Mechanical chameleon through dynamic real-time plasmonic tuning

Patent metadata

Field	Value
Publication number	US-10372012-B2
Application number	US-201615097680-A
Country	US
Kind code	B2
Filing date	Apr 13, 2016
Priority date	Nov 18, 2015
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

A mechanical chameleon through dynamic real-time plasmonic tuning, the external surface of which is covered by plasmonic cells is provided. Plasmonic cells, based on the combination of bimetallic nanodot arrays and electrochemical bias, use the electrochemical method elctrodepositing and stripping Ag shells on plasmonic Au nanodomes and then we achieve the reversible full color plasmonic cells/display. Plasmonic cells, under the control of circuits and sensors, make mechanical chameleon automatically change the color of its own when it's walking to the corresponding background color and always keeping the same color with the color background. This mechanical chameleon through dynamic real-time plasmonic tuning can capture and simulate the entire color-patterns of the environment and then drive the color-changing process in individual cells, fully merging the mechanical chameleon into the surroundings, which makes this technology is readily approachable.

First claim

What is claimed is:

1. A mechanical chameleon through dynamic real-time plasmonic tuning, the external surface of mechanical chameleon is covered by plasmonic cells, the plasmonic cells integrating plasmonic color tunability and electrodeposition induced structural transformability; the fabrication process of the plasmonic cells comprising: electrodepositing and stripping Ag shells on plasmonic Au nanodomes through electrochemical method; and forming Au-core/Ag-shell nanodomes structure; the plasmonic cells, under the control of circuits and sensors, make mechanical chameleon automatically change the color of its own when it's walking to a background with a different color and always keeping the same color as the background.

2. The mechanical chameleon through dynamic real-time plasmonic tuning of claim 1 , wherein: the fabrication process of Au-core/Ag-shell nanodomes structure comprises: firstly, an anodized aluminum oxide (AAO) film with highly ordered pores, serves as the template for etching a nano-hole array on SiO 2 , is transferred onto a SiO 2 film with a thickness of 50 nm on ITO glass; then, reactive ion etching (RIE) is performed in order to remove all 50 nm SiO 2 film underneath the AAO holes; and finally, the sample is packaged into a device and filled with gel electrolyte containing Ag+ion.

3. The mechanical chameleon through dynamic real-time plasmonic tuning of claim 1 , wherein: the fabrication process of Au-core/Ag-shell nanodomes structure comprises: the 3-D print technology is used to get highly ordered Au array on the surface of SiO 2 film with a thickness of 50 nm on ITO glass; and then the sample is packaged into a device and filled with gel electrolyte containing Ag + ion.

4. The mechanical chameleon through dynamic real-time plasmonic tuning of claim 1 , wherein: the electrode of Au-core/Ag-shell nanodomes structure is based on standard three-electrode system and 1.5 V voltage difference between two electrodes is used, but still offers good stability and repeatability.

5. The mechanical chameleon through dynamic real-time plasmonic tuning of claim 1 , wherein: the plasmonic cells display is modeled in the finite difference time domain (FDTD) simulation part.

6. The mechanical chameleon through dynamic real-time plasmonic tuning of claim 1 , comprising: electrodepositing the Ag shells on plasmonic Au nanodomes particles through electrochemical method, the evolution of nanodomes is characterized by a scanning electron microscopy (SEM), a transmission electron microscope (TEM) and an energy dispersive spectroscopy (EDS) mapping.

7. The mechanical chameleon through dynamic real-time plasmonic tuning of claim 1 , wherein: the Au-core/Ag-shell nanostructures are set as hemi-ellipsoids structure.

8. The mechanical chameleon through dynamic real-time plasmonic tuning of claim 1 , wherein: the mechanical chameleon equipped with autonomous control systems and a machine vision system is addressed by using the machine vision system, and acquired information from the machine vision system is automatically addressed and analyzed by the autonomous control systems and delivered to individual plasmonic cells, which is used to simulate the entire color-patterns of the environment so as to change the chameleon's body appearance accordingly.

9. The mechanical chameleon through dynamic real-time plasmonic tuning of claim 1 , wherein: the mechanical chameleon is manufactured by using 3-D print technology.

Assignees

• Univ Wuhan

Inventors

• Wang Guoping
• Chu Sheng
• Zhan Bihong
• Liu Sheng
• Yang Xingxing
• Chen Qijuan

Classifications

• G02F1/25 Primary

  as to hue or predominant wavelength · CPC title

• C23C26/00

  Coating not provided for in groups C23C2/00 - C23C24/00 · CPC title

• C25D11/045

  for forming AAO templates · CPC title

• C23C16/50

  using electric discharges {(generation and control of plasma in discharge tubes for surface treatment H01J37/32, H01J37/34)} · CPC title

• G02F2202/36

  Micro- or nanomaterials · CPC title