Method for producing hydrocarbons and alcohols

Patent metadata

Field	Value
Publication number	US-10384993-B2
Application number	US-201615572333-A
Country	US
Kind code	B2
Filing date	May 5, 2016
Priority date	May 8, 2015
Publication date	Aug 20, 2019
Grant date	Aug 20, 2019

Abstract

In accordance with the present invention, disclosed herein is a method comprising the steps for producing lower molecular weight C1-C5 hydrocarbons and alcohols. Also disclosed herein, are systems utilized to produce low molecular weight C1-C5 hydrocarbons and alcohols.

First claim

What is claimed is:

1. A method comprising the steps of:
a) providing natural gas comprising methane and N 2 ;
b) removing at least a portion of the N 2 from the natural gas, thereby producing a first gas comprising methane and less than about 2 mole % of N 2 ;
c) converting at least a portion of the first gas to synthesis gas comprising H 2 and CO;
d) converting at least a portion of the synthesis gas to a first product stream comprising methane, C2-C9 hydrocarbons, C10+ hydrocarbons, unreacted synthesis gas, and CO 2 ;
d1) separating at least a portion of the methane from the first product stream:
e) separating at least a portion of the unreacted synthesis gas from the first product stream; and
f) converting at least a portion of the unreacted synthesis gas to a first alcohol product comprising methanol and C2+ alcohols.

2. The method of claim 1 , wherein the first gas comprises less than about 1.5 mole % of N 2 .

3. The method of claim 1 , wherein the step of converting at least a portion of the first gas to synthesis gas comprising H 2 and CO is performed in a partial oxidation reactor.

4. The method of claim 1 , wherein at least about 80 wt % of the first gas is converted to the synthesis gas comprising H 2 and CO.

5. The method of claim 1 , wherein the first product stream comprises at least about 60 wt % of C2-C5 hydrocarbons.

6. The method of claim 1 , wherein the first product stream comprises from about 40 wt % to about 70 wt % of C2-C5 olefins.

7. The method of claim 1 , wherein the step of separating at least a portion of the unreacted synthesis gas from the first product stream comprises lowering the pressure of the first product stream, thereby lowering the temperature of the first product stream.

8. The method of claim 1 , wherein at least about 90 wt % of the first alcohol product comprises methanol, ethanol, propanol, butanol, or pentanol, or any combination thereof.

9. The method of claim 1 , wherein the method further comprises the step of separating of at least a portion of CO 2 from the first product stream.

10. The method of claim 9 , wherein the at least a portion of the separated CO 2 is recycled back to the step of converting the at least a portion of the first gas to synthesis gas comprising H 2 and CO.

11. The method of claim 1 , wherein the method further comprises the step of separating at least a portion of C2-C3 hydrocarbons from the first product stream.

12. The method of claim 1 , wherein the method further comprises the step of separating at least a portion of the methanol from the first alcohol product, thereby producing a second product comprising C2+ alcohols.

13. The method of claim 12 , wherein the method further comprises the step of dehydrating at least a portion of the C2+ alcohols in the second product to C2+ olefins.

14. The method of claim 1 , wherein the natural gas further comprises sulfur and wherein the method further comprises the step of removing at least a portion of the sulfur from the natural gas.

15. The method of claim 11 , wherein the method further comprises the step of separating at least a portion of C2-C3 olefins from the at least a portion of C2-C3 hydrocarbons, thereby producing a third product.

16. The method of claim 15 , wherein at least a portion of the third product is recycled into the first gas.

17. The method of claim 1 , wherein the method further comprises the step of separating at least a portion of the C10+ hydrocarbons from the first product stream.

18. The method of claim 1 , wherein the method comprises:
a) providing natural gas comprising methane, N 2 , and sulfur;
b) removing at least a portion of the sulfur from the natural gas;
c) removing at least a portion of the N 2 from the natural gas, thereby producing first gas comprising methane and less than about 1 mole % of N 2 ;
d) converting at least a portion of the first gas to synthesis gas comprising H 2 and CO, wherein the conversion comprises partially oxidizing the first gas;
e) converting at least a portion of the synthesis gas to a first product stream comprising methane, C2-C9 hydrocarbons, C10+ hydrocarbons, aromatics, unreacted synthesis gas, wax, and CO 2 , wherein the conversion comprises reacting a portion of the H 2 and a portion of the CO in synthesis gas in the presence of a Fischer-Tropsch catalyst;
f) separating at least a portion of the wax from the first product stream;
g) separating at least a portion of the CO 2 from the first product stream;
h) separating at least a portion of the methane from the first product stream;
i) converting at least a portion of the unreacted synthesis gas in the first product stream to a first alcohol product comprising methanol and C2+ alcohols;
j) separating at least a portion of the methanol from the first alcohol product, thereby producing a second product; and
k) dehydrating the at least a portion of the C2+ alcohols in the second product to C2+ olefins.

Assignees

• Sabic Global Technologies Bv

Inventors

• Ahmed Labeeb Chaudhary
• Karim Khalid
• Al-Hammad Ali

Classifications

• C07C1/24

  by elimination of water · CPC title

• C01B2203/0261

  containing a catalytic partial oxidation step [CPO] · CPC title

• C07C1/0485

  Set-up of reactors or accessories; Multi-step processes · CPC title

• C10G3/00

  Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids (production from non-melting solid oxygen-containing carbonaceous materials C10G1/00) · CPC title

• C10G2/32

  with the use of catalysts · CPC title