Hydroprocessing thermally cracked products

Patent metadata

Field	Value
Publication number	US-10385283-B2
Application number	US-201715460786-A
Country	US
Kind code	B2
Filing date	Mar 16, 2017
Priority date	Mar 15, 2013
Publication date	Aug 20, 2019
Grant date	Aug 20, 2019

Abstract

Embodiments herein relate to a process flow scheme for the processing of gas oils and especially reactive gas oils produced by thermal cracking of residua using a split flow concept. The split flow concepts disclosed allow optimization of the hydrocracking reactor severities and thereby take advantage of the different reactivities of thermally cracked gas oils versus those of virgin gas oils. This results in a lower cost facility for producing base oils as well as diesel, kerosene and gasoline fuels while achieving high conversions and high catalyst lives.

First claim

What is claimed:

1. A system for upgrading gas oils to distillate hydrocarbons, the system comprising:
a mixing device for mixing a first portion of a first gas oil stream with a second gas oil stream to form a mixed gas oil stream;
a first hydrocracker reaction system for contacting the mixed gas oil stream and hydrogen with a first hydroconversion catalyst to convert at least a portion of the hydrocarbons in the mixed gas oil stream to distillate hydrocarbons;
a separation system for fractionating an effluent from the first hydrocracker reaction system into one or more hydrocarbon fractions including a fraction comprising the unconverted hydrocarbons;
a second hydrocracker reaction system for contacting hydrogen and the fraction comprising the unconverted hydrocarbons with a second hydroconversion catalyst to convert at least a portion of the hydrocarbons in the mixed gas oil stream to distillate hydrocarbons;
a flow line for feeding the effluent from the second hydrocracking reaction system to the fractionating system for concurrent fractionation with the effluent from the first hydrocracker reaction system;
a third hydrocracker reaction system for contacting hydrogen and a second portion of the first gas oil stream with a third hydroconversion catalyst to convert at least a portion of the hydrocarbons in the second portion to distillate hydrocarbons;
a separation system for fractionating an effluent from the third hydrocracker reaction system to recover two or more hydrocarbon fractions;
a diesel hydrotreating unit for hydrotreating a hydrocarbon feedstock;
a flow conduit for feeding the effluent from the diesel hydrotreating unit to the separation system for fractionating step for concurrent fractionation with the effluent from the third hydrocracker reaction system.

2. The system of claim 1 , further comprising at least one of a delayed coking system, a fluid coking system, a visbreaking system, a steam cracking system, and a fluid catalytic cracking system for producing the second gas oil stream.

3. The system of claim 1 , wherein a flow control system is configured to blend the second gas oil stream with the first portion of the first gas oil stream in a ratio of at least 0.10 kg of said second gas oil stream per kg of the first portion of the first gas oil stream but not more than about 0.90 kg of said second gas oil stream per kg of the first portion of the first gas oil stream.

4. The system of claim 1 , wherein a flow control system is configured to blend the second gas oil stream with the first portion of the first gas oil stream in a ratio of at least 0.65 kg of said second gas oil stream per kg of the first portion of the first gas oil stream but not more than about 0.90 kg of said second gas oil stream per kg of the first portion of the first gas oil stream.

5. The system of claim 1 , wherein a flow control system is configured to blend the second gas oil stream with the first portion of the first gas oil stream at a ratio of at least 0.8 kg of said second gas oil stream per kg of the first portion of the first gas oil stream but not more than about 0.90 kg of said second gas oil stream per kg of the first portion of the first gas oil stream.

6. The system of claim 1 , wherein the separation system for fractionating the effluent from the first and second hydrocracker reaction systems comprises:
a vapor-liquid separator for separating the first and second hydrocracker reaction systems into a vapor fraction and a liquid fraction;
a fractionation system for fractionating the liquid fraction into the one or more hydrocarbon fractions including a fraction comprising the unconverted hydrocarbons.

7. The system of claim 6 , further comprising one or more flow lines to recycle at least a portion of the vapor fraction to one or more of the first hydrocracker reaction system, the second hydrocracker reaction system, the third hydrocracker reaction system, and a distillate hydrotreating system.

8. The system of claim 1 , wherein the separation system for fractionating the effluent from the third hydrocracker reaction system is the same separation system with that for separating the effluents from the first and second hydrocracker reaction systems.

9. The system of claim 1 , wherein the separation system for fractionating the effluent from the third hydrocracker reaction system is configure to fractionate the effluent into a C4-fraction, a light naphtha fraction, a heavy naphtha fraction, a kerosene fraction, a diesel fraction, and a base oil fraction.

10. The system of claim 9 , further comprising a flow conduit for feeding at least a portion of the base oil fraction to the second hydrocracker reaction system.

11. The system of claim 1 , further comprising an operating system configured to: operate the first hydrocracking reactor system to achieve at least 30% conversion; operate the second hydrocracking reactor system to achieve at least 45% conversion; and operate the third hydrocracking reactor system to achieve at least 50% conversion, wherein conversion is defined as the hydrocracking of hydrocarbon materials boiling above about 650° F. to hydrocarbon materials boiling below about 650° F., both temperatures as defined by ASTM D 1160 or equivalent distillation method.

12. The system of claim 11 , wherein the operating system is configured for controlling:
the reaction severity for the first hydrocracking reaction system in the range from about 35,000° F.-Bara-Hr to less than about 225,000° F.-Bara-Hr;
the reaction severity for the second hydrocracking reaction system in the range from about 25,000° F.-Bara-Hr to less than about 110,000° F.-Bara-Hr; and
the reaction severity for the third hydrocracking reaction system in the range from about 50,000° F.-Bara-Hr to less than about 235,000° F.-Bara-Hr,
wherein reaction severity is defined as the catalyst average temperature in degrees Fahrenheit of the catalysts loaded in the hydrocracking reactors of a hydrocracking reactor system multiplied by the average hydrogen partial pressure of said hydrocracking reactors in Bar absolute and divided by the liquid hourly space velocity in said hydrocracking reactors.

Assignees

• Lummus Technology Inc

Inventors

• Arora Arun
• Mukherjee Ujjal K
• Louie Wai Seung
• Greene Marvin I

Classifications

• C10G2300/1059

  Gasoil having a boiling range of about 330 - 427 °C · CPC title

• C10L1/06

  for spark ignition · CPC title

• C10L1/08

  for compression ignition · CPC title

• B01D3/14

  Fractional distillation {or use of a fractionation or rectification column} · CPC title

• C10G65/00

  Treatment of hydrocarbon oils by two or more hydrotreatment processes only · CPC title