glass ribbon kept in contact with the molten metal in the step (I) to a single treatment for forming a densified dealkalized layer therein at a treatment temperature at or within a range of 410° C. to 580° C. so that an etching rate ER 1 (nm/min) of the one surface of the glass ribbon defined as a first surface and an etching rate ER 2 (nm/min) of the other surface of the glass ribbon defined as a second surface opposite to the first surface satisfy a relation of ER 2 /ER 1 ≤0.8 when the first surface and the second surface are etched using 0.1 mass % hydrofluoric acid at 50° C. as an etching liquid, wherein
the treatment temperature for a portion of the treatment for forming the densified dealkalized layer is less than 500° C.

6. The method for producing a glass sheet according to claim 5 , further comprising, after the step (II), a step of (III) subjecting a glass sheet obtained by cutting the glass ribbon to chemical strengthening by alkali ion exchange.

Assignees

• Nippon Sheet Glass Co Ltd

Inventors

• Hotta Hirofumi
• Mitani Kazuishi
• Saito Yasuhiro

Classifications

• C03C15/00 Primary

  Surface treatment of glass, not in the form of fibres or filaments, by etching (etching or surface-brightening compositions, in general C09K13/00) · CPC title

• C03C3/087

  containing calcium oxide, e.g. common sheet or container glass · CPC title

• C03C21/002

  to perform ion-exchange between alkali ions (C03C21/005 takes precedence) · CPC title

• C03B18/14

  Changing the surface of the glass ribbon, e.g. roughening (by chemical methods C03C) · CPC title

• C03C21/007 Primary

  in gaseous phase · CPC title