Method for coating with dispersions of active ingredients coated in a polymer layer

Patent metadata

Field	Value
Publication number	US-10399115-B2
Application number	US-201113521652-A
Country	US
Kind code	B2
Filing date	Jan 11, 2011
Priority date	Jan 11, 2010
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

The invention seeks protection for a novel method for the surface functionalization of solid materials with one or more active ingredients intended to confer specific properties thereon, such as anti-UV, fluorescence or coloring properties.

First claim

The invention claimed is:

1. A process of forming a coating based on at least one active ingredient at a surface of a substrate, said process comprising:
(1) obtaining an aqueous dispersion of nanoparticles comprising a core consisting of one or more active ingredient(s), the core is directly coated with an outer layer formed of one or more hydrophilic polymer(s), said active ingredient(s) and hydrophilic polymer(s) being combined in an active ingredient(s)/hydrophilic polymer(s) ratio by weight varying from 0.2 to 0.4;
(2) bringing said surface of said substrate into contact with said aqueous dispersion; and
(3) exposing said substrate obtained on conclusion of (2) to conditions propitious to the formation, at the surface of said substrate, of a polymeric film formed of said nanoparticles;

wherein said one or more active ingredient(s) is (are) chosen from organic UV-absorbing compounds, inorganic UV screening agents and fluorescent agents,
wherein said nanoparticles of (1) are prepared according to a process comprising:
obtaining an organic phase comprising said one or more active ingredient(s) in a solute state;
obtaining an aqueous phase comprising the one or more hydrophilic polymer(s);
adding the organic phase to the aqueous phase under conditions propitious to the formation of an emulsion, wherein the organic phase is dispersed in the aqueous phase, and wherein the emulsion includes at least one surfactant capable of stabilizing the emulsion;
carrying out a thermal quenching of the emulsion thus obtained in order to form said nanoparticles; and

isolating said nanoparticles.

2. The process of claim 1 , wherein the substrate is an organic substrate.

3. The process of claim 1 , wherein the combined stages (2) and (3) are repeated at least once on conclusion of (3).

4. The process of claim 1 , wherein the coating of said substrate obtained on conclusion of said process has a density of active ingredient(s) at least equal to 1 g per m 2 of coating.

5. The process of claim 1 , wherein (3) is a drying stage.

6. The process of claim 1 , wherein the one or more hydrophilic polymer(s) have a molecular weight of greater than 10,000 g/mol.

7. The process of claim 1 , wherein the one or more hydrophilic polymer(s) have a molecular weight of greater than 20,000 g/mol.

8. The process of claim 1 , wherein the one or more hydrophilic polymer(s) have a molecular weight varying from 25,000 to 600,000 g/mol.

9. The process of claim 1 , wherein the one or more hydrophilic polymer(s) are chosen from polyvinyl alcohols, dextran, sodium alginate, polyaspartic acid, polyethylene glycol, polyvinylpyrrolidone, polyacrylic acid and its salts, polyacrylamide, poly(N-isopropylacrylamide), poly(hydroxyethyl acrylate), poly(sodium styrenesulfonate), poly(2-acryl-amido-2-methyl-1-propylenesulfonic acid), polysaccharides, cellulose derivatives, copolymers of the abovementioned polymers and their blends.

10. The process of claim 1 , wherein the one or more hydrophilic polymer(s) are a polyvinyl alcohol or a polyacrylic acid.

11. The process of claim 10 , wherein said polyacrylic acid has a molecular weight ranging from 10,000 to 600,000 g/mol.

12. The process of claim 10 , wherein said polyacrylic acid has a molecular weight ranging from 100,000 to 600,000 g/mol.

13. The process of claim 1 , wherein the nanoparticles have an outer layer formed of at least one polyvinyl alcohol with a molecular weight of greater than 10,000 g/mol.

14. The process of claim 1 , wherein the nanoparticles have an outer layer formed of at least one polyvinyl alcohol with a molecular weight of greater than 20,000 g/mol.

15. The process of claim 1 , wherein the nanoparticles have an outer layer formed of at least one polyvinyl alcohol with a molecular weight varying from 25,000 to 50,000 g/mol.

16. The process of claim 1 , wherein the nanoparticles have a mean size of less than 500 nm.

17. The process of claim 1 , wherein said organic UV-absorbing compound is chosen from substituted benzotriazoles, hydroxybenzophenones, or pyrene and its derivatives.

18. The process of claim 17 , wherein said coating formed has properties of absorbing ultraviolet radiation.

19. The process of claim 1 , wherein (3) is carried out at a temperature varying from 15° C. to 150° C.

20. The process of claim 1 , wherein the substrate is formed of at least one polymeric material.

21. The process of claim 1 , wherein the substrate is a textile.

Assignees

• Poncelet Olivier
• Renard Olivier
• Commissariat Energie Atomique

Inventors

• Poncelet Olivier
• Renard Olivier

Classifications

• D06P1/5228

  Polyalkenyl alcohols, e.g. PVA · CPC title

• D06M23/12

  Processes in which the treating agent is incorporated in microcapsules (making microcapsules B01J13/02) · CPC title

• D06M16/00

  Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic · CPC title

• D06M15/333

  of vinyl acetate; Polyvinylalcohol · CPC title

• D06M15/263

  of unsaturated carboxylic acids; Salts or esters thereof · CPC title