Methods for recovering metals from electronic waste, and related systems

Patent metadata

Field	Value
Publication number	US-10378081-B2
Application number	US-201715690717-A
Country	US
Kind code	B2
Filing date	Aug 30, 2017
Priority date	Sep 3, 2015
Publication date	Aug 13, 2019
Grant date	Aug 13, 2019

Abstract

A method of recovering metals from electronic waste comprises providing a powder comprising electronic waste in at least a first reactor and a second reactor and providing an electrolyte comprising at least ferric ions in an electrochemical cell in fluid communication with the first reactor and the second reactor. The method further includes contacting the powders within the first reactor and the second reactor with the electrolyte to dissolve at least one base metal from each reactor into the electrolyte and reduce at least some of the ferric ions to ferrous ions. The ferrous ions are oxidized at an anode of the electrochemical cell to regenerate the ferric ions. The powder within the second reactor comprises a higher weight percent of the at least one base metal than the powder in the first reactor. Additional methods of recovering metals from electronic waste are also described, as well as an apparatus of recovering metals from electronic waste.

First claim

What is claimed is:

1. A method of recovering metals from electronic waste, the method comprising:
providing a powder comprising electronic waste in at least a first reactor and a second reactor;
providing an electrolyte in an electrochemical cell in fluid communication with the first reactor and the second reactor;
contacting the powder within the first reactor with the electrolyte to dissolve at least one base metal from the powder into the electrolyte while a plurality of precious metals remain in the powder;
contacting the powder within the second reactor with the electrolyte to dissolve at least one base metal from the powder into the electrolyte; and
after contacting the powder within the first reactor with the electrolyte, placing the first reactor out of fluid communication with the electrochemical cell and in fluid communication with a leaching vessel containing a leachate formulated to selectively leach at least one precious metal from the powder while the powder remains within the first reactor.

2. The method of claim 1 , wherein providing a powder comprising electronic waste comprises separating magnetic components from non-magnetic components of the electronic waste and powderizing the non-magnetic components to form the powder.

3. The method of claim 1 , further comprising selecting the electrolyte to comprise ferrous ions and ferric ions.

4. The method of claim 1 , further comprising selecting the leachate to comprise a material formulated to leach gold from the powder.

5. The method of claim 4 , further comprising, after leaching gold from the powder into the leachate, precipitating dissolved gold in the leachate with sodium metabisulphite, zinc metal, or oxalic acid.

6. The method of claim 1 , wherein contacting the powder within the first reactor with the electrolyte to dissolve at least one base metal from the powder comprises dissolving at least one of zinc, tin, and lead into the electrolyte prior to dissolving at least one of nickel and copper into the electrolyte.

7. The method of claim 1 , wherein contacting the powder within the first reactor with the electrolyte and contacting the powder within the second reactor with the electrolyte comprises passing the electrolyte from the electrochemical cell to the first reactor, from the first reactor to the second reactor, and from the second reactor to the electrochemical cell.

8. The method of claim 7 , further comprising, after placing the first reactor out of fluid communication with the electrochemical cell, placing a third reactor in fluid communication with the electrochemical cell, and flowing the electrolyte from the electrochemical cell to the second reactor, from the second reactor to the third reactor, and from the third reactor to the electrochemical cell.

9. The method of claim 1 , further comprising selecting the leachate to comprise a thiosulfate.

10. A reactor system for recovering metals from electronic waste, the reactor system comprising:
a plurality of reactors substantially filled with a powder comprising electronic waste;
a first electrochemical cell comprising a first electrolyte; and
a first leaching vessel including a first leachate formulated to dissolve silver from the powder;
wherein each reactor of the plurality of reactors is configured to be placed in fluid communication with each of the first electrochemical cell and the first leaching vessel while the powder remains within a respective reactor of the plurality of reactors.

11. The reactor system of claim 10 , further comprising a second leaching vessel including a second leachate formulated to dissolve gold from the powder in each of the plurality of reactors, the second leaching vessel configured to be placed in fluid communication with each reactor of the plurality of reactors after the respective powders are exposed to the first electrolyte.

12. The reactor system of claim 11 , wherein the second leachate comprises hypochlorite, a bromine-based solution, a bromide-based solution, or a cyanide solution.

13. The reactor system of claim 11 , wherein each reactor of the plurality of reactors is configured to be placed in fluid communication with the second leaching vessel while the powder remains within the respective reactor of the plurality of reactors.

14. The reactor system of claim 10 , further comprising a second electrochemical cell configured to be placed in fluid communication with each reactor of the plurality of reactors, the second electrochemical cell including an electrolyte formulated to dissolve at least one precious metal from the powder after the powder is exposed to the first electrolyte and the first leachate.

Assignees

• Battelle Energy Alliance Llc

Inventors

• Lister Tedd E
• Parkman Jacob A
• Diaz Aldana Luis A
• Clark Gemma
• Dufek Eric J
• Keller Philip

Classifications

• C25C7/06

  Operating or servicing · CPC title

• C22B11/046 Primary

  from manufactured products, e.g. from printed circuit boards, from photographic films, paper or baths · CPC title

• C25C1/08

  of nickel or cobalt · CPC title

• C22B3/44

  by chemical processes (treatment or purification of solutions by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42) · CPC title

• C25C1/16

  of zinc, cadmium or mercury · CPC title