Electrode material for electrolytic hydrogen generation

Patent metadata

Field	Value
Publication number	US-10385462-B2
Application number	US-201615147252-A
Country	US
Kind code	B2
Filing date	May 5, 2016
Priority date	Jul 9, 2015
Publication date	Aug 20, 2019
Grant date	Aug 20, 2019

Abstract

Some examples of a method for manufacturing an electrode material for electrolytic hydrogen generation are described. Tungsten salt and nickel salt are mixed in a determined molar ratio on a carbon support by effectively controlling synthesis temperature and composition. Water and adsorbed oxygen, produced by mixing the tungsten salt and nickel salt are removed. Then, methane gas is flowed over the mixture resulting in the electrode material. The electrode material is suitable for use as a catalyst in electrolytic hydrogen generation processes, for example, at an industrial scale, to produce large quantities of hydrogen.

First claim

The invention claimed is:

1. A method comprising:
mixing a first quantity of tungsten (W) salt and a second quantity of nickel (Ni) salt in the presence of a carbon support; and
flowing methane gas over the mixture of the first quantity and the second quantity to form tungsten-nickel carbides (W—Ni—C) on said carbon support,
wherein the molar ratio of tungsten to nickel is about 4:1.

2. The method of claim 1 , wherein the tungsten salt is dissolved in isopropanol.

3. The method of claim 1 , wherein the nickel salt is on the carbon support.

4. The method of claim 1 , further comprising removing water and oxygen, flowing the methane gas over the mixture after removing the water and the oxygen.

5. The method of claim 4 , wherein, after removing the water and the oxygen, flowing methane gas over the mixture of the first quantity and the second quantity comprises increasing a temperature of the mixture to about 1000° C.

6. The method of claim 5 , further comprising increasing the temperature at a rate of 5° C/min.

7. The method of claim 5 , further comprising holding the temperature of the mixture for a respective duration at each of about 700° C., about 800° C., about 900° C. and about 1000° C.

8. The method of claim 5 , further comprising, after removing the water and the oxygen and flowing the methane gas over the mixture of the first quantity and the second quantity, using the mixture as an electrode material for hydrogen generation from brine by electrolysis.

9. The method of claim 1 , further comprising pre-treating the carbon support before mixing the first quantity and the second quantity.

10. The method of claim 9 , wherein pre-treating the carbon support comprises removing impurities from the carbon support.

11. The method of claim 9 , wherein pre-treating the carbon support comprises mixing a third quantity of the carbon support with a first volume of hydrochloric acid.

12. The method of claim 11 , wherein the third quantity comprises about 0.2 g of the carbon support.

13. The method of claim 11 , wherein the first volume comprises about 40 mL.

14. The method of claim 11 , wherein the hydrochloric acid has a molarity of about 0.5M.

15. The method of claim 11 , further comprising mixing the third quantity with the first volume for a duration at a rotational speed.

16. The method of claim 15 , wherein the duration is about 15 hours.

17. The method of claim 15 , wherein the rotational speed is about 400 rpm.

18. The method claim 1 , wherein the first quantity of tungsten consists of WCl 6 and the second quantity of nickel consists of Ni(NO 3 ) 2 .6H 2 O.

19. The method of claim 1 , wherein mixing the first quantity of tungsten (W) salt and the second quantity of nickel (Ni) salt on the carbon support comprises:
dispersing a fourth quantity of the carbon support in a second volume of de-ionized water to form a carbon slurry;
dissolving the first quantity of tungsten salt in a third volume of isopropanol;
adding the dissolved first quantity of tungsten salt in the third volume of isopropanol to the carbon slurry;
adding a fourth volume of de-ionized water to the mixture of the tungsten salt in the carbon slurry;
stirring a mixture of the fourth volume of de-ionized water and the mixture of the tungsten in the carbon slurry for a duration; and
vacuum drying the mixture of the fourth volume of de-ionized water and the mixture of the tungsten salt in the carbon slurry after the duration.

20. The method of claim 1 , wherein the carbon support is conductive and hydrophobic.

21. The method of claim 1 , wherein flowing methane through the mixture produces a nickel-tungsten carbide alloy.

22. The method of claim 21 , wherein the tungsten-nickel carbides on the carbon supports have a particle size ranging between about 10 nanometers (nm) and 100 nm.

23. The method of claim 1 , wherein a surface area of the carbon support ranges between about 50 m 2 /g to about 3000 m 2 /g.

Assignees

• Saudi Arabian Oil Co

Inventors

• Merzougui Belabbes
• Abidemi Bukola Saheed
• Qamar Mohammad
• Akinpelu Adeola Akeem
• Noui-Mehidi Mohamed Nabil

Classifications

• B01J23/30

  Tungsten · CPC title

• C01B32/907

  Oxycarbides; Sulfocarbides; Mixture of carbides · CPC title

• C25B1/04 Primary

  by electrolysis of water · CPC title

• B01J23/755

  Nickel · CPC title

• C25B11/12

  Chemistry & Metallurgy · mapped topic