Sonochemical coating of textiles with metal oxide nanoparticles for antimicrobial fabrics

Patent metadata

Field	Value
Publication number	US-10370789-B2
Application number	US-201615132042-A
Country	US
Kind code	B2
Filing date	Apr 18, 2016
Priority date	Jun 30, 2008
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

We disclose a system for preparing antimicrobial surfaces, coated with metal oxide nanoparticles by means of a novel sonochemical method. These antibacterial surfaces are widely used in medical and other applications. The deposition of metal oxides known to possess antimicrobial activity, namely ZnO, MgO and CuO, can significantly extend the applications of textile fabrics, medical devices and other items and prolong the period of their use. By means of the novel sonochemical method disclosed here, uniform deposition of metal oxide nanoparticles is achieved simply.

First claim

What is claimed is:

1. A method comprising:
immersing a surface in a mixture of metal acetate (M(AC)2) added to a solution;
adjusting a pH of the mixture to a range of about 8-10; and
ultrasonically irradiating the mixture via ultrasonic waves, the ultrasonic waves
(i) sonochemically causing bubbles to form in the mixture; and
(ii) sonochemically causing the bubbles to collapse,

wherein the collapsing of the bubbles:
create metal oxide (MO) nanoparticles from the M(AC)2; and
form microjets near the surface that embed the MO nanoparticles into the surface.

2. The method of claim 1 , wherein the solution comprises water and a solvent.

3. The method of claim 2 , wherein the solvent comprises ethanol.

4. The method of claim 1 , wherein the pH is adjusted by addition of a basic material.

5. The method of claim 4 , wherein the basic material is ammonia.

6. The method of claim 1 , wherein the ultrasonic irradiation is at a frequency of approximately 20 kHz.

7. The method of claim 1 , wherein M is selected from a group consisting of metals Zn, Mg, Cu and any combination thereof.

8. The method of claim 1 , wherein the irradiating is carried out for 1 hour.

9. The method of claim 1 , wherein the irradiating is performed under a flow of argon.

10. The method of claim 1 , wherein the irradiating is carried out at approximately 30° C.

11. The method of claim 1 , wherein the surface contains between 0.1 wt % and 10 wt % of metal oxide (MO).

12. The method of claim 1 , further comprising purging the mixture to remove traces of CO 2 or air.

13. The method of claim 12 , wherein the purging is carried out with argon for 1 hour.

14. The method of claim 1 , wherein a concentration of the metal acetate M(AC)2 is between 0.002 M to 0.2 M, and wherein the formed MO nanoparticles have diameters of between 1 nm and 1000 nm.

15. The method of claim 1 , wherein the MO nanoparticles are embedded so that they are about equally distributed on the surface.

16. The method of claim 4 , further comprising:
a. removing the surface from the mixture;
b. removing the basic material from the surface by washing the surface with water; and
c. washing the surface with ethanol.

17. A method, comprising:
immersing a surface in a mixture of metal acetate (M(AC)2) added to water;
adjusting a pH of the mixture to a range of about 8-10; and
ultrasonically irradiating the mixture via ultrasonic waves, the ultrasonic waves
(i) sonochemically causing bubbles to form in the mixture; and
(ii) sonochemically causing the bubbles to collapse,

wherein the collapsing of the bubbles:
create metal oxide (MO) nanoparticles from the M(AC)2; and
form microjets near the surface that embed the MO nanoparticles into the surface.

18. The method of claim 17 , wherein M is selected from a group consisting of metals Zn, Cu and any combination thereof.

19. A method, comprising:
immersing a surface in a liquid mixture comprising metal acetate (M(AC)2);
adjusting a pH of the mixture to a range of about 8-10; and
ultrasonically irradiating the mixture via ultrasonic waves, the ultrasonic waves
(i) sonochemically causing bubbles to form in the mixture; and
(ii) sonochemically causing the bubbles to collapse,

wherein the collapsing of the bubbles:
create metal oxide (MO) nanoparticles from the M(AC)2; and
form microjets near the surface that embed the MO nanoparticles into the surface.

20. A method, comprising:
immersing a surface in a mixture comprising metal oxide (MO) nanoparticles;
adjusting a pH of the mixture to a range of about 8-10; and
ultrasonically irradiating the mixture via ultrasonic waves at a frequency of approximately 20 kHz, the ultrasonic waves
(i) sonochemically causing bubbles to form in the mixture; and
(ii) sonochemically causing the bubbles to collapse,
wherein the collapsing of the bubbles form microjets near the surface that embed MO nanoparticles in the mixture onto the surface.

21. A method, comprising:
immersing a surface in a mixture comprising metal acetate (M(AC)2);
forming metal oxide (MO) nanoparticles by adjusting a pH of the mixture to a range of about 8-10; and
ultrasonically irradiating the mixture via ultrasonic waves at a frequency of approximately 20 kHz, the ultrasonic waves
(i) sonochemically causing bubbles to form in the mixture; and
(ii) sonochemically causing the bubbles to collapse,
wherein the collapsing of the bubbles form microjets near the surface that embed the MO nanoparticles into the surface.

22. A method, comprising:
immersing a surface in a mixture comprising metal acetate M(AC)2;
adjusting a pH of the mixture to a range of about 8-10; and
sonochemically forming bubbles in the mixture by ultrasonically irradiating the mixture with ultrasonic waves at a frequency of approximately 20 kHz; and
sonochemically causing the bubbles to collapse so as to form microjets near the surface, the microjets embedding MO nanoparticles in the mixture onto the surface.

Assignees

• Univ Bar Ilan

Inventors

• Gedanken Aharon
• Nitzan Yeshayahu
• Perelshtein Ilana
• Perkas Nina
• Applerot Guy

Classifications

• A61L2300/102

  Metals or metal compounds, e.g. salts such as bicarbonates, carbonates, oxides, zeolites, silicates · CPC title

• D06M11/44

  Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates · CPC title

• D06M11/36

  with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond · CPC title

• C23C18/1216

  Metal oxides (C23C18/1212 takes precedence) · CPC title

• A61K9/06

  Ointments; Bases therefor; {Other semi-solid forms, e.g. creams, sticks, gels (composition of ointments, creams or gels A61K47/00)} · CPC title