LLDPE-containing impact modifier polyolefin composition

Patent metadata

Field	Value
Publication number	US-10385199-B2
Application number	US-201615738782-A
Country	US
Kind code	B2
Filing date	Jun 22, 2016
Priority date	Jun 24, 2015
Publication date	Aug 20, 2019
Grant date	Aug 20, 2019

Abstract

(C) about 30 to about 60% by weight, of a copolymer of ethylene and propylene containing from about 45% to about 75% by weight of ethylene units and containing from about 55% to about 95% by weight, of a fraction soluble in xylene at 25° C. (XSC).

First claim

What is claimed is:

1. A polyolefin composition comprising:
(A) from about 5 to about 35% by weight of a propylene-based polymer containing about 90% by weight or more of propylene units and containing about 10% by weight or less of a fraction soluble in xylene at 25° C. (XS A ), both the amount of propylene units and of the fraction XS A being referred to the weight of (A);
(B) from about 25 to about 50% by weight, of a copolymer of ethylene and a C 3 -C 8 alpha-olefin containing from about 0.1% to about 20% by weight of alpha-olefin units and containing about 75% by weight or less of a fraction soluble in xylene at 25° C. (XS B ), both the amount of ethylene units and of the fraction XS B being referred to the weight of (B); and
(C) from about 30 to about 60% by weight, of a copolymer of ethylene and propylene containing from about 25% to about 75% by weight of ethylene units and containing from about 55% to about 95% by weight, of a fraction soluble in xylene at 25° C. (XS C ), both the amount of ethylene units and of the fraction XS C being referred to the weight of (C);
the amounts of (A), (B) and (C) being referred to the total weight of (A)+(B)+(C), wherein, following a progressive fractionation having a first, a second, and a third dissolution temperature (77° C., 100° C., and 130° C.) and the fraction collected at the second dissolution temperature corresponds to the second fractionation step and fraction 2, the composition has about 20% by weight or less of a fraction obtained in the second fractionation step (fraction 2).

2. The polyolefin composition according to claim 1 , wherein the propylene-based polymer (A) is present in amount of about 15 to about 25% by weight, referred to the total weight of (A)+(B)+(C).

3. The polyolefin composition according to claim 1 , wherein the propylene-based polymer (A) is a homopolymer and contains about 5% by weight or less of a fraction soluble in xylene at 25° C. (XS A ), referred to the weight of (A).

4. The polyolefin composition according to claim 1 , wherein the propylene-based polymer (A) has a melt flow rate (230° C./2.16 kg) between about 80 to about 170 g/10 min.

5. The polyolefin composition according to claim 1 , wherein the copolymer of ethylene (B) is present in amount of about 30 to about 40% by weight, referred to the total weight of (A)+(B)+(C).

6. The polyolefin composition according to claim 1 , wherein the copolymer of ethylene (B) has a melt flow rate (230° C./2.16 kg) between about 1 to about 30 g/10 min.

7. The polyolefin composition according to claim 1 , wherein the copolymer of ethylene and propylene (C) is present in amount of about 40 to about 55% by weight, referred to the total weight of (A)+(B)+(C).

8. The polyolefin composition according to claim 1 , wherein the copolymer of ethylene and propylene (C) contains from about 45% to about 65% by weight of ethylene units, referred to the weight of (B).

9. The polyolefin composition according to claim 1 , wherein the copolymer of ethylene and propylene (C) further contains from about 10% to about 30% by weight of an alpha-olefin having 4 to 8 carbon atoms.

10. The polyolefin composition according to claim 9 , wherein the alpha-olefin having 4 to 8 carbon atoms is 1-butene.

11. The polyolefin composition according to claim 1 , having:
a. a melt flow rate (230° C./2.16 kg) between about 1.0 to about 5.0 g/10 min;
b. a content of from about 30% to about 55% by weight of a fraction soluble in xylene at 25° C.;
c. an intrinsic viscosity [η], measured in tetrahydronaphthalene at 135° C., of the XS fraction between about 2.0 to about 4.0 dl/g; and
d. a total content of C4-C8 alpha-olefin units, determined by IR analysis, of about 3% by weight or higher.

12. A process for the preparation of a polyolefin composition comprising:
at least three sequential polymerization steps,
wherein the polyolefin composition comprises
(A) from about 5 to about 35% by weight of a propylene-based polymer containing about 90% by weight or more of propylene units and containing about 10% by weight or less of a fraction soluble in xylene at 25° C. (XS A ), both the amount of propylene units and of the fraction XS A being referred to the weight of (A);
(B) from about 25 to about 50% by weight, of a copolymer of ethylene and a C 3 -C 8 alpha-olefin containing from about 0.1% to about 20% by weight of alpha-olefin units and containing about 75% by weight or less of a fraction soluble in xylene at 25° C. (XS B ), both the amount of ethylene units and of the fraction XS B being referred to the weight of (B); and
(C) from about 30 to about 60% by weight, of a copolymer of ethylene and propylene containing from about 25% to about 75% by weight of ethylene units and containing from about 55% to about 95% by weight, of a fraction soluble in xylene at 25° C. (XS C ), both the amount of ethylene units and of the fraction XS C being referred to the weight of (C);
the amounts of (A), (B) and (C) being referred to the total weight of (A)+(B)+(C), wherein, following a progressive fractionation having a first, a second, and a third dissolution temperature (77° C., 100° C., and 130° C.) and the fraction collected at the second dissolution temperature corresponds to the second fractionation step and fraction 2, the composition has about 20% by weight or less of a fraction obtained in the second fractionation step (fraction 2)
and components (A), (B) and (C) are prepared in separate subsequent steps, operating in each step, except the first step, in the presence of the polymer formed and a catalyst used in the preceding step.

13. A formed article comprising:
a polyolefin blend of
(i) the polyolefin composition comprising:
(A) from about 5 to about 35% by weight of a propylene-based polymer containing about 90% by weight or more of propylene units and containing about 10% by weight or less of a fraction soluble in xylene at 25° C. (XS A ), both the amount of propylene units and of the fraction XS A being referred to the weight of (A);
(B) from about 25 to about 50% by weight, of a copolymer of ethylene and a C 3 -C 8 alpha-olefin containing from about 0.1% to about 20% by weight of alpha-olefin units and containing about 75% by weight or less of a fraction soluble in xylene at 25° C. (XS B ), both the amount of ethylene units and of the fraction XS B being referred to the weight of (B); and
(C) from about 30 to about 60% by weight, of a copolymer of ethylene and propylene containing from about 25% to about 75% by weight of ethylene units and containing from about 55% to about 95% by weight, of a fraction soluble in xylene at 25° C. (XS C ), both the amount of ethylene units and of the fraction XS C being referred to the weight of (C);
the amounts of (A), (B) and (C) being referred to the total weight of (A)+(B)+(C), wherein, following a progressive fractionation having a first, a second, and a third dissolution temperature (77° C., 100° C., and 130° C.) and the fraction collected at the second dissolution temperature corresponds to the second fractionation step and fraction 2, the composition has about 20% by weight or less of a fraction obtained in the second fractionation step (fraction 2); and
(ii) at least about 50% by weight, referred to the total weight of the polyolefin composition, of one or more additional polyolefins.

14. The formed article according to claim 13 , wherein the article is injection molded.

Assignees

• Basell Poliolefine Italia Srl

Inventors

• Cavalieri Claudio
• Grazzi Michele
• Pantaleoni Roberto

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L23/16 Primary

  Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08L2205/035

  containing four or more polymers in a blend · CPC title

• C08L2310/00

  Masterbatches · CPC title