Thermally reversible thermal interface materials with improved moisture resistance
US-9085719-B2 · Jul 21, 2015 · US
US10377877B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-10377877-B2 |
| Application number | US-201715619863-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jun 12, 2017 |
| Priority date | Aug 30, 2016 |
| Publication date | Aug 13, 2019 |
| Grant date | Aug 13, 2019 |
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A self-healing thermal interface material includes a reactive silicone-based material and a thermally conductive filler material. The reactive silicone-based material is modified to include one or more hydrogen bonding functional groups.
Opening claim text (preview).
What is claimed is: 1. A process of forming a self-healing thermal interface material, the process comprising: forming a blend, the blend including: a silicone-based material that includes a hydrogen bonding functional group; and a thermally conductive filler material that includes a thymine functional group, an adenine functional group, or a combination thereof; and forming a self-healing thermal interface material that includes the blend. 2. The process of claim 1 , wherein the thermally conductive filler material includes the thymine functional group, and wherein the hydrogen bonding functional group includes the adenine functional group. 3. The process of claim 2 , wherein the thermally conductive filler material includes an alumina particle having the thymine functional group chemically bonded to a surface of the alumina particle. 4. The process of claim 2 , wherein the silicone-based material includes a silicone polymer, and wherein the adenine functional group is chemically bonded to a polymer backbone of the silicone polymer. 5. The process of claim 1 , wherein the thermally conductive filler material includes the adenine functional group, and wherein the hydrogen bonding functional group includes the thymine functional group. 6. The process of claim 5 , wherein the thermally conductive filler material includes an alumina particle having the adenine functional group chemically bonded to a surface of the alumina particle. 7. The process of claim 5 , wherein the silicone-based material includes a silicone polymer, and wherein the thymine functional group is chemically bonded to a polymer backbone of the silicone polymer. 8. The process of claim 1 , wherein the silicone-based material includes a blend of a first silicone polymer that includes the adenine functional group and a second silicone polymer that includes the thymine functional group. 9. A process of forming a self-healing thermal interface material, the process comprising: forming a blend, the blend including: a silicone-based material; a first thermally conductive filler material that includes a thymine functional group; and a second thermally conductive filler material that includes an adenine functional group; and forming a self-healing thermal interface material that includes the blend. 10. The process of claim 9 , wherein the first thermally conductive filler material includes an alumina particle having the thymine functional group chemically bonded to a surface of the alumina particle. 11. The process of claim 9 , wherein the second thermally conductive filler material includes an alumina particle having the adenine functional group chemically bonded to a surface of the alumina particle. 12. The process of claim 9 , wherein the silicone-based material includes a silicone polymer having a hydrogen bonding functional group chemically bonded to a polymer backbone of the silicone polymer. 13. The process of claim 12 , wherein the hydrogen bonding functional group includes the thymine functional group, the adenine functional group, or a combination thereof. 14. The process of claim 9 , wherein the silicone-based material includes a blend of a first silicone polymer that includes the adenine functional group and a second silicone polymer that includes the thymine functional group. 15. A process of forming an apparatus that includes a self-healing thermal interface material, the process comprising: disposing a self-healing thermal interface material on a heat generating component; and disposing a heat dissipating component on the self-healing thermal interface material, wherein the self-healing thermal interface material includes a blend of a silicone-based material and at least one thermally conductive filler material, the at least one thermally conductive filler material including: a thermally conductive filler material that includes a thymine functional group, an adenine functional group, or a combination thereof; or a first thermally conductive filler material that includes a thymine functional group and a second thermally conductive filler material that includes an adenine functional group. 16. The process of claim 15 , wherein the heat generating component includes a die or a lidded die. 17. The process of claim 15 , wherein the heat dissipating component includes a heat sink or a cold plate. 18. The process of claim 15 , wherein the silicone-based material includes a silicone polymer having a hydrogen bonding functional group chemically bonded to a polymer backbone of the silicone polymer. 19. The process of claim 18 , wherein the hydrogen bonding functional group includes the thymine functional group, the adenine functional group, or a combination thereof. 20. The process of claim 15 , wherein the silicone-based material includes a blend of a first silicone polymer that includes the adenine functional group and a second silicone polymer that includes the thymine functional group.
containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen · CPC title
Solid materials, e.g. powdery or granular · CPC title
nitrogen-containing groups · CPC title
containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title
of aluminium · CPC title
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