Method and composition for contemporaneously dimerizing and hydrating a feed having butene to produce a gasoline composition

Patent metadata

Field	Value
Publication number	US-10370612-B2
Application number	US-201715472848-A
Country	US
Kind code	B2
Filing date	Mar 29, 2017
Priority date	Nov 1, 2011
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

Methods for producing alcohols and oligomers contemporaneously from a hydrocarbon feed containing mixed butenes using an acid based catalyst are provided. Additionally, methods for producing fuel compositions having alcohols and oligomers prepared from mixed olefins are also provided as embodiments of the present invention. In certain embodiments, the catalyst can include a dual phase catalyst system that includes a water soluble acid catalyst and a solid acid catalyst.

First claim

We claim:

1. A gasoline composition, the composition comprising:
a fuel-grade gasoline; and
an octane enhancing additive comprising mixed butanols and DIBs, wherein the octane enhancing additive is prepared by contacting a mixed butene stream with a dual phase catalyst system and water under conditions operable to oligomerize and hydrate the butenes to form the octane enhancing additive.

2. The composition of claim 1 , wherein the octane enhancing additive is present in an amount of between about 5 and 30% by weight of the gasoline composition.

3. The composition of claim 1 , wherein the gasoline composition has an increased RON and a decreased RVP, relative to the fuel-grade gasoline prior to being combined with the octane enhancing additive comprising the mixed butanols and DIBs.

4. The composition of claim 1 , wherein the dual phase catalyst system comprises a water soluble acid catalyst and a water insoluble acid catalyst.

5. The composition as claimed in claim 4 , wherein the water soluble acid catalyst is an organic acid selected from acetal acid, tosylate acid and perflurated acetic acid.

6. The composition as claimed in claim 4 , wherein the water soluble acid catalyst is an inorganic acid selected from HCl, H 3 PO 4 , and H 2 SO 4 .

7. The composition as claimed in claim 4 , wherein the water insoluble acid catalyst is selected from ion exchange resin, zeolite, and a supported acid.

Assignees

• Saudi Arabian Oil Co

Inventors

• Xu Wei
• Mohammad Thamer A
• Harale Aadesh
• Shaik Kareemuddin M

Classifications

• C10L1/182

  containing hydroxy groups; Salts thereof {(C10L1/1802, C10L1/1805, C10L1/1808, C10L1/1811, C10L1/1814, C10L1/1817 take precedence)} · CPC title

• C07C2531/10

  sulfonated · CPC title

• C10G2300/305

  Octane number, e.g. motor octane number [MON], research octane number [RON] · CPC title

• C07C31/12

  containing four carbon atoms · CPC title

• C10L2200/0254

  Oxygen containing compounds · CPC title