Sodium bicarbonate particles manufactured by atomization

Patent metadata

Field	Value
Publication number	US-10398652-B2
Application number	US-201314653616-A
Country	US
Kind code	B2
Filing date	Dec 23, 2013
Priority date	Dec 21, 2012
Publication date	Sep 3, 2019
Grant date	Sep 3, 2019

Abstract

Method for producing sodium bicarbonate particles by spray-drying of an aqueous solution comprising 1 to 10% by weight of sodium bicarbonate and an additive selected from the group consisting of: magnesium salt, sodium alkylbenzene sulfonate and soybean lecithin. Sodium bicarbonate particles obtainable by such process and comprising at least 20 mg of the additive per kg of sodium bicarbonate particles.

First claim

The invention claimed is:

1. A method for producing sodium bicarbonate particles comprising:
spray-drying of an aqueous solution comprising 1 to 10% by weight of sodium bicarbonate and an additive selected from the group consisting of: a magnesium salt, sodium alkylbenzene sulfonate and soybean lecithin, to form sodium bicarbonate particles, wherein said formed sodium bicarbonate particles have a lower mean particle size D50 by weight compared to sodium bicarbonate particles obtained without the additive and at least 50% of the formed sodium bicarbonate particles have spherical shape, wherein said spray-drying is carried out in a gas comprising at least 5% of CO 2 by volume on a dry gas basis and in a spray-drying chamber, and wherein the gas is preheated before being introduced into the spray-drying chamber at a temperature of at least 40° C. and at most 220° C.

2. The method according to claim 1 , wherein the aqueous solution comprises at least 1 mg and at most 2000 mg of the additive per kilogram of aqueous solution, and when the additive is a magnesium compound, the above quantities are expressed of mg Mg/kg of said aqueous solution.

3. The method according to claim 1 , comprising at most 1500 mg of the additive per kilogram of said aqueous solution.

4. The method according to claim 1 , wherein said aqueous solution comprises at least or more than 2% by weight of sodium bicarbonate.

5. The method according to claim 1 , wherein said aqueous solution comprises at most or less than 8% of sodium bicarbonate.

6. The method according to claim 1 , wherein the gas is preheated before being introduced into the spray-drying chamber at a temperature of at most 200° C.

7. The method according to claim 1 , wherein said gas after spray-drying has a temperature of at most 80° C.

8. Sodium bicarbonate particles produced by the method according to claim 1 , and comprising at least 20 mg and at most 50,000 mg of the additive per kg of sodium bicarbonate particles, wherein said sodium bicarbonate particles have a lower mean particle size D50 by weight compared to sodium bicarbonate particles obtained without the additive and at least 50% of the formed sodium bicarbonate particles have spherical shape and wherein the sodium bicarbonate particles have a bulk density of between 40 and less than 450 kg/m 3 .

9. The sodium bicarbonate particles according to claim 8 , having a BET specific surface area of at least 4 m 2 /g.

10. The sodium bicarbonate particles according to claim 9 , wherein the additive is a compound of magnesium Mg 2+ and having a BET specific surface area of at least 6 m 2 /g.

11. The sodium bicarbonate particles according to claim 9 , wherein the additive is an alkylbenzenesulfonate and having a BET specific surface area of at least 6 m 2 /g.

12. The sodium bicarbonate particles according to claim 9 , wherein the additive is soybean lecithin.

13. The sodium bicarbonate particles according to claim 8 , wherein the additive is a magnesium salt, and being in shape of hollow spheres.

14. The sodium bicarbonate particles according to claim 8 , being made with an aqueous composition comprising from 150 to 500 mg Mg of a magnesium salt per kg of aqueous solution.

15. The sodium bicarbonate particles according to claim 14 , having a bulk density of 40 to 80 kg/m 3 .

16. The sodium bicarbonate particles according to claim 8 , being made with an aqueous solution comprising 100 to 1000 mg of sodium alkylbenzenesulfonate per kg of aqueous solution.

17. An aqueous gel comprising the sodium bicarbonate particles according to claim 8 .

18. Sodium carbonate particles obtained by calcination of the sodium bicarbonate particles according to claim 8 , and having a BET specific surface area of at least 15 m 2 /g.

19. Sodium bicarbonate particles, comprising at least 20 mg and at most 50,000 mg of an additive per kg of sodium bicarbonate particles and having a BET specific surface area of at least 6 m 2 /g, wherein the additive is a compound of magnesium Mg 2+ , wherein said sodium bicarbonate particles have a lower mean particle size D50 by weight compared to sodium bicarbonate particles obtained without the additive and at least 50% of the formed sodium bicarbonate particles have spherical shape and wherein the sodium bicarbonate particles have a bulk density of from 40 to 80 kg/m 3 .

20. The sodium bicarbonate particles according to claim 8 , having a mean particle size by weight (D50) of about 3 to 11 μm.

21. The method according to claim 1 , wherein said sodium bicarbonate particles have a mean particle size by weight (D50) of about 3 to 11 μm.

22. The sodium bicarbonate particles according to claim 19 , wherein more than 70% of the spheres are hollow spheres with a shape factor of less than 1.

Assignees

• Solvay

Inventors

• Savary David Jean Lucien

Classifications

• C01D7/38

  Preparation in the form of granules, pieces or other shaped products · CPC title

• C01D7/123 Primary

  by thermal decomposition of solids in the absence of a liquid medium · CPC title

• A61K9/1611

  Inorganic compounds · CPC title

• A61K9/1682 Primary

  Processes · CPC title

• A61K9/1617

  Organic compounds, e.g. phospholipids, fats · CPC title