Compositions based on ethylene-vinyl acetate copolymers and their use as anti-gelling additives of paraffinic crude oils

Patent metadata

Field	Value
Publication number	US-10370607-B2
Application number	US-201415102138-A
Country	US
Kind code	B2
Filing date	Dec 5, 2014
Priority date	Dec 6, 2013
Publication date	Aug 6, 2019
Grant date	Aug 6, 2019

Abstract

A polymeric composition suitable for lowering the Pour Point of paraffinic crude oils comprising a synergic mixture including at least two ethylene-vinyl acetate copolymers respectively having an average molecular weight Mw lower than 130,000 Dalton (measured via GPC), a content of vinyl acetate monomer ranging from 15 to 50% by weight, with the proviso that the content of vinyl acetate monomer in the respective copolymers differs from one copolymer to another, by over 5%, on a weight basis.

First claim

The invention claimed is:

1. A polymeric composition suitable for lowering the Pour Point of paraffinic crude oils comprising a synergic mixture comprising at least two ethylene-vinyl acetate (EVA) copolymers having an average molecular weight M w ranging from 25,000 to 100,000 Dalton (measured via GPC), a content of vinyl acetate (VA) monomer ranging from 15 to 50% by weight, respectively, with the proviso that the content of vinyl acetate monomer in the respective at least two ethylene-vinyl acetate copolymers differs from one another by a value higher than 5% on a weight basis,
wherein the synergic mixture does not comprise an alkyl(meth)acrylate polymer.

2. The polymeric composition according to claim 1 , wherein the number of EVA copolymers in the synergic mixture ranges from 2 to 6.

3. The polymeric composition according to claim 1 , wherein the EVA copolymers have a weight average molecular weight M W ranging from 25,000 to 80,000 Dalton.

4. The polymeric composition according to claim 1 , wherein the content of VA comonomers, on a weight basis, differs from one copolymer to another by a value from 7 to 22%.

5. The polymeric composition according to claim 1 , wherein the synergic mixture comprises three EVA copolymers having a content of vinyl acetate comonomer of 20, 30 and 40% by weight, respectively.

6. The polymeric composition according to claim 1 , wherein the synergic mixture comprises three EVA copolymers having a content of vinyl acetate comonomer of 24, 33 and 40% by weight, respectively.

7. The polymeric composition according to claim 1 , wherein the concentration of a single EVA copolymer, in the synergic mixture, is equal to or higher than 5% by weight.

8. The polymeric composition according to claim 7 , wherein the concentration of said single EVA copolymer in the synergic mixture ranges from 10 to 60% by weight.

9. A process for the lowering the Pour Point of a paraffinic crude oil having a paraffin content higher than 5% by weight, which comprises adding, to the paraffinic crude oil, from 50 to 1,500 ppm (by weight), with respect to the crude oil, a synergic mixture comprising at least two ethylene-vinyl acetate copolymers respectively having an average molecular weight M W ranging from 25,000 to 100,000 Dalton (measured via GPC), a content of vinyl acetate monomer ranging from 15 to 50% by weight, with the proviso that the content of vinyl acetate monomer in the respective at least two ethylene-vinyl acetate copolymers differs by a value higher than 5% on a weight basis,
wherein the synergic mixture does not comprise an alkyl(meth)acrylate polymer.

10. The process according to claim 9 , which comprises:
a. dissolving the synergic mixture in an organic solvent to obtain a solution (a),
b. adding the solution (a) to the paraffinic crude oil at the fluidification temperature of the crude oil, with a concentration of the synergic mixture in the crude oil ranging from 50 to 1,500 ppm.

11. The process according to claim 10 , wherein the solution (a) comprises from 1 to 10% by weight of the synergic mixture.

12. The process according to claim 10 , wherein the organic solvent is an aromatic hydrocarbon, an aliphatic hydrocarbon, a polar solvent, or mixtures thereof.

13. The process according to claim 9 , wherein the synergic mixture is added to the paraffinic crude oil together with a surfactant with a hydrophilic lipophilic balance (HLB), higher than or equal to 10.

14. A paraffinic crude oil having a Pour Point lower than 10° C. comprising:
i. a paraffinic crude oil with an average content of paraffins higher than 5% by weight; and
ii. 50-1,500 ppm (by weight) with respect to the crude oil of a synergic composition comprising at least two ethylene-vinyl acetate copolymers having a weight average molecular weight M W ranging from 25,000 to 100,000 Dalton (measured via GPC), a content of vinyl acetate monomer ranging from 15 to 50% by weight, with the proviso that the content of vinyl acetate monomer in the respective at least two ethylene-vinyl acetate copolymers differs from one another by a value higher than 5% on a weight basis,
wherein the synergic composition does not comprise an alkyl(meth)acrylate polymer.

Assignees

• Versalis Spa
• Eni Spa

Inventors

• Mariani Paolo
• Agnoli Michela
• Casalini Alessandro
• Merlini Massimo

Classifications

• C08L23/0853

  Ethylene vinyl acetate copolymers · CPC title

• C10L1/1973 Primary

  mono-carboxylic · CPC title

• C10L10/16

  Pour-point depressants · CPC title

• C10L2300/30

  Mixture of three components · CPC title

• C10L2230/14

  for improving storage or transport of the fuel · CPC title