Catalyst containing γ-valerolactone and/or the hydrolysis products thereof, and use thereof in a hydroprocessing and/or hydrocracking method

Patent metadata

Field	Value
Publication number	US-10399070-B2
Application number	US-201615570661-A
Country	US
Kind code	B2
Filing date	Mar 11, 2016
Priority date	Apr 30, 2015
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

The invention relates to a catalyst comprising a support based on alumina or silica or silica-alumina, at least one element of group VIII, at least one element of group VIB and at least one additive selected from γ-valerolactone, 4-hydroxyvaleric acid, 2-pentenoic acid, 3-pentenoic acid or 4-pentenoic acid. The invention also relates to the process for the preparation of said catalyst and the use thereof in a hydrotreatment and/or hydrocracking process.

First claim

The invention claimed is:

1. A catalyst comprising a support based on alumina or silica or silica-alumina, at least one element of group VIII, at least one element of group VIB, at least one additive that is γ-valerolactone, 4-hydroxyvaleric acid, 2-pentenoic acid, 3-pentenoic acid or 4-pentenoic acid, and phosphorus, the phosphorus content being 0.1 to 20% by weight expressed as P 2 O 5 with respect to the total weight of the catalyst and the ratio of phosphorus to the element of group VIB in the catalyst is greater than or equal to 0.05.

2. The catalyst according to claim 1 , having a content of the element of group VIB of 5 to 40% by weight expressed as oxide of the metal of group VIB with respect to the total weight of the catalyst and a content of the element of group VIII of 1 to 10% by weight expressed as oxide of the metal of group VIII with respect to the total weight of the catalyst.

3. The catalyst according to claim 1 , having a molar ratio of the element of group VIII to the element of group VIB in the catalyst of 0.1 to 0.8.

4. The catalyst according to claim 1 , having a total content of additive(s) γ-valerolactone, 4-hydroxyvaleric acid, 2-pentenoic acid, 3-pentenoic acid, or 4-pentenoic acid of 1 to 35% by weight with respect to the total weight of the catalyst.

5. The catalyst according to claim 1 , which additionally contains an organic compound other than the additive γ-valerolactone, 4-hydroxyvaleric acid, 2-pentenoic acid, 3-pentenoic acid or 4-pentenoic acid, said organic compound containing oxygen and/or nitrogen and/or sulphur.

6. The catalyst according to claim 5 , in which the organic compound is a compound comprising one or more of a carboxyl, alcohol, thiol, thioether, sulphone, sulphoxide, ether, aldehyde, ketone, ester, carbonate, amine, nitrile, imide, oxime, urea or amide functions.

7. The catalyst according to claim 6 , in which the organic compound is triethylene glycol, diethylene glycol, ethylenediaminetetraacetic acid, maleic acid, citric acid, dimethylformamide, bicine, or tricine.

8. The catalyst according to claim 1 , in which the support contains from 0.1 to 50% by weight of zeolite.

9. The catalyst according to claim 1 , that is at least partially sulphurized.

10. A process for the hydrotreatment and/or hydrocracking of hydrocarbon-containing cuts, comprising subjecting said cuts to hydrotreatment and/or hydrocracking, conditions in the presence of a catalyst according to claim 1 .

11. A process for the preparation of a catalyst according to claim 1 comprising:
a) bringing at least one component of an element of group VIB, at least one component of an element of group VIII, at least one additive that is γ-valerolactone, 4-hydroxyvaleric acid, 2-pentenoic acid, 3-pentenoic acid or 4-pentenoic acid and phosphorus into contact with a support based on alumina or silica or silica-alumina, or bringing a regenerated catalyst containing a support based on alumina or silica or silica-alumina, at least one component of an element of group VIB, at least one component of an element of group VIII and phosphorus into contact with at least one additive γ-valerolactone, 4-hydroxyvaleric acid, 2-pentenoic acid, 3-pentenoic acid or 4-pentenoic acid, so as to obtain a catalyst precursor,
b) drying said catalyst precursor originating from a) at a temperature of less than 200° C., without calcining it subsequently.

12. The process according to claim 11 , in which a) comprises the following:
a′) impregnating a support based on alumina or silica or silica-alumina with at least one solution containing at least one element of group VIB, at least one element of group VIII, at least one additive that is γ-valerolactone, 4-hydroxyvaleric acid, 2-pentenoic acid, 3-pentenoic acid or 4-pentenoic acid and phosphorus so as to obtain a catalyst precursor.

13. The process according to claim 11 , in which a) comprises the following:
a1) impregnating a support based on alumina or silica or silica-alumina with at least one solution containing at least one element of group VIB, at least one element of group VIII and phosphorus in order to obtain an impregnated support,
a2) drying the impregnated support obtained in a1) at a temperature of less than 200° C. in order to obtain a dried impregnated support, and calcining the dried impregnated support in order to obtain a calcined impregnated support,
a3) impregnating the dried and optionally calcined impregnated support obtained in a2) with an impregnating solution comprising at least one additive that is γ-valerolactone, 4-hydroxyvaleric acid, 2-pentenoic acid, 3-pentenoic acid or 4-pentenoic acid so as to obtain a catalyst precursor,
a4) optionally, leaving the catalyst precursor obtained in a3) to mature.

14. The process according to claim 11 , in which a) comprises the following:
a1′) preparing a support comprising at least one additive that is γ-valerolactone, 4-hydroxyvaleric acid, 2-pentenoic acid, 3-pentenoic acid or 4-pentenoic acid and at least one part of phosphorus,
a2′) impregnating the support obtained in a1′) with an impregnating solution comprising at least one element of group VIB, at least one element of group VIII and phosphorus so as to obtain a catalyst precursor,
a3′) optionally, leaving the catalyst precursor obtained in a2′) to mature.

15. The process according to claim 11 , in which a) comprises the following:
a1″) by co-impregnation, bringing a solution containing at least one element of group VIB, at least one element of group VIII, at least one organic compound containing oxygen and/or nitrogen and/or sulphur, and phosphorus into contact with a support based on alumina or silica or silica-alumina so as to obtain an impregnated support,
a2″) drying the impregnated support originating from step a1″) at a temperature of less than 200° C., without calcining it subsequently, in order to obtain a dried impregnated support,
a3″) bringing the dried impregnated support originating from step a2″) into contact with a solution of an organic compound containing oxygen and/or nitrogen and/or sulphur, identical to or different from that used in step a1″), so as to obtain a catalyst precursor,
a4″) optionally, leaving the catalyst precursor obtained in step a3″) to mature, and at least one of the organic compounds in step a1″) or in a3″) is γ-valerolactone, 4-hydroxyvaleric acid, 2-pentenoic acid, 3-pentenoic acid or 4-pentenoic acid.

16. The process according to claim 11 , in which a) comprises the following:
a1′″) impregnating a regenerated catalyst containing a support based on alumina or silica or silica-alumina, at least one component of an element of group VIB, at least one component of an element of group VIII and phosphorus with an impregnating solution comprising at least one additive that is γ-valerolactone, 4-hydroxyvaleric acid, 2-pentenoic acid, 3-pentenoic acid or 4-pentenoic acid so as to obtain a catalyst precursor,
a2′″) optionally, leaving the catalyst precursor obtained in a1′″) to mature.

17. The process according to claim 11 , in which the total molar ratio of the γ-valerolactone, 4-hydroxyvaleric acid, 2-pentenoic acid, 3-pentenoic acid or 4-pentenoic acid additive(s) to the element(s) of group VIII is 0.1 to 5.0 mol/mol.

Assignees

• Ifp Energies Now

Inventors

• Carrette Pierre-Louis

Classifications

• C10G47/20

  the catalyst containing other metals or compounds thereof · CPC title

• B01J37/28

  Phosphorising · CPC title

• B01J37/20

  Sulfiding · CPC title

• B01J37/0205

  in several steps · CPC title

• B01J37/0009

  Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst · CPC title