Catalyst

Patent metadata

Field	Value
Publication number	US-10399061-B2
Application number	US-201515127068-A
Country	US
Kind code	B2
Filing date	Mar 19, 2015
Priority date	Mar 21, 2014
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

The Fischer-Tropsch process can be used for the conversion of hydrocarbonaceous feed stocks into normally liquid and/or solid hydrocarbons. The feed stock (e.g. natural gas, associated gas and/or coal-bed methane, coal) is converted in a first step into a mixture of hydrogen and carbon monoxide (this mixture is often referred to as synthesis gas or syngas). The synthesis gas (or syngas) is then converted in one or more steps over a suitable catalyst at elevated temperature and pressure into paraffinic compounds ranging from methane to high molecular weight molecules comprising up to 200 carbon atoms, or, under particular circumstances, even more. The present invention relates to a catalyst, a method for manufacturing said catalyst. The present invention further relates to a catalyst obtainable by said method. The present invention further relates to a multi tubular reactor comprising said catalyst.

First claim

That which is claimed is:

1. A catalyst for carrying out a Fischer-Tropsch reaction comprising a matrix material (1) and a catalytic material (2) wherein the catalyst comprises stepped-shape channels through which synthesis gas comprising hydrogen and carbon monoxide can flow, the stepped-shape channels defined by opposing stepped-shape walls, such that a fluid flowing through the catalyst moves up/down a stairs and said channels are in connection with each other such that a fluid can flow from one channel to an adjacent channel and adjacent channels are oriented crosswise.

2. A catalyst according to claim 1 wherein the catalyst has an open volume of more than 60%, with respect to the reactor volume.

3. A catalyst according to claim 1 wherein the catalyst has a specific surface area from 1000-5000 m2/m3.

4. A catalyst according to claim 1 wherein the catalytic material is present as a layer on the stepped-shape walls and has a layer thickness of from about 1 to 300 microns.

5. A catalyst according to claim 1 wherein the catalytic material comprises a catalyst support material wherein the catalyst support material is selected from the group consisting of refractory oxides, metals, or mixtures thereof.

6. A catalyst according to claim 1 wherein the catalyst material comprises a catalytically active component which is selected from the group consisting of cobalt, iron, ruthenium and mixtures thereof.

7. A catalyst according to claim 1 wherein the catalyst material comprises a promoter, selected from the group consisting of zirconium, manganese, vanadium, rhenium, platinum, palladium and mixtures thereof.

8. A method for manufacturing a catalyst according to claim 1 , wherein the stepped-shape walls comprise a catalytic material, said method comprising the steps of:
(i) forming a layer of a matrix material by providing a powder or a paste;
(ii) binding or fusing a powder or a paste in said layer according to a predetermined pattern; and
(iii) repeating (i) and (ii) layer upon layer to form a structure wherein each subsequent layer is bound or fused to a preceding layer forming a structure comprising stepped shape channels through which synthesis gas comprising hydrogen and carbon monoxide can flow,
wherein the catalytically active material is provided in step (i) as a powder or a paste, or wherein the catalytically active material is provided after obtaining the structure in step (iii) by applying a slurry comprising the catalytically active material to the structure obtaining a catalyst.

9. A method according to claim 8 wherein, each layer obtained in step (i) comprises openings which openings of the layers obtained in step (i) together form one or more channels in the catalyst obtained in step (iii).

10. A method according to claim 8 wherein, in step (i) the catalyst material (2) is provided such that it borders the openings and is provided such that the catalyst material (2) is present only between the openings and the matrix material (1).

11. A method according to claim 8 wherein, in step (iii), steps (i) and (ii) are repeated such that the channels of the catalyst have a stepped shape.

12. A method according to claim 8 , wherein the method can be divided into at least three stages wherein:
in stage I the steps (i) and (ii) are repeated several times to obtain a first layer (A) having openings with a stepped-shape in a first direction (I);
in stage II steps (i) and (ii) are repeated several times to obtain a second layer (B) (on the first layer) having openings with a stepped shape in a second direction (II);
in stage III, stage I and stage II are repeated at least once to form a structure;
wherein said first and second direction intersect, are substantially perpendicular to each other.

13. A reactor tube comprising a catalyst according to claim 1 wherein one or more of the catalyst snugly fit the reactor tube or said reactor tube comprises several catalysts forming a stacked bed.

14. A method of manufacturing hydrocarbons comprising the step of providing a reaction fluid to a catalyst according to claim 1 .

Assignees

• Shell Oil Co

Inventors

• Chettouf Abderrahmane
• Den Breejen Johan Peter
• Dogterom Ronald Jan
• Fleys Matthieu Simon Henri

Classifications

• B22F10/20

  Direct sintering or melting · CPC title

• F01N3/281

  Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates · CPC title

• C10G2/341

  with stationary catalyst bed · CPC title

• C10G2/333

  of the platinum-group · CPC title

• C10G2/32

  with the use of catalysts · CPC title