Modified thin film composite reverse osmosis membrane and a process for preparation thereof

Patent metadata

Field	Value
Publication number	US-10384171-B2
Application number	US-201314647065-A
Country	US
Kind code	B2
Filing date	Nov 25, 2013
Priority date	Nov 23, 2012
Publication date	Aug 20, 2019
Grant date	Aug 20, 2019

Abstract

The present invention relates to a complete process for preparation of high flux and salt rejection thin film composite (TFC) reverse osmosis (RO) membrane including process for preparation of support membrane for thin film, process for thin film coating of support membrane by in-situ interfacial polymerization between diamines and trimesoyl chloride, machine design, chemistry and details of process (engineering+chemistry+ambient) parameter at 1×100 sqm scale upgradeable to a scale even 10-20 times higher. The produced membrane is characterized by 96% salt rejection and 48 LM-2H 1 flux with 2000 ppm sodium chloride solution at 250 psi pressure and 95% salt rejection and 46 LM2H 1 flux with 35000 ppm sodium chloride solution at 900 psi pressure. The present invention also relates to complete machine design for PSF ultrafiltration membrane casting and coating for TFC membrane production at commercial level.

First claim

We claim:

1. A modified thin film composite (TFC) reverse osmosis membrane on conventional polysulphone support wherein the membrane comprises a polyamide ultrathin layer which is formed by an interfacial polymerization reaction at the aqueous-organic interface between an aqueous diamine phase and an organic-acid chloride phase in presence of 0.27-2.7% Red-Ox initiator at temperature ranging between 20-40° C. for a period ranging between 10-60 min followed by curing the said membrane at temperature ranging between 50-70° C.;
wherein:
the aqueous diamine phase comprises 2-3% phenylenediamine MPD (w/v), 0.5-1.5% dimethylsulfoxide DMSO (v/v), 0.2-1% Glycerol (v/v), 0.1-1% sulphopropyl methacrylate SPMA (w/v), 0.01% (methylene-bis-acrylamide) MBA (w/v), 0.1% polyvinyl alcohol (PVA) (w/v); and
the organic acid chloride phase comprises 0.1-0.125% trimesoyl chloride TMC (w/v), 0.01-0.05% dimethylformamide DMF (v/v), and hexane.

2. A modified thin film composite reverse osmosis membrane as claimed in claim 1 , wherein said membrane is characterized by 96-97.5% salt rejection and 38-67.6 LM −2 H − 1 flux with 2200 ppm sodium chloride solution at 250 psi i.e. 1723.689 kPa pressure at 27° C.

3. Use of a modified thin film composite reverse osmosis membrane as claimed in claim 1 , in brackish water purification.

4. Use of a modified thin film composite reverse osmosis membrane as claimed in claim 1 , in high salinity water purification.

Assignees

• Council Scient Ind Res

Inventors

• Reddy Alamuru Venkata Rami
• Kumar Saha Nirmal
• Kumar Jewrajka Suresh
• Trivedi Jitendra Jaydevprasad
• Ray Paramita
• Pathak Nagendra
• Trivedi Gaurang Shambuprasad
• Gohil Temubha Bhupatsinh
• Patil Rahul Shubhash

Classifications

• B01D71/56 Primary

  Polyamides, e.g. polyester-amides · CPC title

• B01D2325/28

  Degradation or stability over time · CPC title

• B01D67/0088

  Physical treatment with compounds, e.g. swelling, coating or impregnation · CPC title

• B01D2323/12

  Specific ratios of components used · CPC title

• C02F2101/10

  Inorganic compounds · CPC title