Coated lithium-nickel composite oxide particles, and method for producing coated lithium-nickel composite oxide particles

Patent metadata

Field	Value
Publication number	US-10374226-B2
Application number	US-201515314729-A
Country	US
Kind code	B2
Filing date	May 20, 2015
Priority date	May 30, 2014
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

Provided are: superior coated lithium-nickel composite oxide particles which have an environmental stability that enables suppression of the occurrence of impurities due to absorption of moisture or carbon dioxide, which have high adhesion that prevents a coating layer from readily separating, and which have lithium ion conductivity; and a method for producing such particles. Provided is a method for producing coated lithium-nickel composite oxide particles, the method being characterized by contacting a cyclic siloxane with the surfaces of nickel-based lithium-nickel composite oxide particles to form surface coats. The particles have high adhesion to a coating layer and as a compound can suppress the permeation of moisture and carbon dioxide, and also have lithium ion conductivity. It is therefore possible to provide coated lithium-nickel composite oxide particles that are excellent for use in lithium ion cells.

First claim

The invention claimed is:

1. Coated lithium-nickel composite oxide particles, wherein surface coats are formed on surfaces of nickel-based lithium-nickel composite oxide particles and the surface coats are silicone compounds represented by the following Formula (3) obtained by ring-opening reaction,
(R 1 R 2 SiO) a [(R 1 )(R 2 ) 2 SiO 1/2 ] b (R 1 SiO 3/2 ) c   (3)

wherein R 1 represents a methyl group, R 2 at least partially includes an ether group and represents a functional group including one or more selected from the group consisting of at least an ether group and a hydrogen group, and a, b, and c represent a positive integer including zero.

2. The coated lithium-nickel composite oxide particles according to claim 1 , wherein the R 2 in the above Formula (3) is an ether group of the following Formula (4),
—C n H 2n —O—C m H 2m+1   (4)

wherein n, and m represent an integer of from 2 to 10, respectively.

3. The coated lithium-nickel composite oxide particles according to claim 1 , wherein mass of the surface coats is from 0.1 to 1.0% by mass based on the lithium-nickel composite oxide particles.

4. The coated lithium-nickel composite oxide particles according to claim 1 , wherein the coated lithium-nickel composite oxide particles are used as a positive-electrode active substance of a lithium-ion battery.

5. The coated lithium-nickel composite oxide particles according to claim 1 , wherein the coated lithium-nickel composite oxide particles are spherical particles having an average particle diameter of from 5 to 20 μm.

6. The coated lithium-nickel composite oxide particles according to claim 1 , wherein the surface coats are formed onto the entire surface of the nickel-based lithium-nickel composite oxide particles.

7. The coated lithium-nickel composite oxide particles according to claim 1 , wherein the surface coats are directly cross-linked to the surfaces of the nickel-based lithium-nickel composite oxide particles.

8. A method for producing the lithium-nickel composite oxide particles of claim 1 , comprising: forming surface coats by bringing a cyclic siloxane into contact with surfaces of nickel-based lithium-nickel composite oxide particles.

9. The method for producing coated lithium-nickel composite oxide particles according to claim 8 , wherein the cyclic siloxane is 2,4,6,8-tetramethylcyclotetrasiloxane of the following Formula (1), and forms surface coats by gas-phase contact

10. The method for producing coated lithium-nickel composite oxide particles according to claim 9 , wherein an environmental temperature at the time of the gas-phase contact is from 40° C. to 100° C.

11. The method for producing coated lithium-nickel composite oxide particles according to claim 9 , wherein an organic ether compound or organic ester compound having an unsaturated bond at one end is added to a residual hydrogen atom after the gas-phase contact.

12. The method for producing coated lithium-nickel composite oxide particles according to claim 8 , wherein, the lithium-nickel composite oxide is represented by the following Formula (2),
Li x Ni (1-y-z) M y N z O 2 )  (2)

wherein x is a value of from 0.80 to 1.10, y is a value of from 0.01 to 0.20, z is a value of from 0.01 to 0.15, and 1-y-z is a value exceeding 0.65, and M represents at least one element selected from Co or Mn, and N represents at least one element selected from Al, In or Sn.

Assignees

• Sumitomo Metal Mining Co

Inventors

• Ota Yosuke
• Yamabe Hidetoshi

Classifications

• B01J13/04

  by physical processes, e.g. drying, spraying · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/525 Primary

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M4/36

  Selection of substances as active materials, active masses, active liquids · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title