Method for producing saturated aldehyde from 1,2-alkanediol
US-2015343429-A1 · Dec 3, 2015 · US
US10384998B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10384998-B2 |
| Application number | US-201816202914-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 28, 2018 |
| Priority date | May 31, 2016 |
| Publication date | Aug 20, 2019 |
| Grant date | Aug 20, 2019 |
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To provide a method for producing propionaldehyde directly from glycerol with high yield, gasified glycerol is brought into contact with a silica-type regular mesoporous body. More specifically, gasified glycerol is supplied to a catalyst layer containing a regular mesoporous body while heating the catalyst layer at a temperature ranging from 200 to 800° C. in such a manner that a W/F value can fall within the range from 0.001 to 1000 g·min/ml inclusive wherein W represents an amount (g) of a catalyst and F represents a supply rate (ml/min) of supplied glycerol.
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The invention claimed is: 1. A method for producing propionaldehyde wherein propionaldehyde is directly produced from glycerol, the method comprising contacting gasified glycerol with a silica-based regular mesoporous material. 2. The method for producing propionaldehyde according to claim 1 , wherein the regular mesoporous material has a pore size of 2.0 nm or more and 10.0 nm or less. 3. The method for producing propionaldehyde according to claim 1 , wherein the regular mesoporous material is FSM-16. 4. The method for producing propionaldehyde according to claim 1 , wherein the glycerol is biomass-derived glycerol. 5. The method for producing propionaldehyde according to claim 1 , wherein the gasified glycerol is supplied to the catalyst layer containing the regular mesoporous material. 6. The method for producing propionaldehyde according to claim 5 , wherein the glycerol is passed through the catalyst layer heated in the range of 200° C. to 800° C. 7. The method for producing glycerol according to claim 5 , wherein the supply of glycerol is carried out in a range of 0.001 g·min/ml or more and 1000 g·min/ml or less as W/F, where W is an amount (g) of the catalyst and F is a supply rate (ml/min) of the supplied glycerol.
Mesoporous materials not having base exchange properties, e.g. Si-MCM-41 · CPC title
by dehydration and rearrangement involving two hydroxy groups in the same molecule · CPC title
Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen · CPC title
involving transformation of singly bound oxygen functional groups to >C = O groups (involving two hydroxy groups C07C45/52; hydroperoxides C07C45/53) · CPC title
Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41 · CPC title
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