Organic light-emitting device and method of producing the same

Patent metadata

Field	Value
Publication number	US-10374187-B2
Application number	US-201514669606-A
Country	US
Kind code	B2
Filing date	Mar 26, 2015
Priority date	May 22, 2012
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

An organic light-emitting device and a method of producing the same, the device including a substrate; a first electrode layer on the substrate; an emission layer on the first electrode layer; an electron transport layer on the emission layer, the electron transport layer including first electron transport layers and a second electron transport layer between the first electron transport layers and the second electron transport layer including a lanthanide metal; and a second electrode layer on the electron transport layer.

First claim

What is claimed is:

1. An organic light-emitting device, comprising:
a substrate;
a first electrode layer on the substrate;
an emission layer on the first electrode layer;
an electron transport layer on the emission layer, the electron transport layer including first electron transport layers and at least one second electron transport layer, wherein the at least one second electron transport layer:
is between the first electron transport layers,
has a thickness of about 5 Å to about 15 Å, and
includes a lanthanide metal;

a second electrode layer on the electron transport layer; and
an electron injection layer between the electron transport layer and the second electrode layer, wherein the electron injection layer includes a carboxylate compound of an alkali metal, an acetate compound of an alkali metal, an azide compound of an alkali metal, or a carboxide of an alkali metal.

2. The organic light-emitting device of claim 1 , wherein the second electrode layer includes an Ag-rich alloy containing a dominant amount of Ag.

3. The organic light-emitting device of claim 1 , wherein the second electrode layer includes an alloy of Mg and Ag.

4. The organic light-emitting device of claim 3 , wherein a volume ratio of Mg to Ag in the second electrode layer is about 1:5 to about 1:10.

5. The organic light-emitting device of claim 1 , wherein the at least one second electron transport layer includes ytterbium or samarium.

6. The organic light-emitting device of claim 1 , wherein the electron transport layer includes two or more layers of the second electron transport layer.

7. The organic light-emitting device of claim 1 , wherein the first electron transport layers each include Alq 3 , 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP), 4,7-diphenyl-1,10-phenanthroline (Bphen), 3-(4-biphenylyl)-4-phenyl-5-tert-butylphenyl-1,2,4-triazole (TAZ), 4-(naphthalen-1-yl)-3,5-diphenyl-4H-1,2,4-triazole (NTAZ), 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (tBu-PBD), (bis(2-methyl-8-quinolinolato-N 1,O8)-(1,1′-biphenyl-4-olato)aluminum (BAlq), beryllium bis(benzoquinolin-10-olate (Bebq 2 ), or 9,10-di(naphthalene-2-yl)anthracene (ADN).

8. The organic light-emitting device of claim 1 , wherein the first electron transport layers each have a thickness of about 150 Å to about 500 Å.

9. The organic light-emitting device of claim 1 , wherein the first electron transport layers each further include a lithium complex.

10. The organic light-emitting device of claim 1 , further comprising at least one of a hole transport layer or a hole injection layer between the first electrode layer and the emission layer.

11. The organic light-emitting device of claim 10 , wherein the hole transport layer or the hole injection layer further includes a charge-generating material.

12. The organic light-emitting device of claim 11 , wherein the charge-generating material is a p-type dopant.

13. The organic light-emitting device of claim 1 , further comprising a hole injection transport layer between the first electrode layer and the emission layer, the hole injection transport layer having both hole injecting and transporting capabilities.

14. The organic light-emitting device of claim 1 , wherein:
the first electrode layer is an anode, and
the second electrode layer is a cathode.

15. A method of producing an organic light-emitting device, the method comprising:
providing a substrate;
providing a first electrode layer on the substrate;
forming a hole injection layer or a hole transport layer on the first electrode layer;
forming an emission layer on the hole injection layer or the hole transport layer;
forming an electron transport layer on the emission layer such that the electron transport layer includes first electron transport layers and at least one second electron transport layer, wherein the at least one second electron transport layer:
is between the first electron transport layers,
has a thickness of about 5 Å to about 15 Å, and
includes a lanthanide metal;

forming an electron injection layer on the electron transport layer; and
forming a second electrode layer on the electron injection layer, wherein the electron injection layer includes a carboxylate compound of an alkali metal, an acetate compound of an alkali metal, an azide compound of an alkali metal, or a carboxide of an alkali metal.

16. The method of claim 15 , wherein the second electrode layer includes an Ag-rich alloy containing a dominant amount of Ag.

17. The method of claim 15 , wherein the at least one second electron transport layer includes ytterbium or samarium.

Assignees

• Samsung Display Co Ltd

Inventors

• Kim Eung-Do

Classifications

• H01L51/0072

  Electricity · mapped topic

• H01L51/0061

  Electricity · mapped topic

• H01L51/005

  Electricity · mapped topic

• H01L51/0081

  Electricity · mapped topic

• H01L51/0058

  Electricity · mapped topic