Planar composite having layers of plastic of different damping properties

Patent metadata

Field	Value
Publication number	US-10399736-B2
Application number	US-201314415713-A
Country	US
Kind code	B2
Filing date	Jul 18, 2013
Priority date	Jul 19, 2012
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

The present invention relates generally to a planar composite including, as a layer sequence, a first PE blend layer, a carrier layer, a barrier layer, and a further PE blend layer. The first PE blend layer or the further PE blend layer in each case includes in a range of from 10 to 50 wt. %, in each case based on the blend, a first LDPEa, and a further LDPEt to the extent of at least 50 wt. %, in each case based on the blend. The present invention furthermore relates to a process for the production of the planar composite, a container which surrounds an interior and comprises at least one such planar composite, and a process for the production of the container including the steps of provision of the planar composite of the abovementioned layer construction, folding, joining and optionally filling and closing of the container.

First claim

The invention claimed is:

1. A planar composite comprising as a layer sequence:
a carrier layer; and
a barrier layer,
wherein the layer sequence comprises a first PE blend layer;
wherein the first PE blend layer comprises in a range of from 10 to 50 wt. % of a first LDPEa, and a further LDPEt to the extent of at least 50 wt. %, in each case based on the blend; and
wherein the first PE blend layer has a damping factor difference in a range of from −0.3 to −0.6,
wherein the damping factor difference calculated from:
damping factor difference=log(tan δ) f″=0.1 Hz −log(tan δ) f′=0.01 Hz ,

wherein the damping factor δ is defined by: damping factor δ=arctan(G″/G′),
wherein G′ is the storage modulus and G″ is the loss modulus,
wherein G′ and G″ are determined from shear rheology measurements conducted with a plate-plate geometry, at a sample temperature of 170° C. and a deformation amplitude of y=5%.

2. The planar composite according to claim 1 , wherein the layer sequence comprises a further PE blend layer;
wherein the further PE blend layer comprises in a range of from 10 to 50 wt. % of a first LDPEa, and a further LDPEt to the extent of at least 50 wt. %, in each case based on the blend; and
wherein the further PE blend layer has a damping factor difference in a range of from −0.3 to −0.6.

3. The planar composite according to claim 1 , wherein an additional PE blend layer is provided between the carrier layer and the barrier layer;
wherein the additional PE blend layer comprises in a range of from 10 to 50 wt. % of a first LDPEa, and a further LDPEt to the extent of at least 50 wt. %, in each case based on the blend.

4. The planar composite according to claim 1 , wherein the first LDPEa has a damping factor difference of greater than −0.4; and
wherein the further LDPEt has a damping factor difference of less than −0.4.

5. The planar composite according to claim 1 , wherein the carrier layer comprises a cardboard.

6. The planar composite according to claim 1 , wherein the first LDPEa or the further LDPEt has a mass density in a range of from 0.915 g/cm 3 to 0.940 g/cm 3 .

7. The planar composite according to claim 1 , wherein the barrier layer is one or a combination of at least two of a barrier layer of plastic, a metal layer, and a metal oxide layer.

8. The planar composite according to claim 1 , wherein the carrier layer has at least one hole which is covered at least with the barrier layer and at least with the first PE blend layer, a further PE blend layer, or an additional PE blend layer or a combination of at least two of these as a hole-covering layer.

9. A process for the production of a planar composite, wherein the planar composite comprises a carrier layer and a barrier layer, the process comprising the steps of:
provision of a first LDPEa and a further LDPEt,
wherein the first LDPEa has a damping factor difference of greater than −0.4, and wherein the further LDPEt has a damping factor difference of less than −0.4;
mixing of the first LDPEa and the further LDPEt to give a PE blend,
wherein the PE blend has a damping factor difference in a range of from −0.3 to −0.6,
wherein the PE blend comprises in a range of from 10 to 50 wt. %, in each case based on the blend, the first LDPEa, and the further LDPEt to the extent of at least 50 wt. %, in each case based on the PE blend;
application of the PE blend to a composite precursor, wherein the composite precursor comprises a carrier layer;
wherein the damping factor difference is calculated from:
damping factor difference=log(tan δ) f″=0.1 Hz −log(tan δ) f′=0.01 Hz ,

wherein the damping factor δ is defined by: damping factor δ=arctan(G″/G′),
wherein G′ is the storage modulus and G″ is the loss modulus,
wherein G′ and G″ are determined from shear rheology measurements conducted with a plate-plate geometry, at a sample temperature of 170° C. and a deformation amplitude of y=5%.

10. The process according to claim 9 , wherein the mixing is carried out in a melt including the first LDPEa and the further LDPEt.

11. The process according to claim 9 , wherein the application is carried out through a slot.

12. The process according to claim 11 , wherein the slot and the composite precursor move relative to one another.

13. A planar composite obtainable by a process for the production of a planar composite, wherein the planar composite comprises a carrier layer and a barrier layer, the process comprising the steps of:
provision of a first LDPEa and a further LDPEt,
wherein the first LDPEa has a damping factor difference of greater than −0.4, and wherein the further LDPEt has a damping factor difference of less than −0.4;
mixing of the first LDPEa and the further LDPEt to give a PE blend,
wherein the PE blend comprises in a range of from 10 to 50 wt. %, in each case based on the blend, the first LDPEa, and the further LDPEt to the extent of at least 50 wt. %, in each case based on the PE blend;
application of the PE blend to a composite precursor, wherein the composite precursor comprises a carrier layer;
wherein the damping factor difference is calculated from:
damping factor difference=log(tan δ) f″=0.1 Hz −log(tan δ) f′=0.01 Hz ,

wherein the damping factor δ is defined by: damping factor δ=arctan(G″/G′),
wherein G′ is the storage modulus and G″ is the loss modulus,
wherein G′ and G″ are determined from shear rheology measurements conducted with a plate-plate geometry, at a sample temperature of 170° C. and a deformation amplitude of y=5%,
wherein the PE blend has a damping factor difference in a range of from −0.3 to −0.6.

14. A container which surrounds an interior and comprises at least one planar composite according to claim 1 .

15. A process for the production of a container which surrounds an interior, the process comprising the steps of:
provision of a planar composite according to claim 1 ;
folding of the planar composite to form a fold having at least two fold surfaces adjacent to one another,
wherein a further PE layer faces the interior of the container;
joining at least a part of the at least two fold surfaces to form a container region; and
closing of the folded, planar composite with a closing tool.

16. The process according claim 15 , wherein the folding is carried out in a temperature range of from 10 to 50° C.

17. The process according claim 15 , wherein the joining step is carried out by irradiation, contact with a hot solid, by mechanical vibration or hot gas or a combination of at least two of these.

18. The process according to claim 15 , wherein the container is filled with a foodstuff before the folding step or after the joining step.

19. The process according to claim 15 , wherein the planar composite has at least one score and the fold is effected along the score.

20. A container obtainable by a process for the production of a container which surrounds an interior, the process comprising the steps of:
provision of a planar composite according to claim 1 ;
folding of the planar composite to form a fold having at least two fold surfaces adjacent to one another,
wherein a further PE layer faces the interior of the container;
joining at least a part of the at least two fold surfaces to form a container region; and
closing of the folded, planar composite with a closing tool.

Assignees

• Sig Technology Ag

Inventors

• Duisken Mike
• Bothor Roland

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L23/06

  Polyethylene · CPC title

• B31B50/64

  by applying heat or pressure, e.g. by welding (to unite areas where adhesives are applied B31B50/62) · CPC title

• B32B2307/7244

  Oxygen barrier · CPC title

• Y10T428/1352

  Polymer or resin containing [i.e., natural or synthetic] · CPC title