Methods and systems for improving the energy efficiency of carbon dioxide capture

Patent metadata

Field	Value
Publication number	US-10376829-B2
Application number	US-201715621889-A
Country	US
Kind code	B2
Filing date	Jun 13, 2017
Priority date	Jun 13, 2017
Publication date	Aug 13, 2019
Grant date	Aug 13, 2019

Abstract

A system for carbon dioxide capture from a gas mixture comprises a lean solvent comprising 3-amino-1-propanol (AP), 2-dimethylamino-2-methyl-1-propanol (DMAMP), and water; an absorber containing at least a portion of the lean solvent, wherein the absorber is configured to receive the lean solvent and a gaseous stream comprising carbon dioxide, contact the lean solvent with the gaseous stream, and produce a rich solvent stream and a gaseous stream depleted in carbon dioxide; a stripper, wherein the stripper is configured to receive the rich solvent stream; a cross-exchanger fluidly coupled to a rich solvent outlet on the absorber and a rich solvent inlet on the stripper; a reboiler fluidly coupled to a lower portion of the stripper; and a condenser fluidly coupled to a vapor outlet of the stripper.

First claim

What is claimed is:

1. A method for capturing carbon dioxide from a gas mixture comprising:
contacting a gaseous stream comprising carbon dioxide with a lean solvent, wherein the lean solvent comprises 3-amino-1-propanol (AP), 2-dimethylamino-2-methyl-1-propanol (DMAMP), and water;
absorbing at least a portion of the carbon dioxide in the lean solvent to produce a rich solvent;
transferring the rich solvent to a stripper, wherein the stripper comprises a reboiler;
applying heat to the rich solvent using the reboiler;
generating a vapor stream within the reboiler while incurring an energy consumption to regenerate the lean solvent, wherein the vapor stream comprises steam and at least a portion of the carbon dioxide from the rich solvent; and
transferring the vapor stream to a condenser.

2. The method of claim 1 , wherein a heat duty of the condenser is reduced relative to a corresponding method in which the solvent does not include the combination AP and DMAMP, and reducing a heat duty of the reboiler relative to a corresponding process in which the solvent does not include the combination of AP and DMAMP.

3. The method of claim 1 , wherein the energy consumption of the method is reduced by at least 5% relative to a corresponding process in which the solvent does not include the combination of AP and DMAMP.

4. The method of claim 1 , wherein the lean solvent comprises a ratio of AP to DMAMP between approximately 1:11 and 5:1.

5. The method of claim 1 , wherein the lean solvent comprises approximately 10 wt % AP and approximately 40 wt % DMAMP.

6. The method of claim 5 , wherein absorbing at least a portion of the carbon dioxide in the lean solvent to produce a rich solvent does not form a precipitate.

7. The method of claim 1 , further comprising:
generating a vapor stream by flashing the lean solvent from the reboiler in a lean flash tank;
compressing the vapor stream from the lean flash tank; and
reintroducing the compressed vapor to the stripper.

Assignees

• Fluor Tech Corp

Inventors

• Mathias Paul M
• Reddy Satish
• Yonkoski Joseph

Classifications

• B01D2258/0283

  Flue gases · CPC title

• B01D2252/504

  Mixtures of two or more absorbents · CPC title

• B01D2252/20484

  with one hydroxyl group · CPC title

• B01D2252/20431

  Tertiary amines · CPC title

• B01D2252/20421

  Primary amines · CPC title