Method of predicting the concentration of asphaltenes using a first precipitant and correlation back to an asphaltene concentration measurement using a second precipitant

Patent metadata

Field	Value
Publication number	US-10379100-B2
Application number	US-201515564802-A
Country	US
Kind code	B2
Filing date	Apr 7, 2015
Priority date	Apr 7, 2015
Publication date	Aug 13, 2019
Grant date	Aug 13, 2019

Abstract

A method for determining the asphaltene content of oil includes obtaining an oil sample, determining an optical spectrum of the oil sample and removing asphaltenes from the oil sample by precipitating asphaltenes using a first alkane precipitant. The method also includes determining an optical spectrum of maltenes of the oil sample and subtracting the optical spectrum of the maltenes of the oil sample from the optical spectrum of the oil sample to yield an optical spectrum of asphaltenes of the oil sample. The method further includes using the optical spectrum of asphaltenes of the oil sample to determine asphaltene content of the oil sample using a second alkane precipitant.

First claim

What is claimed is:

1. A method for characterizing asphaltene content of an oil sample, comprising:
(a) obtaining the oil sample;
(b) determining an optical spectrum of the oil sample;
(c) removing asphaltenes from the oil sample to yield maltenes of the oil sample by precipitating asphaltenes using a first alkane precipitant, wherein the first alkane precipitant has a molecular formula with a number of carbon atoms greater than that of heptane;
(d) determining an optical spectrum of the maltenes of the oil sample precipitated with the first alkane precipitant in (c);
(e) determining spectral data related to asphaltenes of the oil sample by subtracting at least part of the optical spectrum of (d) from a corresponding part of the optical spectrum of (b); and
(f) using a correlation that relates the spectral data as determined in (e) to concentration of asphaltenes in the oil sample as measured by precipitation using a second alkane precipitant, wherein the second alkane precipitant has a molecular formula with a number of carbon atoms equal to or less than heptane.

2. The method of claim 1 , wherein the oil sample of (a) is diluted with a solvent before its optical spectrum is determined in (b) and the operations of (c) and (d) are conducted on the oil sample of (a) without diluting the oil sample of (a).

3. The method of claim 2 , wherein the solvent is selected from the group consisting of toluene, xylene, or 1 methylnaphthalene.

4. The method of claim 1 , wherein the optical spectrum of the oil sample is determined in (b) by analyzing at least a portion of the oil sample with a spectrometer.

5. The method of claim 1 , wherein the asphaltenes are removed from the oil sample in (c) by mixing the oil sample with the first alkane precipitant and removing precipitated asphaltenes from the oil-precipitant mixture.

6. The method of claim 5 , wherein the oil sample is mixed with the first alkane precipitant in a microfluidic mixer.

7. The method of claim 5 , wherein the precipitated asphaltenes are removed from the oil-precipitant mixture using a microfluidic filter.

8. The method of claim 1 , wherein the optical spectrum of (d) is determined by analyzing at least a portion of the maltenes of the oil sample of (c) with a spectrometer.

9. The method of claim 1 , wherein the spectral data related to asphaltenes of the oil sample is determined in (e) by i) subtracting a part of the optical spectrum of (d) at a longer wavelength from a part of the optical spectrum of (d) at a shorter wavelength and ii) subtracting a part of the optical spectrum of (b) at the longer wavelength from a part of the optical spectrum of (b) at the shorter wavelength and iii) subtracting the result of (i) from the result of ii).

10. The method of claim 9 , wherein the longer wavelength is 800 nanometers and the shorter wavelength is 600 nanometers.

11. The method of claim 1 , wherein the first alkane precipitant is selected from the group consisting of octane, nonane, decane, undecane, dodecane, tridecane, tetradecane, pentadecane, and hexadecane.

12. The method of claim 1 , wherein the second alkane precipitant is selected from the group consisting of heptane, hexane, and pentane.

13. The method of claim 1 , wherein the correlation of (f) is performed on a computer processing system using a correlation function that relates the spectral data as determined in (e) to concentration of asphaltenes in the oil sample as measured by precipitation using the second alkane precipitant.

14. A method for characterizing asphaltene content of an oil sample, comprising:
(a) obtaining the oil sample;
(b) determining an optical spectrum of the oil sample;
(c) removing asphaltenes from the oil sample to yield maltenes of the oil sample by precipitating asphaltenes using a first alkane precipitant, wherein the first alkane precipitant has a molecular formula with a number of carbon atoms greater than that of heptane;
(d) determining an optical spectrum of the maltenes of the oil sample precipitated with the first alkane precipitant in (c);
(e) determining spectral data related to asphaltenes of the oil sample by subtracting at least part of the optical spectrum of (d) from a corresponding part of the optical spectrum of (b); and
(f) using a correlation that relates the spectral data as determined in (e) to concentration of asphaltenes in the oil sample as measured by precipitation using a second alkane precipitant, wherein the second alkane precipitant is different from the first alkane precipitant and has a molecular formula with a number of carbon atoms greater than that of heptane; and
(g) using a correlation that relates the spectral data as determined in (e) to concentration of asphaltenes in the oil sample as measured by precipitation using a third alkane precipitant, wherein the third alkane precipitant has a molecular formula with a number of carbon atoms equal to or lower than heptane.

15. The method of claim 14 , wherein the correlation of (f) is performed on a computer processing system using a first correlation function that relates the spectral data as determined in (e) to concentration of asphaltenes in the oil sample as measured by precipitation using the second alkane precipitant.

16. The method of claim 15 , wherein the correlation of (g) is performed on the computer processing system using a second correlation function that relates the spectral data as determined in (e) to concentration of asphaltenes in the oil sample as measured by precipitation using the third alkane precipitant.

17. The method of claim 16 , wherein the spectral data related to asphaltenes of the oil sample as determined in (e) comprises a characteristic optical density or absorbance, wherein the first correlation function relates the characteristic optical density or absorbance to concentration of asphaltenes in the oil sample as measured by precipitation using the second alkane precipitant, and wherein the second correlation function relates the characteristic optical density or absorbance to concentration of asphaltenes in the oil sample as measured by precipitation using the third alkane precipitant.

18. The method of claim 14 , which is carried out by a borehole tool with the oil sample at downhole pressure and temperature conditions.

19. The method of claim 13 , wherein the spectral data related to asphaltenes of the oil sample as determined in (e) comprises a characteristic optical density or absorbance, and wherein the correlation function relates the characteristic optical density or absorbance to concentration of asphaltenes in the oil sample as measured by precipitation using the second alkane precipitant.

20. The method of claim 1 , which is carried out by a borehole tool with the oil sample at downhole pressure and temperature conditions.

Assignees

• Schlumberger Tech Coporation
• Schlumberger Technology Corp

Inventors

• Mostowfi Farshid
• Sieben Vincent Joseph

Classifications

• E21B49/10

  using side-wall fluid samplers or testers · CPC title

• E21B49/0875

  determining specific fluid parameters · CPC title

• G01N33/2835

  Specific substances contained in the oils or fuels · CPC title

• G01N33/2823 Primary

  Raw oil, drilling fluid or polyphasic mixtures · CPC title

• G01N2021/8472

  Investigation of composite materials · CPC title