Use of renewable oil in hydrotreatment process

Patent metadata

Field	Value
Publication number	US-10385278-B2
Application number	US-201815954501-A
Country	US
Kind code	B2
Filing date	Apr 16, 2018
Priority date	Feb 15, 2011
Publication date	Aug 20, 2019
Grant date	Aug 20, 2019

Abstract

The use of bio oil from at least one renewable source in a hydrotreatment process, in which process hydrocarbons are formed from said glyceride oil in a catalytic reaction, and the iron content of said bio oil is less than 1 w-ppm calculated as elemental iron. A bio oil intermediate including bio oil from at least one renewable source and the iron content of said bio oil is less than 1 w-ppm calculated as elemental iron.

First claim

What is claimed is:

1. A method for avoiding catalyst plugging that causes an increase in a pressure drop of a hydrotreatment reactor during hydrotreatment comprising:
purifying a biological feedstock from at least one renewable source to lower a content of impurities therein, which have a correlation between (a) and (b) greater than 0.14,
wherein (a) is a rate of increase in the pressure drop measured as bar/kg of biological feedstock and
(b) is a respective concentration of each impurity measured in ppm,

wherein the concentration of each impurity with the correlation greater than 0.14 is lowered to a value between 0.25 to 1 w-ppm;
hydrotreating the purified biological feedstock from at least one renewable source with a catalyst to form hydrocarbons during a catalytic reaction in a trickle bed reactor; and
avoiding plugging of the catalyst used in hydrotreating that causes an increase in the pressure drop of the hydrotreatment reactor.

2. The method according to claim 1 , wherein the correlation is 0.75 or greater.

3. The method according to claim 1 , wherein the concentration of each impurity of the feedstock with the correlation greater than 0.14 was above 1 ppm before purification.

4. The method according to claim 1 or 3 , wherein the impurities of the feedstock with the correlation greater than 0.14 include iron.

5. The method according to claim 1 , wherein the concentration of each impurity of the feedstock with the correlation greater than 0.14 is lowered to a value between 0.25 to 0.5 w-ppm.

6. The method according to claim 1 , wherein the biological feedstock is selected from the group consisting of rapeseed oil, colza oil, canola oil, tall oil, sunflower oil, soybean oil, hempseed oil, cottonseed oil, corn oil, olive oil, linseed oil, mustard oil, palm oil, peanut oil, castor oil, coconut oil, camellia oil, jatropha oil, an oil derived from a microbial source, animal fat, fish oil, lard, tallow, train oil, recycled fat from the food industry, and a mixture thereof.

7. The method according to claim 1 , wherein the hydrocarbons formed in the hydrotreating are further processed in a hydroisomerisation process to iso-paraffins.

8. The method according to claim 6 , wherein the microbial source is algae, bacteria, molds, filamentous fungi or a combination thereof.

9. The method according to claim 1 , wherein the hydrotreating is hydrodeoxygenation performed under a pressure from 10 to 150 bar, and at a temperature of from 200 to 400° C.

10. The method according to claim 1 , wherein the catalyst comprises Pd, Pt, Ni, NiMo or CoMo, and a support of alumina and/or silica.

11. The method according to claim 1 , wherein the catalyst comprises a NiMo/Al 2 O 3 catalyst, a CoMo/Al 2 O 3 catalyst, or a combination thereof.

12. The method according to claim 7 , wherein the iso-paraffins are converted into components for use in products selected from the group consisting of a base oil, lubrication oil, heating oil, diesel fuel, gasoline, liquefied petroleum gas, aviation fuel, solvent and biogas.

13. The method according to claim 1 , wherein the purified biological feedstock has a phosphorous content that is greater than 5 w-ppm calculated as elemental phosphorous.

14. The method according to claim 2 , wherein the impurities of the feedstock with the correlation of 0.75 or greater include iron.

Assignees

• Neste Oyj

Inventors

• Ouni Tuomas
• Sippola Vainö
• Lindqvist Petri

Classifications

• C10G2300/1014

  of vegetal origin · CPC title

• C10G2400/18

  Solvents · CPC title

• C07C69/66

  Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, [IMAGE cpc-sch-C07C-0958.gif] groups,[IMAGE cpc-sch-C07C-0959.gif] groups, or[IMAGE cpc-sch-C07C-0960.gif] in the acid moiety · CPC title

• C07C1/207

  from carbonyl compounds · CPC title

• C10G2300/205

  Metal content · CPC title