Composition for forming coat-type insulating film

Patent metadata

Field	Value
Publication number	US-10373729-B2
Application number	US-201515508772-A
Country	US
Kind code	B2
Filing date	Aug 25, 2015
Priority date	Sep 3, 2014
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

Provided is an insulating coating composition. The composition is highly safe, in which an organic material to form an insulating film is dissolved highly stably. The composition can form an insulating film by coating, where the insulating film has a low relative permittivity, a high insulation resistance, and high wettability and allows an upper layer to be formed thereon by coating. The insulating coating composition according to the present invention contains a cyclic olefin copolymer and a solvent. The cyclic olefin copolymer is a copolymer between a cyclic olefin and a chain olefin. The solvent includes a compound represented by Formula (1) and having a normal boiling point of 100° C. to lower than 300° C. In Formula (1), Ring Z is a ring selected from a 5- or 6-membered saturated or unsaturated cyclic hydrocarbon and a benzene ring; and R 1 is selected from a hydrocarbon group and acyl. Ring Z has a substituent or substituents including the R 1 O group. When Ring Z has two or more substituents, two of the substituents may be linked to each other to form a ring with a carbon atom or atoms constituting Ring Z.

First claim

The invention claimed is:

1. An insulating coating composition, comprising:
a cyclic olefin copolymer being a copolymer between a cyclic olefin and a chain olefin; and
a solvent comprising a compound being represented by Formula (1) and having a normal boiling point of from 100° C. to lower than 300° C., Formula (1) expressed as follows:

wherein Ring Z is a ring selected from a 5- or 6-membered saturated or unsaturated cyclic hydrocarbon and a benzene ring; and R 1 is selected from a hydrocarbon group and acyl, where Ring Z has one or more substituents including R 1 O group, and where, when Ring Z has two or more substituents, two of the substituents may be linked to each other to form a ring with a carbon atom or atoms constituting Ring Z,
wherein the cyclic olefin copolymer is a copolymer consisting of a monomer unit represented by Formula (2) and derived from optionally substituted norbornene, and a monomer unit represented by Formula (3) and derived from the C 2 -C 8 chain α-olefin, Formulae (2) and (3) are expressed as follows:

wherein R 2 and R 3 are each, identically or differently, selected from hydrogen, halogens, hydroxy, substituted oxys, carboxy, substituted oxycarbonyls, substituted or unsubstituted carbamoyls, cyano, nitro, substituted or unsubstituted aminos, sulfo, heterocyclic groups except for heterocyclic groups containing an oxirane ring, alkyls, alkenyls, alkynyls, C 3 -C 8 cycloalkyls, and aryls and R 4 is selected from hydrogen atom and C 1 -C 6 alkyl.

2. The insulating coating composition according to claim 1 ,
wherein the solvent comprises at least one compound selected from the group consisting of cyclohexyl methyl ether, cyclohexanol acetate, methoxybenzene, ethoxybenzene, and cyclopentyl methyl ether.

3. The insulating coating composition according to claim 1 ,
wherein the composition has a viscosity of 0.1 to 5000 mPa·s at a temperature of 25° C. and a shear rate of 10 s −1 .

4. The insulating coating composition according to claim 2 ,
wherein the composition has a viscosity of 0.1 to 5000 mPa·s at a temperature of 25° C. and a shear rate of 10 s −1 .

Assignees

• Daicel Corp

Inventors

• Akai Yasuyuki
• Suzuki Youji
• Yokoo Takeshi

Classifications

• H10P14/6342

  Liquid deposition, e.g. spin-coating, sol-gel techniques or spray coating · CPC title

• H10P14/683

  carbon-based polymeric organic materials, e.g. polyimides, poly cyclobutene or PVC · CPC title

• H01B3/441 Primary

  from alkenes · CPC title

• C09D7/20

  Diluents or solvents · CPC title

• C09D145/00

  Coating compositions based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Coating compositions based on derivatives of such polymers (based on polymers of cyclic esters of polyfunctional acids C09D131/00; based on polymers of cyclic anhydrides or imides C09D135/00) · CPC title