Hydrocarbon soluble metal composition and a method of making it thereof

Patent metadata

Field	Value
Publication number	US-10399073-B2
Application number	US-201615229013-A
Country	US
Kind code	B2
Filing date	Aug 4, 2016
Priority date	Nov 19, 2015
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

This present invention relates to oil-soluble metal compositions of metals and a method for its preparation. The composition finds application in catalysis as catalysts precursors or additives for in situ generation of nano dispersed metal/metal sulfide clusters for heavy oil hydroconversion and in the area of lubrication as friction modifiers.

First claim

We claim:

1. An oil-soluble metal composition comprising of reaction products of beta hydroxy acids, quaternary salts and a metal source, wherein the metal source comprises metal salts selected from the groups comprising of Group VIB;
wherein the metal source is present in the range of 5 wt % to 25 wt % of the composition;
wherein the beta hydroxy acid is represented by the general formula C x H (x−y) O 3 where x is 7, 11 or 15 and, correspondingly, y is 1, 3 or 5; and
wherein the quaternary salt is having formula 3,

wherein:
R 1 is a higher aliphatic alkyl group, which is saturated or unsaturated, and having a carbon chain length of from 8 through 20 carbons;
R 2 and R 3 are saturated or unsaturated alkyl groups having from 1 to 4 carbons in chain length; and
R 4 is a radical selected from the group consisting of unsaturated and saturated aliphatic alkyl groups of from 1 to 4 carbons in chain length, aromatic, cyclic and heterocyclic groups having carbon atoms from 3 to 6, phenyl, thionyl, furfuryl and pyridyl groups; and
X is an ion selected from the group of ions consisting of chloride, bromide, iodide, nitrate, sulfate and salicylate ion; and
M is nitrogen.

2. The oil-soluble metal composition as claimed in claim 1 , wherein beta hydroxy acids include mono and/or polycylic beta hydroxy acid analogs having formula 1 and 2:

wherein R 1 to R 6 are independently selected from the group consisting of saturated or unsaturated, linear or branched chain, substituted or unsubstituted alkyl or alkoxy groups with carbon atoms preferably in the range of C 1 -C 10 ; H; hydroxyl; fluoro; chloro; bromo; iodo;
thiol; amino; cyano; thiocyano; nitro; carboxyl; carbonyl and amide.

3. The oil-soluble metal composition as claimed in claim 1 , wherein beta hydroxy acid analogs are selected from the group consisting of salicylic acid, 1-hydroxy-2-naphthoic acid, 1-hydroxy-2-anthroic acid, 2-hydroxy-3-naphthoic acid, 2-hydroxy-3-anthroic acid, 4-hydroxyisophthalic acid, 2,6-dihydroxybenzoic acid, 5-nitrosalicylic acid, 5-iodosalicylic acid, 5-bromosalicylic acid, 5-iodosalicylic acid, 5-fluorosalicylic acid, 3-chlorosalicylic acid, 4-chlorosalicylic acid, 5-chlorosalicylic acid, and combinations thereof.

4. The oil-soluble metal composition as claimed in claim 1 , wherein the quaternary nitrogen salts include cyclic quaternary nitrogen derivatives, selected from the alkyl pyridinium and the alkyl piperidinium derivatives.

5. The oil-soluble metal composition as claimed in claim 1 , wherein quaternary nitrogen salts are selected from the group consisting of benzalkonium chloride, benzethonium chloride, benzododecinium bromide, bis(hydrogenated tallow alkyl)dimethyl chlorides, benzylcocoalkyldimethyl chlorides, benzoxonium chloride, cetalkonium chloride, cocamidopropyl betaine, cocamidopropyl hydroxysultaine, cetyltrimethyl ammonium bromide, cetyltrimethyl ammonium chloride, cetyltrimethyl ammonium iodide, cetyltrimethyl ammonium nitrate, cetyltrimethyl ammonium sulfate, cetyltrimethyl ammonium salicylate, cetyldimethylbenzylammonium chloride, cetyldimethylbenzylammonium bromide, cetyldimethylbenzylammonium iodide, cetyldimethylbenzylammonium sulfate, cetyldimethylbenzylammonium nitrate, cetyldimethylbenzylammonium salicylate, cetylpyridinium chloride, cetylpyridinium bromide, cetylpyridinium iodide, cetylpyridinium nitrate, cetylpyridinium sulfate, cetylpyridinium salicylate, methyltrioctylammonium chloride, didecyldimethylammonium chloride, dodecyldimethylbenzylammonium chloride, dimethyldioctadecylammonium chloride, domiphen bromide, hexamethylenetetramine chloroallyl chloride, polyquaternium, stearalkonium chloride, tetraoctylammonium bromide, thonzonium bromide, hexadecyltributylphosphonium bromide, tetraphenylphosphonium chloride, methyltriphenoxyphosphonium iodide, monoalkyltrimethylammonium salts, dialkyltrimethylammonium salts, trialkyltrimethylammonium salts, methyldiethanolamine esterquats, triethanolamine esterquats, methyl bis(2-hydroxyethyl) alkyl ammonium chloride, where the carbon chain (C8-18) is derived from coconut, cottonseed, soya and tallow acids and methyl poly(oxyethylene) alkyl ammonium chloride, where the poly(oxyethylene) content is 3-15 moles and the alkyl group (C8-18) is derived from coconut, cottonseed, soya and tallow acid, Quaternary salts derived from the reaction products of fatty acids, trietanolamine and dimetylsulfate or mixture thereof.

6. The oil-soluble metal composition as claimed in claim 1 , wherein the metal salts are water soluble salts of the metal ions capable of reacting with other reactants, the beta hydroxy acid and/or the quaternary salts, or their reaction product.

7. The oil-soluble metal composition as claimed in claim 6 , wherein metal salts include salts of metals selected from the group consisting of Ti, Zr, V, Nb, Cr, Mo, W, Mn, Re, Fe, Co, Ni, Cu, La, Ce, and combinations thereof.

8. The oil-soluble metal composition as claimed in claim 7 , wherein source of V, Cr, Nb, Mo and W are the metal halides, alkali, alkali-earth and ammonium salt of each metal, wherein:
(a) the metal halides is selected from a group comprising of MoCl 5 , CrCl 3 , WCl 6 , NbCl 4 , NbCl 5 , VCl 3 , VCl 5 ; and
(b) alkali, alkali-earth and ammonium salt are selected from a group comprising of ammonium vanadate, sodium vanadate, ammonium chromate, sodium chromate, ammonium niobate (V) oxalate hydrate, ammonium molybdate, sodium molybdate, potassium molybdate, calcium molybdate, ammonium tungstate, sodium tungstate and mixtures thereof.

9. The oil-soluble metal composition as claimed in claim 6 , wherein salts of metals are selected from the groups consisting of ammonium and/or sodium salt of the metal ions.

10. A process for the preparation of an oil-soluble metal composition as claimed in claim 1 , the process comprising the steps of:
(a) reacting the beta hydroxyl acid (s), and the quaternary salt(s) in hydrocarbon solvent to form a composition,
wherein the beta hydroxy acid is represented by the general formula C x H (x−y) O 3 where x is 7, 11 or 15 and, correspondingly, y is 1, 3 or 5; and
wherein the quaternary salt is having formula 3,

wherein:
R 1 is a higher aliphatic alkyl group, which is saturated or unsaturated, and having a carbon chain length of from 8 through 20 carbons;
R 2 and R 3 are saturated or unsaturated alkyl groups having from 1 to 4 carbons in chain length; and
R 4 is a radical selected from the group consisting of unsaturated and saturated aliphatic alkyl groups of from 1 to 4 carbons in chain length, aromatic, cyclic and heterocyclic groups having carbon atoms from 3 to 6, phenyl, thionyl, furfuryl and pyridyl groups; and
X is an ion selected from the group of ions consisting of chloride, bromide, iodide, nitrate, sulfate and salicylate ion; and
M is nitrogen;
(b) reacting the composition obtained in step (a) with the metal source in the presence of water to form a mixture,
wherein the metal source comprises metal salts selected from the groups comprising of Group VIB; and
wherein the metal source is present in the range of 5 wt % to 25 wt % of the composition;
(c) heating the mixture obtained in step (b) at a temperature in the range 50-150° C. for a period of 0.5-6 hours to form a waxy product and

Assignees

• Indian Oil Corp Ltd

Inventors

• Balasundaram Murugan
• Xavier Kochappilly Ouseph
• Pulikottil Alex Cheru
• Kuvettu Mohan Prabhu
• Kumar Brijesh
• Das Biswapriya

Classifications

• C10M159/18

  Complexes with metals · CPC title

• B01J2531/845

  Cobalt · CPC title

• B01J2531/847

  Nickel · CPC title

• B01J31/22 Primary

  Organic complexes · CPC title

• B01J2531/842

  Iron · CPC title